Tri-isopropyl silyl acrylate

용도Triisopropylsilyl acrylate is a resin monomer used to make new antifouling coatings for marine vessels. Ternary monomer reactivity ratios of triisopropylsilyl acrylate (SiA), methyl methacrylate (MMA), and n-butyl acrylate (BA), as common monomers in self-polishing coatings (SPCs) binders are obtained using experimental data collected from free radical bulk polymerization at 70 °C[1].

Stir at the band of 1000ml, in the there-necked flask device of nitrogen mouth and drain, under nitrogen protection, choose triisopropyl silanol, toluene and triethylamine, proportionally 1mol: 400ml: 1.2mol mixes, heating under temperature 45 degree, reacts 3 hours; Add thiodiphenylamine, the quality of thiodiphenylamine is 0.03% of triisopropyl silanol quality; Add acrylate chloride, the ratio of acrylate chloride and triisopropyl silanol is 1mol: 1.2mol; React 2 as a child rectifying and draw Triisopropylsilyl acrylate, after measured, the rate of recovery of product is 97%, and purity is greater than 99.7%.