Benzyl methacrylate (HCID 17236)

이름 및 식별자

우선 이름: Benzyl methacrylate
IUPAC: benzyl 2-methylprop-2-enoate
현지명: 메타크릴산 벤질
영어명: Benzyl methacrylate
분자식: C11H12O2
분자량: 176.21

이름 및 동의어

BENZYL METHACRYLATE2495-37-62-Propenoic acid, 2-methyl-, phenylmethyl esterDTXSID0022193Z3248K2SSMNSC-20970DTXCID302193RefChem:566762219-674-4benzyl 2-methylprop-2-enoatebenzylmethacrylateMethacrylic acid benzyl ester

이름 더 보기

2-프로펜산,2-메틸-,페닐메틸에스테르,2-메틸-2-프로펜산,페닐메틸,메스아크릴산,벤질2-메타크릴산메타크릴산벤질벤질메타크릴레이트메타크릴산벤질(BENZYLMETHACRYLATE)벤질 메타크릴레이트BZMABenzylmethacrylatMethacrylic acid benzylBENZYLMETHACRAYLATEBenzyl 2-methylacrylateCHLUMICRYI BZMA MonomerBenzyl methacrylate ,98%

phenylmethyl 2-methylprop-2-enoateMethacrylic acid, benzyl ester25085-83-0EINECS 219-674-4UNII-Z3248K2SSMMFCD00053684NSC 20970Benzyl methacrylate, 98%

데이터베이스 식별자

CAS: 2495-37-6
PubChem CID: 17236
DTXSID: DTXSID0022193
ChEMBL: CHEMBL3187485
UNII: Z3248K2SSM
EC Number: 219-674-4
Nikkaji: J60.239F

물성

구조 계산 물성

XLogP: 2.9
극성 표면적: 26.3 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 2
회전 가능 결합 수: 4
무거운 원자 수: 13
형식 전하: 0
복잡도: 190

실험 및 물리화학적 성질

SpringerMaterials PropertiesBoiling point

Physical DescriptionLiquid

물리화학적 성질

녹는점: 25 °C · <25 °C
끓는 점: 95 · 95-98 °C/4 mmHg (lit.)
밀도: 1.04 g/mL · 1.04 g/mL at 25 °C (lit.)
증기압: 3 Pa · 3Pa at 20℃
굴절률: 20 · n20/D 1.512(lit.)
인화점: 225 °F · 225 °F
저장 조건: 2 · 2-8°C(protect from light)
물리적 상태: 투명한 액체
색상: 무색의
수용성: 물에 불용성.
BRN: 2045924 · 2045924
안정성: 안정적인. 가연성. 자유 라디칼 개시제, 산화제, 환원제와 호환되지 않습니다. 열을 피하십시오. 감광성.
화장품 원료 기능: 필름 형성제
InChI: 1S/C11H12O2/c1-9(2)11(12)13-8-10-6-4-3-5-7-10/h3-7H,1,8H2,2H3
InChIKey: AOJOEFVRHOZDFN-UHFFFAOYSA-N
SMILES: CC(=C)C(=O)OCc1ccccc1
LogP: 3.1 at · 3.1 at 20℃
NIST: Benzyl methacrylate(2495-37-6)
EPA: 2 · 2-Propenoic acid, 2-methyl-, phenylmethyl ester (2495-37-6)

화학적 성질

Colorless oily liquid. Very slightly soluble in water, soluble in alcohol and oils. Soft, warm, herbaceous-rosy odor of moderate tenacity.

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H315 (91.1%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P272, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 313 reports by companies from 19 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 4건

Chemical: 2-Propenoic acid, 2-methyl-, phenylmethyl ester

2-Propenoic acid, 2-methyl-, phenylmethyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, 2-methyl-, phenylmethyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 20-05-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/10958

Benzyl methacrylate: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazard Classes and CategoriesSkin Irrit. 2 (91.1%)

안전 데이터

wgk: 1
tsca: TSCA listed
HS 번호: 29163990
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26
기존화학 물질: KE-25170
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
스토리지 클래스: 10 - Combustible liquids

화학 및 산업

용도 및 제조

U.S. Production2023: 700,000 - <850,000 lb

Industry UsesAdhesion/cohesion promoter

General Manufacturing Information · 2건

Adhesive Manufacturing

2-Propenoic acid, 2-methyl-, phenylmethyl ester: ACTIVE

응용 분야 · 2건

개요The cyclic methacrylate monomer benzyl methacrylate (BzMA) was evaluated as an alternative to traditional methyl methacrylate (MMA) as a hard monomer in the application of an acrylate latex pressure-sensitive adhesive (PSA). BzMA is widely used in nanoimprinting lithography, paint applications, inkjet inks, transparent adhesives, orthodontic adhesive compositions, and stationary phases in liquid chromatography[1].

용도Benzyl methacrylate is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.