3- 글리시 독시 프로필 트리 메 톡시 실란

Glycidoxypropyltrimethoxysilane

HCID 17317CAS 233765-90-7

부분 구조 검색 유사 구조 찾기

기본 정보

표준 SMILES: CO[Si](CCCOCC1CO1)(OC)OC
InChIKey: BPSIOYPQMFLKFR-UHFFFAOYSA-N
분자식: C9H20O5Si
평균 분자량: 236.34 g/mol
단동위원소 질량: 236.10800027

개요

See also: Glycidylpropyltrimethoxysilane homopol.~ (annotation moved to).

이름 및 식별자

우선 이름: Glycidoxypropyltrimethoxysilane
IUPAC: trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane
현지명: 3- 글리시 독시 프로필 트리 메 톡시 실란
영어명: 3-Glycidoxypropyltrimethoxysilane
분자식: C9H20O5Si
분자량: 236.34

이름 및 동의어

2530-83-8Silan A 187Silicone KBM 403Silane A 187Silane Z 6040GlycidoxypropyltrimethoxysilaneNUCA 1873-(Trimethoxysilyl)propyl glycidyl ethergamma-GlycidoxypropyltrimethoxysilaneGlycidyloxypropyltrimethoxysilaneKBM 403KBM 430

이름 더 보기

3-글리시독시프로필트리메톡시실란글리시독시프로필트리메톡시실란트라이메톡시[3-(옥시라닐메톡시)프로필]실란글라이시독시프로필트라이메톡시실란글리시독시프로필트리메톡시실란(GLYCIDOXYPROPYLTRIMETHOXYSILANE)[[3-(트라이메톡시릴릴)프로폭시]메틸]옥시란[3-(2,3-에폭시프로폭시)프로필]트라이메톡시실란[3-(글리시딜옥시)프로필]트라이메톡시실란1-(글리시딜록시)-3-(트라이메톡시실릴)프로판A-187Dynasylan GLYMOTMSPGEUnion Carbide A-187Y-4087감마-글리시독시프로필트라이메톡시실란KH-560GLYMO3-GLYCIDYLOXYPROPYLTRIMETHOXYSILANEγ-Glycidoxypropyltrimethoxysilane3-(2,3-EPOXYPROPOXY)PROPYLTRIMETHOXYSILANESilane coupling agent KH-560γ-(2,3-epoxypropoxy)propytrimethoxysilaneGF80GOPTS

DZ 6040A 187Y 4087Z 6040(3-(2,3-Epoxypropoxy)propyl)trimethoxysilane5K9X9X899R[3-(2,3-Epoxypropoxy)propyl]trimethoxysilaneRefChem:922335

데이터베이스 식별자

CAS: 233765-90-7、2530-83-8、25704-87-4
PubChem CID: 17317
DTXSID: DTXSID5027489
ChEMBL: CHEMBL2140162
UNII: 5K9X9X899R
EC Number: 219-784-2、247-194-5、807-562-3
Nikkaji: J48.152A

물성

구조 계산 물성

극성 표면적: 49.5 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 5
회전 가능 결합 수: 9
무거운 원자 수: 15
형식 전하: 0
복잡도: 166

실험 및 물리화학적 성질

PolymersPlastics & Rubber -> Glycidyl Ethers

Density1.065-1.075 @25 °C

Boiling Point290 °C @760 [mm Hg]

Vapor Pressure0.002 [mmHg]

Physical Description · 2건

Liquid; Dry Powder; Liquid

Liquid; [eChemPortal: SIDSUNEP] Clear colorless liquid; [MSDSonline]

물리화학적 성질

녹는점: -50 °C · -50°C
끓는 점: 120 °C2 · 120 °C2 mm Hg(lit.)
밀도: 1.07 g/mL · 1.070 g/mL at 20 °C
증기압: 0 · 0-12790Pa at 20-25℃
굴절률: 20 · n20/D 1.429(lit.)
인화점: 230 °F · >230 °F
저장 조건: 30 °C · Store below +30°C.
용해도: 아세토니트릴(약간 용해됨), 클로로포름
물리적 상태: 액체
색상: 투명한
Specific Gravity: 1.07 · 1.07
수용성: 알코올, 케톤, 지방족 또는 방향족 탄화수소와 혼합 가능합니다. 물과 섞이지 않습니다.
BRN: 4308125 · 4308125
Henry's Law Constant: 1.4 · 1.4×102 mol/(m3Pa) at 25℃, Ebert et al. (2023)
안정성: 수분에 민감한
화장품 원료 기능: 손톱 컨디셔닝
InChI: 1S/C9H20O5Si/c1-10-15(11-2,12-3)6-4-5-13-7-9-8-14-9/h9H,4-8H2,1-3H3
InChIKey: BPSIOYPQMFLKFR-UHFFFAOYSA-N
SMILES: CO[Si](CCCOCC1CO1)(OC)OC
LogP: -2.6 · -2.6-0.5 at 20℃
NIST: 3 · 3-Glycidoxypropyltrimethoxysilane(2530-83-8)
EPA: 3 · 3-(Trimethoxysilyl)propyl glycidyl ether (2530-83-8)

화학적 성질

Colorless transparent liquid

안전 및 규제

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 13.6% (281 of 2064) of reports.

