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펜타보란

Pentaborane

HCID 178604530
노트반응
기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
19624-22-7
분자식
B5H9
평균 분자량
55.06 g/mol

이름 및 식별자

우선 이름
Pentaborane
현지명
펜타보란
영어명
Pentaborane
분자식
B5H9
분자량
55.06

이름 및 동의어

펜타보란펜타보레인펜타보레인(펜타보란)pentaborane(9)Chebi:33591PentaboraneNido-pentaborane(9)2,3:2,5:3,4:4,5-Tetra-muh-nido-pentaborane(9)(2,3-Muh),(2,5-muh),(3,4-muh),(4,5-muh)-nido-pentaborane(9)

데이터베이스 식별자

CAS
19624-22-7

물성

물리화학적 성질

녹는점
-46.6 ° · -46.6°
끓는 점
60 ° · bp 60°
밀도
40 · d40 0.61
증기 밀도
2.2 · 2.2
용해도
2 O · reacts with hot H2O
물리적 상태
발화 가능한 액체
색상
무색의 기체 또는 액체
냄새
나쁜 냄새
수용성
88 · 가열하면 가수분해됨 [COT88]
비열
2.74 J/ · Cp(liquid): 2.74 J/(g·K); Cp(gas): 1.81 J/(g·K), at 25℃
Dielectric constant
21 · 21.0(Ambient)
EPA
Pentaborane (19624-22-7)

화학적 성질

Pentaborane is a colorless, volatile liquid. Unpleasant, sweetish odor, like sour milk. The Odor Threshold is 0.8 ppm.

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

안전 데이터

OEB
E
OEL
TWA: 0.005 ppm (0.01 mg/m3), STEL: 0.015 ppm (0.03 mg/m3)
IDLA
1 ppm
tsca
TSCA listed
ridadr
UN 1380
독성
LC50 ihl-rat: 6 ppm/4H AIHAAP 19,46,58
포장분류
I
위험 등급
4.2
기존화학 물질
KE-27855
유해 물질 데이터
19624-22-7(Hazardous Substances Data)

화학 및 산업

응용 분야 · 3건

개요Pentaborane is a nonmetallic, colorless liquid with a pungent odor. It decomposes at 300°F (148°C), if it has not already ignited, and will ignite spontaneously in air if impure. It is a dangerous fire and explosion risk, with a flammable range of 0.46%–98% in air. Boiling point is 145°F (64°C), flash point is 86°F (30°C), and ignition temperature is 95°F (35°C), which is extremely low. Any object that is 95°F (35°C) or above can be an ignition source. Ignition sources can be ordinary objects on a hot day in the summer, such as the pavement, metal on vehicles, and even the air. In addition to extreme flammability, it is also toxic by ingestion or inhalation and is a strong irritant. TLV is 0.005 ppm in air, and it is immiscible in water. The four-digit UN identification number is 1380. The NFPA 704 designation for pentaborane is health 4, flammability 4, and reactivity 2. The primary uses are as fuel for air-breathing engines and as a propellant.

용도There appears to be no commercial market for pentaborane. In the 1950s it was explored as a potential rocket fuel.

일반 설명A clear colorless liquid with a pungent odor like sour milk, and flammable.It is corrosive to natural rubber, some synthetic rubber, some greases, and some lubricants and gives off irritating or toxic fumes (or gases) in a fire. It reacts violently with fire. Pentaboron nonahydride incompatible with strong oxidants such as chromium anhydride, chlorate and potassium permanganate, and other contacts. Vapors toxic both under prolonged exposure to low concentrations and short exposure to high concentrations. Density 0.61 g / cm3. Under prolonged exposure to intense heat the containers may rupture violently and rocket.

제조 방법

Pentaborane is obtained by passing diborane through a hot tube. Careful control of temperature, pressure, and flow are required to obtain good yields and avoid further pyrolysis to higher hydrides.

상·하류 제품 정보

상류 원료

펜타보란(9),1-요오도-

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