2-Ethylhexyl glycidyl ether (HCID 17162)

개요

2-ethylhexyl glycidyl ether is a clear colorless liquid. (NTP, 1992)

이름 및 식별자

우선 이름: 2-Ethylhexyl glycidyl ether
IUPAC: 2-(2-ethylhexoxymethyl)oxirane
현지명: 2-에틸헥실 글리시딜 에테르
영어명: 2-Ethylhexyl glycidyl ether
분자식: C11H22O2
분자량: 186.29

이름 및 동의어

2-ETHYLHEXYL GLYCIDYL ETHER2461-15-6Glycidyl 2-ethylhexyl etherOxirane, [[(2-ethylhexyl)oxy]methyl]-(((2-Ethylhexyl)oxy)methyl)oxiraneOxirane, 2-[[(2-ethylhexyl)oxy]methyl]-2,3-Epoxypropyl-(2-ethylhexyl) etherOxirane, (((2-ethylhexyl)oxy)methyl)-((2-Ethylhexyl)methyl)oxirane[(2-Ethylhexyl)methyl]oxiraneCCRIS 2634DTXSID6025301

이름 더 보기

2-에틸헥실글리시딜에테르2-에틸헥실글리시딜에테르(2-ETHYLHEXYLGLYCIDYLETHER)2-에틸헥실 글리시딜 에테르EHGEglycidyl2-ethylhexyletheroctylglycinether2-ethvlhexvlglvcidvletherEthyl Hexyl Glycidyl EtherEthylhexyl glycidyl ether, 2-

3-(GLYCIDYLOXYMETHYL)HEPTANEEINECS 219-553-6Propane, 1,2-epoxy-3-((2-ethylhexyl)oxy)-NSC 252154BRN 1236919LU1UZ98B89Oxirane, 2-(((2-ethylhexyl)oxy)methyl)-[[(2-ethylhexyl)oxy]methyl]oxirane

데이터베이스 식별자

CAS: 2461-15-6
PubChem CID: 17162
DTXSID: DTXSID6025301
ChEMBL: CHEMBL1412431
UNII: LU1UZ98B89
EC Number: 219-553-6
Nikkaji: J216.100A

물성

구조 계산 물성

XLogP: 2.9
극성 표면적: 21.8 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 2
회전 가능 결합 수: 8
무거운 원자 수: 13
형식 전하: 0
복잡도: 125

실험 및 물리화학적 성질

Density0.893 at 68 °F (NTP, 1992) - Less dense than water; will float

Solubilityless than 1 mg/mL at 66 °F (NTP, 1992)

Flash Point206 °F (NTP, 1992)

Boiling Point244 to 248 °F at 20 mmHg (NTP, 1992)

Physical Description · 2건

2-ethylhexyl glycidyl ether is a clear colorless liquid. (NTP, 1992)

Liquid

물리화학적 성질

끓는 점: 60 · 60-62 °C/0.3 mmHg (lit.)
밀도: 0.891 g/mL · 0.891 g/mL at 25 °C (lit.)
증기압: 29 Pa · 29Pa at 25℃
굴절률: 1.434 · 1.434
인화점: 206 °F · 206°F
저장 조건: Store at room temperature
물리적 상태: 투명한 액체
색상: 무색 내지 거의 무색
Specific Gravity: 0.91 · 0.910.891
냄새: Faint odor
수용성: 19 · 19ºC에서 <0.1g/100mL
안정성: 안정적인. 타기 쉬운. 강한 산화제, 산, 염기와 호환되지 않습니다.
InChI: 1S/C11H22O2/c1-3-5-6-10(4-2)7-12-8-11-9-13-11/h10-11H,3-9H2,1-2H3
InChIKey: BBBUAWSVILPJLL-UHFFFAOYSA-N
SMILES: CCCCC(CC)COCC1CO1
LogP: 3.83 · 3.83
NIST: Oxirane, [[(2-ethylhexyl)oxy]methyl]-(2461-15-6)
EPA: 2 · 2-Ethylhexyl glycidyl ether (2461-15-6)

화학적 성질

2-Ethylhexyl glycidyl ether is a colourless liquid, it has a low volatility and good chemical stability.

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 0.5% (7 of 1458) of reports.

Warning

H315 (97.1%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P272, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 1458 reports by companies from 18 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 5건

Chemical: Oxirane, [[(2-ethylhexyl)oxy]methyl]-

Oxirane, 2-[[(2-ethylhexyl)oxy]methyl]- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Oxirane, 2-[[(2-ethylhexyl)oxy]methyl]- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

TP - indicates a substance that is the subject of a proposed TSCA section 4 test rule.

Status: Active Update: 15-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13238

Oxirane, [[(2-ethylhexyl)oxy]methyl]-: Does not have an individual approval but may be used under an appropriate group standard

Fire HazardsThis chemical is combustible. (NTP, 1992)

Health HazardsSYMPTOMS: Symptoms of exposure to this compound may include irritation of the skin and eyes.

Reactive GroupEthers

Reactivity Profile2-ETHYLHEXYL GLYCIDYL ETHER is incompatible with acids, bases and oxidizing agents. (NTP, 1992)

Air and Water ReactionsInsoluble in water.

안전 및 보호

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)

First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Personal Protective Equipment (PPE) · 1건

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

안전 데이터

wgk: 2
tsca: TSCA listed
rtecs: TZ3300000
독성: rat,LD50,oral,7800mg/kg (7800mg/kg),"Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2n rev. ed. in 1985.Vol. 2A, Pg. 2210, 1981.
HS 번호: 29109000
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-37/39
기존화학 물질: 98-3-948
Hazard Classifications: Skin Irrit. 2Skin Sens. 1
스토리지 클래스: 10 - Combustible liquids

화학 및 산업

용도 및 제조

U.S. Production2023: 700,000 - <850,000 lb

Consumer UsesPaint additives and coating additives not described by other categories

Industry UsesSolvent

General Manufacturing Information · 2건

Paint and Coating Manufacturing

Oxirane, 2-[[(2-ethylhexyl)oxy]methyl]-: ACTIVE

응용 분야

용도2-Ethylhexyl glycidyl ether is a used as a commercial reactive diluent. It is also known to induce sister-chromatid exchanges in Chinese hamster cells.

일반 설명Clear colorless liquid.

제조 방법

생산 방법2-Ethylhexyl glycidyl ether is made by condensation of 2-ethylhexanol with epichlorohydrin followed by dehydrochlorination with caustic to form the epoxy ring.