Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
이소프로필글리시딜에테르
이소프로필글리시딜에테르 · 아이소프로필 글리시딜 에테르 · ISOPROPYL GLYCIDYL ETHER · 2-(Isopropoxymethyl)oxirane · IPGE · NCI-C56439 · AKOS NCG-0053 · ISOPROPOXYMETHYLOXIRANE
식별자 및 물리적 특성
| CAS No. | 4016-14-2 |
|---|---|
| 분자식 | C6H12O2 |
| 평균 분자량 | 116.16 g/mol |
| 단동위원소 질량 | 116.08372962 g/mol |
| SMILES | CC(C)OCC1CO1 |
| InChIKey | NWLUZGJDEZBBRH-UHFFFAOYSA-N |
| PubChem CID | 19920 |
| ChEMBL | CHEMBL1487011 |
| EC No. | 223-672-9 |
| DTXSID | DTXSID6025480 |
| 현지명 | 이소프로필글리시딜에테르 |
화학 및 물리적 성질
| XLogP | 0.6 |
|---|---|
| 극성 표면적 | 21.8 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 2 |
| 회전 가능 결합 수 | 3 |
| 무거운 원자 수 | 8 |
| 형식 전하 | 0 |
| 복잡도 | 70 |
| LogP(분배 계수) | 0.5 |
| 밀도 | 0.92 (USCG, 1999) - Less dense than waterwill float0.9186 @ 20 °C/4 °CRelative density (water = 1): 0.920.924 g/mL at 25 °C (lit.) |
| Color/Form | MOBILE, COLORLESS LIQUIDColorless liquid. |
| 용해도 | greater than or equal to 100 mg/mL at 66 °F (NTP, 1992)18.8% IN WATER, SOL IN KETONES & ALCOHOLSSolubility in water, g/100ml: 1919%188g/L |
| 인화점 | 92 °F (NTP, 1992)33 °C33 °C c.c. |
| 끓는 점 | 261 °F at 760 mmHg (NTP, 1992)137 °C @ 760 MM HG279 °F131-132 °C (lit.) |
| 증기 밀도 | 4.15 (AIR= 1)Relative vapor density (air = 1): 4.15 |
| 후각 역치 | Odor Threshold Low: 300.0 [ppm]Odor threshold from "Quick Guide: The Electronic NIOSH Pocket Guide to Chemical Hazards" |
| 증기압 | 9.4 mmHg at 77 °F (NTP, 1992)9.4 [mmHg]9.4 MM HG @ 25 °CVapor pressure, kPa at 25 °C: 1.259 mmHg at 77 °F(77 °F): 9 mmHg13 hPa (25 °C) |
| Physical Description | Isopropyl glycidyl ether is a colorless liquid. (USCG, 1999)[NIOSH]COLOURLESS LIQUID.Colorless liquid. |
| Other Experimental Properties | CONVERSION FACTORS: 1 PPM APPROX= 4.74 MG/CU M @ 25 °C, 760 MM HG, 1 MG/L APPROX= 211 PPM @ 25 °C, 760 MM HG |
| 굴절률 | n20/D 1.410(lit.) |
| 저장 조건 | Store below +30°C. |
| 물리적 상태 | 무색의 액체 |
| 색상 | 무색 내지 거의 무색 |
| pH | 7 (188g/l, H2O, 20℃) |
| 용해도 | 19g/L at 25℃ |
| BRN | 103028 |
| 안정성 | 안정적인. 가연성. 강한 산화제와 호환되지 않습니다. |
| InChI | 1S/C6H12O2/c1-5(2)7-3-6-4-8-6/h5-6H,3-4H2,1-2H3 |
| InChIKey | NWLUZGJDEZBBRH-UHFFFAOYSA-N |
| SMILES | CC(C)OCC1CO1 |
| LogP(분배 계수) | 0.8 at 25℃ |
| EPA | Isopropyl glycidyl ether (4016-14-2) |
화학적 성질
colourless liquid
안전 및 규제
| GHS 분류 | WarningH226 (100%): Flammable liquid and vapor [Warning Flammable liquids]H315 (97.6%): Causes skin irritation [Warning Skin corrosion/irritation]H317 (95.1%): May cause an allergic skin reaction [Warning Sensitization, Skin]H319 (97.6%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]H335 (92.7%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposureRespiratory tract irritation]P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P272, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 41 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
|---|---|
| 규제 정보 | TP - indicates a substance that is the subject of a proposed TSCA section 4 test rule.Status: Active Update: 25-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/23504Isopropyl glycidyl ether IGE: Does not have an individual approval but may be used under an appropriate group standardThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| 운송 라벨(DOT) | Flammable Liquid |
| 화재 위험 | Special Hazards of Combustion Products: Toxic vapors and gases, such as carbon monoxide, may be released in a fire.Behavior in Fire: Vapors can flow along surfaces to remote ignition source and flash back. (USCG, 1999)Flammable. Above 33 °C explosive vapour/air mixtures may be formed. |
| 건강 유해성 | Exposure can cause mental confusion and moderate irritation of the eyes, skin, and respiratory tract. Chronic exposure can cause dermatitis and skin sensitization. (USCG, 1999) |
용도
용도
Glycidyl isopropyl ether is a stabilizer of chlorinated solvents, and viscosity reducer of epoxy resins.
일반 설명
Colorless liquid.
제조 및 합성 방법
생산 방법
Isopropyl glycidyl ether is manufactured through the condensation of isopropyl alcohol and epichlorohydrin with subsequent dehydrochlorination with caustic to form the epoxy ring.