기본 정보
- CAS
2549-53-3- 표준 SMILES
C=C(C)C(=O)OCCCCCCCCCCCCCC- InChIKey
ATZHWSYYKQKSSY-UHFFFAOYSA-N- 분자식
- C18H34O2
- 평균 분자량
- 282.5 g/mol
- 단동위원소 질량
- 282.25588033
이름 및 식별자
- 우선 이름
- Tetradecyl methacrylate
- IUPAC
- tetradecyl 2-methylprop-2-enoate
- 현지명
- 테트라데실 2-메틸-2-프로펜산
- 영어명
- tetradecyl methacrylate
- 분자식
- C18H34O2
- 분자량
- 282.46
이름 및 동의어
TETRADECYL METHACRYLATEMyristyl methacrylateMethacrylic acid, tetradecyl ester2-Propenoic acid, 2-methyl-, tetradecyl esterEINECS 219-835-9DTXSID9027491UNII-64043KD67RHSDB 58851-TETRADECANOL, METHACRYLATETETRADECYL METHACRYLATE [HSDB]EC 219-835-9RefChem:188536
이름 더 보기
테트라데실2-메틸-2-프로펜산테트라데실2-메틸-2-프로펜산(TETRADECYL2-METHYL-2-PROPENOATE)etradecylmethacrylateAlkyl Methacrylate 14Lauryl Tetradecyl Methacrylate2-methylacrylic acid myristyl ester2-Methylpropenoic acid tetradecyl esterLauryl Methacrylate 1214 F (LMA 1214 F)
Tetradecyl 2methyl2propenoateDTXCID6074912Propenoic acid, 2methyl, tetradecyl esterATZHWSYYKQKSSY-UHFFFAOYSA-N2549-53-3tetradecyl 2-methylprop-2-enoate2-Propenoic acid,2-methyl-, tetradecyl esterTetradecyl 2-methyl-2-propenoate
데이터베이스 식별자
- CAS
2549-53-3- PubChem CID
- 17351
- DTXSID
DTXSID9027491- UNII
- 64043KD67R
- EC Number
- 219-835-9
- Nikkaji
- J107.762G
물성
구조 계산 물성
- XLogP
- 8.3
- 극성 표면적
- 26.3 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 2
- 회전 가능 결합 수
- 15
- 무거운 원자 수
- 20
- 형식 전하
- 0
- 복잡도
- 246
실험 및 물리화학적 성질
PolymersPlastics & Rubber -> (Meth)acrylates
SpringerMaterials PropertiesBoiling point
LogPlog Kow = 7.66 /Estimated/
Boiling Point147-154 °C at 0.093 kPa
Polymerization
Methyl methacrylate, and in general the methacrylic esters, polymerize much less readily than the corresponding ordinary acrylates. None the less, they are stabilized by adding hydroquinone or pyrogallol, particularly in the presence of metallic copper. /methacrylates/
Vapor Pressure
0.00018 [mmHg]
0.00018 mm Hg @ 25 °C /Estimated/
Refractive IndexIndex of refraction: 1.4480 @ 20 °C/D
Henry's Law ConstantHenry's Law constant: 2.5X10-2 atm cu m/mol @ 25 °C /Estimated/
Physical DescriptionLiquid
Other Experimental PropertiesHydroxyl radical reaction rate constant: 3.7X10-11 cu cm/molecule-sec @ 25 °C /Estimated/
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 4.9% (38 of 783) of reports.
Warning
H315 (95.1%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P272, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 783 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Regulatory Information
Chemical: 2-Propenoic acid, 2-methyl-, tetradecyl ester
2-Propenoic acid, 2-methyl-, tetradecyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, 2-methyl-, tetradecyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 25-08-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/14692
2-Propenoic acid, 2-methyl-, tetradecyl ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Other Safety InformationIMAP assessments - 2-Propenoic acid, 2-methyl-, tetradecyl ester: Human health tier I assessment
Hazards SummarySee ACRYLIC RESINS (MONOMERS).
Hazard Classes and CategoriesSkin Irrit. 2 (95.1%)
안전 및 보호
Storage Conditions
화학 및 산업
약리 정보
Metabolism/Metabolites
Small quantities of methacrylates may readily be metabolized by saponification into the alcohol and methacrylic acid. The latter may form an acetyl-coenzyme A derivative, which then enters the normal lipid metabolism. /Methacrylates/
Acrylates and methacrylates are detoxified predominantly via conjugation with glutathione via the Michael addition reaction or glutathione-S-transferase. They are also likely to be hydrolyzed via carboxylesterases. The lower molecular weight esters are rapidly metabolized and eliminated, therefore, will not likely cause cumulative toxicity. /Acrylates and Methacrylates/
용도 및 제조
Uses
Used as monomer for polymethacrylates, additive for hydraulic oils, and softener for lacquers; [HSDB]
Painting (Pigments, Binders, and Biocides) [Category: Paint]
Monomer for the synthesis of polymethacrylates, additive for hydraulic oils; softener for lacquers.
U.S. Production2023: 10,000,000 - <25,000,000 lb
Consumer UsesMonomers
Industry UsesMonomers
Methods of Manufacturing
The methacrylates can be synthesized by catalytic oxidation of isobutylene and subsequent esterification with the appropriate alcohol, or by reacting acetone with hydrocyanic acid and subsequent esterification in sulfuric acid with the appropriate alcohol. /Methacrylic esters/
Household ProductsInformation on 1 consumer products that contain Tetradecyl methacrylate in the following categories is provided:
General Manufacturing Information
Plastics Material and Resin Manufacturing
2-Propenoic acid, 2-methyl-, tetradecyl ester: ACTIVE
관련 반응
0건
현재 필터 조건에 해당하는 반응 기록이 없습니다.
화합물 노트
불러오는 중…