Danger

H318 (54.1%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

P203, P264+P265, P273, P280, P305+P354+P338, P317, P318, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 2064 reports by companies from 31 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

유해성 정보

Regulatory Information · 6건

Chemical: Silane, trimethoxy[3-(oxiranylmethoxy)propyl]-

Chemical: Silane, trimethoxy[(oxiranylmethoxy)propyl]-

Regulation (EC) No 1935/2004 (amended)

Oxirane, 2-[[3-(trimethoxysilyl)propoxy]methyl]- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Oxirane, 2-[[3-(trimethoxysilyl)propoxy]methyl]- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

TP - indicates a substance that is the subject of a proposed TSCA section 4 test rule.

Status: Active Update: 10-02-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/14972

Other Safety Information · 2건

Evaluation - Chemicals that are unlikely to require further regulation to manage risks to environment

Hazards Summary · 1건

Mildly irritating to skin and eyes; Not a known skin sensitizer; Rapidly hydrolyzes into methanol and silanetriols; Oral LD50 (rats) = 7010 to 16900 mg/kg and dermal LD50 (rats) = 6800 mg/kg; [OECD SIDS: Trimethoxy[3-(oxiranylmethoxy)propyl]-silane - 2004] May cause irritation; May form siloxane polymer on contact with skin, eyes, or lungs; [MSDSonline]

Hazard Classes and Categories · 3건

Eye Dam. 1 (54.1%)

Skin Irrit. 2 (100%)

Serious eye damage/eye irritation - Category 1

안전 및 보호

Protective Action Criteria (PAC) · 3건

3.4 [mg/m3]

38 [mg/m3]

230 [mg/m3]

독성 정보

Toxicity DataLCLo (rat) =5,300 mg/m3/4h

안전 데이터

wgk: 2
tsca: TSCA listed
rtecs: VV4025000
독성: LD50 oral in rat: 22600uL/kg
HS 번호: 29310095
risk_code: 36/38-21-52-41
hazard_code: Xn,Xi
safety_code: 28A-26-36/37/39-24/25
포장분류: III
기존화학 물질: KE-34368
F 고인화성물질: 10-21
자연 발화 온도: 400°C
Hazard Classifications: Aquatic Chronic 3Eye Dam. 1
스토리지 클래스: 10 - Combustible liquids

화학 및 산업

용도 및 제조

Uses · 2건

Used as additive (cross-linking agent) for adhesion promotion in adhesives, sealants, coatings, and composites; Used in reinforcing glass fibers and foundry resins; [eChemPortal: SIDSUNEP]

Molding and Core Making [Category: Foundry]

U.S. Production2023: 2,500,000 - <4,000,000 lb

Consumer UsesAntioxidant

Industry UsesSizing agent

Household ProductsInformation on 3 consumer products that contain gamma-Glycidoxypropyltrimethoxysilane in the following categories is provided:

General Manufacturing Information · 2건

All Other Chemical Product and Preparation Manufacturing

Oxirane, 2-[[3-(trimethoxysilyl)propoxy]methyl]-: ACTIVE

응용 분야 · 3건

용도유기 실리콘 소재,로빙을 사용하여 하드 복합 재료의 강도 특성을 개선하는 데 사용될 수 보강 모드 유리 섬유 접착제와 무기 충전제 또는 유리 보강 등의 열가소성 수지.

용도Pre-treatment of carbon steel with 3-(Glycidoxypropyl)trimethoxysilane enhances the dry and wet adhesion while reducing the cathotic disbondment rate of an epoxy coating

일반 설명(3-Glycidyloxypropyl)trimethoxysilane (GPTMS) is a bifunctional organosilane with three methoxy groups on one side and an epoxy ring on the other. The methoxy groups bind well with glass substrates creating a 3D matrix. The epoxy group is reactive with amides, alcohols, thiols and acids. GPTMS is highly reactive in water and can be used as a linking agent between the surface of the silica and the polymeric matrix.