N,N-Diethylethanamine trihydrofluoride (HCID 175505)

개요

See also: Triethylammonium fluoride (annotation moved to).

이름 및 식별자

우선 이름: N,N-Diethylethanamine trihydrofluoride
IUPAC: N,N-diethylethanamine;trihydrofluoride
현지명: 불화 트리에틸암모늄
영어명: Triethylamine trihydrofluoride
분자식: C6H18F3N
분자량: 161.21

이름 및 동의어

Triethylamine trihydrofluorideN,N-Diethylethanamine trihydrofluoridetriethylamine trishydrofluorideEINECS 277-550-5DTXSID2074372Ethanamine, N,N-diethyl-, hydrofluoride (1:3)RefChem:822328DTXCID7047568Ethanamine, N,Ndiethyl, trihydrofluorideEthanamine, N,Ndiethyl, hydrofluoride (1:3)UN179073602-61-6

이름 더 보기

불화트리에틸암모늄불화트리에틸암모늄트라이에틸아민 트라이하이드로플루오라이드N,N-다이에틸에탄아민 트라이하이드로플루오라이드N,N-다이에틸에탄아민 하이드로플루오라이드 (1:3)불화 트리에틸암모늄에탄아민, N,N-다이에틸-, 트라이하이드로플루오라이드트리에틸아민 트리스(플루오린화 수소)HFTEA.3HFTRIETHYLAMINE TRIS(HYDROGEN FLUORIDE)Triethylamine trihydroflourideTREAT-HFtrihydrofluorideTriethylamine trihydriethylamine trihydrofluorideHYDROGEN FLUORIDE TRIETHYLAMINE

Ethanamine, N,N-diethyl-, trihydrofluorideN,N-diethylethanamine;trihydrofluorideMFCD00043294hydrogen fluoride in triethylaminehf 37% in triethylamineC6H18F3NTREAT HFZX9Z7YP3AB

데이터베이스 식별자

CAS: 73602-61-6
PubChem CID: 175505
DTXSID: DTXSID2074372
UNII: ZX9Z7YP3AB

물성

구조 계산 물성

극성 표면적: 3.2 Å²
수소 결합 공여자 수: 3
수소 결합 수용자 수: 4
회전 가능 결합 수: 3
무거운 원자 수: 10
형식 전하: 0
복잡도: 25.7

실험 및 물리화학적 성질

Chemical ClassesNitrogen Compounds -> Other Nitrogen Compounds

Physical DescriptionColorless liquid with a pungent odor; Hygroscopic; [Alfa Aesar MSDS]

물리화학적 성질

녹는점: -29 · -29--27°C
끓는 점: 70 °C15 · 70 °C15 mm Hg(lit.)
밀도: 0.989 g/mL · 0.989 g/mL at 25 °C(lit.)
굴절률: 20 · n20/D 1.3915(lit.)
인화점: 190 °F · 190 °F
저장 조건: 30 °C · Store below +30°C.
용해도: soluble in Chloroform, Hexane
물리적 상태: 액체
Specific Gravity: 0.989 · 0.989
색상: 투명한 노란색에서 갈색까지
수소이온지수(pH): 3 · 3 (H2O, 20℃)(saturated aqueous solution)
수용성: 녹는
BRN: 5522945 · 5522945
InChI: 1S/C6H15N.3FH/c1-4-7(5-2)6-3;;;/h4-6H2,1-3H3;3*1H
InChIKey: IKGLACJFEHSFNN-UHFFFAOYSA-N
SMILES: F[H].F[H].F[H].CCN(CC)CC
EPA: Ethanamine, N,N-diethyl-, trihydrofluoride (73602-61-6)

화학적 성질

clear yellow liquid

안전 및 규제

유해성 정보

Regulatory Information · 2건

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Triethylamine trishydrofluoride: HSNO Approval: HSR006811 Approved with controls

Hazards SummaryCauses burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Highly toxic by ingestion, inhalation, and skin absorption; [Alfa Aesar MSDS] See Hydrogen fluoride. See Triethylamine hydrochloride.

독성 정보

Adverse EffectsDermatotoxin - Skin burns.

안전 데이터

wgk: 3
tsca: TSCA listed
ridadr: UN 3265 8/PG 2
HS 번호: 29211910
risk_code: 26/27/28-35-36/37/38-20/21/22-11
hazard_code: T+,T,C,Xi,F
safety_code: 26-36/37/39-45-7/9-36/37-36-61-29-16-3
포장분류: II
위험 등급: 8
기존화학 물질: KE-05-1313
위험 참고 사항: Corrosive
Hazard Classifications: Acute Tox. 1 DermalAcute Tox. 2 InhalationAcute Tox. 2 OralEye Dam. 1Skin Corr. 1A
스토리지 클래스: 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
함량 및 규제정보: 물질구분: 유독물질; 혼합물(제품)함량정보: 불화 트리에틸암모늄 및 이를 25% 이상 함유한 혼합물
유해화학물질 필터링: 2003-1-540

화학 및 산업

용도 및 제조

General Manufacturing InformationEthanamine, N,N-diethyl-, hydrofluoride (1:3): ACTIVE

응용 분야 · 2건

용도Triethylamine trihydrofluoride acts as a mild and selective fluorinating agent used in the synthesis of acid fluorides and alkyl fluorides. It is also used in the synthesis of vicinal difluorides from epoxides, 3-fluoroazetidine. It is utilized as a selective reagent for the cleavage of O-silyl groups in carbohydrates, nucleotides and cyanohydrins. It is actively involved in the electrochemical fluorodeiodination of alkyl iodides and fluorodesilylation in beta-lactams.

일반 설명Triethylamine trihydrofluoride (TREAT-HF) is a mild and selective reagent for the fluorination of a wide variety of compounds.