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염소산용액

Chloric acid

HCID 19654
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
7790-93-4
표준 SMILES
[O-][Cl+2]([O-])O
InChIKey
LSUVGSGHYCLVPU-UHFFFAOYSA-N
분자식
ClHO3
평균 분자량
84.46 g/mol
단동위원소 질량
83.96142157

개요

Chloric acid is a colorless liquid. It will accelerate the burning of combustible materials and can ignite most on contact. It is corrosive to metals and tissue. It is used as a reagent in chemical analysis and to make other chemicals.

이름 및 식별자

우선 이름
Chloric acid
IUPAC
chloric acid
현지명
염소산용액
영어명
CHLORIC ACID
분자식
ClHO3
분자량
84.46

이름 및 동의어

CHLORIC ACID7790-93-4Z0V9L75H3KDTXSID1047449CHEBI:17322RefChem:5667DTXCID9027449CLO2--Portable sterilization card232-233-0ChlorsaeureChloric(V) acidUNII-Z0V9L75H3K
이름 더 보기
클로르산염소산염소산용액Chloride AcidC01485NA-9191chloricNA 2626Hypure CchloricacidChloric acid solutionCHLORIC ACID, 35 WT. % SOLUTIONCHLORIC ACID ISO 9001:2015 REACH
hydrogenchloric acidEINECS 232-233-0UN2626hydrogen chloric acidHClO3hydroxidodioxidochlorineCHLORIC ACID [MI]SCHEMBL18802

데이터베이스 식별자

CAS
7790-93-4
PubChem CID
19654
DTXSID
DTXSID1047449
ChEMBL
CHEMBL1161633
ChEBI
CHEBI:17322
UNII
Z0V9L75H3K
EC Number
232-233-0
Nikkaji
J74.689D

물성

구조 계산 물성보충 중

XLogP
2.1
극성 표면적
54.4 Ų
수소 결합 공여자 수
1
수소 결합 수용자 수
3
회전 가능 결합 수
0
무거운 원자 수
4
형식 전하
0
복잡도
46.2

실험 및 물리화학적 성질

Chemical Classes · 2건

Toxic Gases & Vapors -> Acids, Inorganic

Reactive agents - 4th degree

Physical Description · 2건

Chloric acid is a colorless liquid. It will accelerate the burning of combustible materials and can ignite most on contact. It is corrosive to metals and tissue. It is used as a reagent in chemical analysis and to make other chemicals.

Found only in aqueous solution; [Merck Index] Clear colorless liquid; [MSDSonline]

물리화학적 성질

녹는점
-20 ℃ · <-20℃ [CRC10]
끓는 점
100 °C · >100 °C
밀도
1.2 g/mL · 1.2 g/mL at 25 °C
용해도
2 O · very soluble in H2O
색상
exists only in aqueous solution
수용성
2 O · 매우 잘 녹는 H2O [CRC10]
Merck
13 · 13,2109
EPA
Chloric acid (7790-93-4)

화학적 성질

can occur only in an aqueous solution; oxidizing agent; preparation: reaction between H2SO4 and barium chlorate; used as a catalyst in the polymerization of acrylonitrile, as an oxidizing agent [MER06] [HAW93]

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H271 (100%): May cause fire or explosion; strong Oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P260, P264, P280, P283, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P306+P360, P316, P321, P363, P370+P378, P371+P380+P375, P405, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H271: May cause fire or explosion; strong Oxidizer [Danger Oxidizing liquids; Oxidizing solids]

유해성 정보

Regulatory Information · 2건

Chloric acid: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelOxidizer
Fire Hazards · 2건

Excerpt from ERG Guide 140 [Oxidizers]:

CAUTION: Ammonium nitrate products may explode if involved in fire or contaminated with hydrocarbons (fuels), organic matter, other contaminants or when hot molten and contained. Treat as an explosive (GUIDE 112).

Health Hazards · 2건

Excerpt from ERG Guide 140 [Oxidizers]:

· Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death.

