1,3-디메틸-1,3-디하이드로-2-페닐-2H-벤즈이미다졸
1,3-디메틸-1,3-디하이드로-2-페닐-2H-벤즈이미다졸 · 1,3-Dimethyl-2-phenylbenzimidazoline · 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole · 1,3-Dimethyl-2-phenyl-2,3-dihydro-1H-benzimidazole · 1,3-dimethyl-2-phenyl-2h-benzimidazole · 1,3-dimethyl-2-pehnylbenzimidazolium cation · 1,3-Dimethyl-2-phenyl-2,3-dihydrobenzimidazole · 2,3-Dihydro-1,3-dimethyl-2-phenylbenzimidazole
식별자 및 물리적 특성
| CAS No. | 3652-92-4 |
|---|---|
| 분자식 | C15H16N2 |
| 평균 분자량 | 224.307 g/mol |
| 단동위원소 질량 | 224.13134851 g/mol |
| SMILES | CN1c2ccccc2N(C)C1c1ccccc1 |
| InChIKey | VDFIVJSRRJXMAU-UHFFFAOYSA-N |
| PubChem CID | 199049 |
| DTXSID | DTXSID90190025 |
| 현지명 | 1,3-디메틸-1,3-디하이드로-2-페닐-2H-벤즈이미다졸 |
화학 및 물리적 성질
| 녹는점 | 93-94 °C |
|---|---|
| 끓는 점 | 359.9±42.0 °C(Predicted) |
| 밀도 | 1.095±0.06 g/cm3(Predicted) |
| 저장 조건 | Store at room temperature |
| pKa(산도 계수) | 5.68±0.40(Predicted) |
안전 및 규제
| 신호 어 | Warning |
|---|---|
| 유해·위험 문구 | 암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드 H315 |
용도
용도
1,3-Dimethyl-1,3-dihydro-2-phenyl-2H-benzimidazole is used for heterocycle capable of reducing α-halo ketones, α,β-unsaturated carbonyl compounds, and α- nitro sulfones.
제조 및 합성 방법
제조 방법
1,3-Dimethyl-1,3-dihydro-2-phenyl-2H-benzimidazole is prepared by the following steps: N1,N2-dimethyl-o-phenylenediamine is condensed with benzaldehyde in methanol-acetic acid. The product is purified by recrystallization from petroleum ether. The spent reagent may be recovered and reactivated by Sodium Borohydride in methanol.