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HCID 2124생성일: 2026년 11월 3일

플루오린화 알루미늄

불화알루미늄 · 삼플루오르화알루미늄 · 알루미늄플로라이드 · 플루오르화알루미늄 · 플루오린화알루미늄 · 알루미늄플루오라이드 · ALUMINIUM FLUORIDE · Aluminum trifluoride

https://huagongshe.com/ko/chemical/2124

플루오린화 알루미늄 분자 구조식

식별자 및 물리적 특성

CAS No.7784-18-1
분자식AlF3
평균 분자량83.9767 g/mol
단동위원소 질량83.97674829 g/mol
SMILES[F][Al]([F])[F]
InChIKeyKLZUFWVZNOTSEM-UHFFFAOYSA-K
PubChem CID2124
ChEBICHEBI:49464
EC No.232-051-1
DTXSIDDTXSID8030712
현지명플루오린화 알루미늄

화학 및 물리적 성질

극성 표면적0
수소 결합 공여자 수0
수소 결합 수용자 수3
회전 가능 결합 수0
무거운 원자 수4
형식 전하0
복잡도8
물질 분류Metals -> Metals, Inorganic CompoundsCorrosives
화장품Oral careAntiplaque
밀도2.88 at 77 °F (USCG, 1999) - Denser than waterwill sink3.102.9 g/cm³3.1 @25 °C3.1 g/mL at 25 °C (lit.)
Color/FormWhite, hexagonal crystals
용해도Loses water at 100 °C, more at 200 °C. ... slight solubility. /Trihydrate/In water, 0.559 g/100 mL @ 25 °CSparingly soluble in acids and alkalies, even hot concentrated H2SO4 has little effect.INSOL IN ALC & ACETONESolubility in water, g/100ml at 20 °C: 0.5산과 알칼리에 거의 용해되지 않습니다. 아세톤에 불용성.
끓는 점1272 °C @760 [mm Hg]1291 °C
DecompositionWhen heated to decomposition it emits highly toxic fumes of /hydrogen fluoride/.
녹는점1291 °C1290 °C1290 °C (lit.)
증기압1 mm Hg @ 1238 °CVapor pressure, Pa at 1238 °C: 133
Physical DescriptionAluminum fluoride appears as odorless white powder or granules. Denser than water. Solubility in water at 25 °C equals 0.559 g / 100 mL.Other SolidDry PowderWhite solid[Hawley] Hygroscopic[ICSC] Odorless powder[MSDSonline]HYGROSCOPIC WHITE OR COLOURLESS CRYSTALS.
Stability/Shelf LifeLow melting solids or colorless, volatile liquids. /Alkylaluminum halides/Less sensitive than trialkylaminums to oxidation upon exposure to air. /Alkylaluminum halides/
자연 발화 온도Not flammable (USCG, 1999)
인화점1250°C
저장 조건2-8°C, protect from light, stored under nitrogen
물리적 상태가루
색상흰색에서 밝은 회색까지
비중2.882
용해도약간 용해됨
비열Cp(crystal): 0.89 J/(g·K)Cp(gas): 0.75 J/(g·K), at 25℃
Merck14,339
유전율2.2(Ambient)
화장품 원료 기능안티플라크구강 관리
InChI1S/Al.3FH/h3*1H/q+3/p-3
InChIKeyKLZUFWVZNOTSEM-UHFFFAOYSA-K
SMILESF[Al](F)F
NISTAluminum trifluoride(7784-18-1)
EPAAluminum trifluoride (7784-18-1)

화학적 성질

Aluminum fluoride, AlF3, is an anhydrous crystalline powder with a melting point of 1291 "C. Aluminum fluoride (hydrated), AlF3·31/2H20, is a white crystalline powder that is insoluble in water.