Hazards Summary · 1건

A strong skin and mucous membrane irritant; [Merck Index] Corrosive to tissue; [CAMEO] An eye irritant; [eChemPortal: ERMA] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis and pulmonary edema; [MSDSonline]

화학 및 산업

용도 및 제조

UsesUsed as an oxidizing agent and as a catalyst in acrylonitrile polymerization; [Merck Index] Used in chemical analysis and to make other chemicals; [CAMEO]
General Manufacturing InformationChloric acid: ACTIVE
응용 분야 · 3건

개요Chloric acid, HClO3, is an oxoacid of chloride, and the formal precursor of chlorate salts. It is a strong acid (pKa=-1) and a strong oxidizing agent. It is stable in cold aqueous solution up to a concentration of approximately 30%, and solution of up to 40% can be prepared by careful evaporation under reduced pressure. Above these concentrations, and on warming, chloric acid solutions decompose to give a variety of products, for example: 8HClO3→4HClO4+2H2O+2Cl2+3O2 Note that it disproportionates into perchloric acid in which the chlorine atom has a+7 oxidation state and also the zero oxidation state of chlorine gas (an oxidation–reduction reaction). Thus, under the proper conditions, it can also be used to make perchloric acid. 3HClO3→HClO4+H2O+2ClO2

용도Oxidizing agent; with H2SO3 as catalyst in acrylonitrile polymerization.

일반 설명CHLORIC ACID is a colorless liquid. CHLORIC ACID will accelerate the burning of combustible materials and can ignite most on contact. CHLORIC ACID is corrosive to metals and tissue. CHLORIC ACID is used as a reagent in chemical analysis and to make other chemicals.

상·하류 제품 정보

하류 제품

Moclobemidesodium oleyl sarcosinate시클로프로필아민아이오딘산 나트륨(요오드산 나트륨)

관련 반응

15건
반응 기록 만들기
HRID 5280 반응식
HRID 5280반응물로uspto-grants-1993_09
HRID 5283 반응식
HRID 5283반응물로uspto-grants-1993_09
HRID 61321 반응식
HRID 61321반응물로uspto-grants-2016_09
HRID 93419 반응식
HRID 93419반응물로Training data from https://doi.org/10.1039/C8SC04228D (2/10)
HRID 291636 반응식
HRID 291636반응물로Training data from https://doi.org/10.1039/C8SC04228D (8/10)
HRID 298530 반응식
HRID 298530반응물로Training data from https://doi.org/10.1039/C8SC04228D (8/10)
HRID 481927 반응식
HRID 481927생성물로uspto-grants-1998_08
HRID 944683 반응식
HRID 944683반응물로Validation data from https://doi.org/10.1039/C8SC04228D
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화합물 노트

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이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
더보기
새 노트새 반응견적 요청하기
DOT ID and Guide2626 140
Reactive GroupAcids, Strong Oxidizing
Reactivity AlertsStrong Oxidizing Agent
Reactivity Profile · 1건

Self-reactive. Concentrations of CHLORIC ACID above 40% decompose [Mellor 2 Supp. 1:576 1956]. Antimony sulfide and concentrated solutions of chloric acid react with incandescence [Mellor Supp. II Part I:584 1956]. Arsenic sulfide and concentrated solutions of chloric acid react with incandescence. Reacts with vigor even explodes with other metal sulfides, i.e. copper sulfide [Mellor Supp. II Part I:584 1956]. In contact with oxidizable materials, including ammonia, reactions can be extremely violent. Filter paper ignites after soaking in chloric acid, [Mellor, 1946, Vol. 2, 310]. Explosions have been recorded by mixtures of chloric acid solution with metals such as: antimony, bismuth, and iron. This is due to the formation of explosive compounds including hydrogen.

Air and Water ReactionsWater soluble.
Hazard Classes and Categories · 3건

Ox. Liq. 1 (100%)

Oxidizing liquids - Category 1-2

Reactive agents - 4th degree

안전 및 보호

Fire FightingExcerpt from ERG Guide 140 [Oxidizers]:
Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Keep combustibles (wood, paper, oil, etc.) away from spilled material.

First Aid · 2건

Excerpt from ERG Guide 140 [Oxidizers]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 140 [Oxidizers]:
Isolation and Evacuation · 2건

Excerpt from ERG Guide 140 [Oxidizers]:

Immediate precautionary measure

Personal Protective Equipment (PPE)Excerpt from ERG Guide 140 [Oxidizers]:
Emergency Response Planning GuidelinesSmall Fire

독성 정보

Adverse EffectsDermatotoxin - Skin burns.

안전 데이터

tsca
TSCA listed
ridadr
UN 2626
risk_code
8-34
hazard_code
O,C
safety_code
17-26-36/37/39-45
포장분류
II
위험 등급
5.1
기존화학 물질
KE-05474
크리스탈 바이올렛
부틸나프탈렌술폰산 나트륨
하이드라진, 모노수화물
에스트론
산화 녹말
alkyl phenylsufonate
소다의 염산
1-아미노-4-하이드록시-2-페녹시안트라퀴논
CI 77492
산화코발트
CHLORIDE STANDARD
2-아미노-4-클로로-6-니트로벤조산