안전 및 규제

GHS 분류This chemical does not meet GHS hazard criteria for 95.2% (360 of 378) of all reports.Not ClassifiedAggregated GHS information provided per 378 reports by companies from 11 notifications to the ECHA C&L Inventory.DangerH301: Toxic if swallowed [Danger Acute toxicity, oral]P203, P260, P261, P264, P264+P265, P270, P271, P280, P301+P316, P304+P340, P305+P351+P338, P318, P319, P321, P330, P337+P317, P403+P233, P405, and P501 (click each P-code to see the statement)
규제 정보Chemical: Aluminium fluoride (AlF3)Aluminum fluoride (AlF3) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Aluminum fluoride (AlF3) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 05-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/15258Aluminium fluoride: Does not have an individual approval but may be used under an appropriate group standardThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
기타 안전 정보IMAP assessments - Aluminium fluoride (AlF3): Human health tier I assessment
화재 위험Special Hazards of Combustion Products: When heated to sublimation condition, emits toxic fumes of fluoride (USCG, 1999)Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
화재 가능성Certain polymerization catalysts, such as aluminum alkyls, react & burn violently on contact with water. /Aluminum alkyls/Aluminum alkyls are organic aluminum compounds that are highly reactive and dangerous because of spontaneous burning in air. /Aluminum alkyls/Prophoric material in flammable solvent. Vapors are heavier than air & may travel to a source of ignition & flash back. /Aluminum alkyls/
건강 유해성ACUTE: respiratory irritationpossible nose bleeding or vomitingCHRONIC: aggravates bronchitis/asthmaincreased bone density. (USCG, 1999)

용도

용도

Aluminum fluoride is used to produce lowmelting aluminum metal, as a flux in ceramic glazes and white enamels, and as a catalyst in chemical reactions.

일반 설명

Odorless white powder or granules. Denser than water. Solubility in water at 25°C equals 0.559 g / 100 mL.

유해성 요약
A severe eye irritantA respiratory tract irritant[HSDB] A skin, eye, and respiratory tract irritantRepeated or prolonged inhalation exposure may cause asthma. The substance may have effects on the bone, nervous system, resulting in bone alterations (fluorosis), and nervous system impairment. [ICSC] A corrosive substance that can cause injury to the skin, eyes, and respiratory tractInhalation may cause chemical pneumonitis[MSDSonline] See FLUORIDES.
반응성 그룹Salts, Basic
Special ReportsAnonInformation profiles on Potential Occupaional Hazards: Aluminum & Compounds, 2nd Draft (Revised)GRA & I Issue 21 NTIS/PB89-216238 (1989)> TD3: Information profiles are working papers used by the National Institute for Occupational Safety and Health to assist the Institute in establishing priorities. The proile summarizes data on organic and inorganic substances containing aluminum as the only metal. Each summary presents data on known and suspected health effects, the extent of worker exposure, physical and chemical properties and the industrial importance of the following aluminum compounds: aluminum metal, aluminum ammonium sulfate, aluminum chlorhydrate, aluminum chloride anhydrous, aluminum chloride hydrous, aluminum distearate, aluminum ethoxide, aluminum fluoride, aluminum hydride, aluminum hydroxide, aluminum nitrate, aluminum oxide, aluminum ortho-phosphate, aluminum potassium sulfate, aluminum silicate, aluminum sodium sulfate, aluminum sulfate, calcium aluminum silicate, diethylaluminum chloride, sodium aluminate, tri-n-butylaluminum, triethylaluminum, tri-n-hexylaluminum, triisobutylaluminum, tri-n-octylaluminum. Detailed literature searches are conducted to identify information to be used in the profile sumaries. Sponsored by National Inst. for Occupational Safety and Health, Rockville, MD.
OSHA StandardsPermissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 2.5 mg/cu m. /Fluorides, as F/Vacated 1989 OSHA PEL TWA 2 mg/cu m is still enforced in some states. /Aluminum (soluble salts & alkyls, as Al)/
Reactivity ProfileALUMINUM FLUORIDE when heated to sublimation condition, emits toxic fumes of fluoride (USCG, 1999).
Chemical DangersDecomposes on heating and under the influence of moisture. This produces toxic and corrosive fumes including hydrogen fluoride (see ICSC 0283).
Air and Water ReactionsSlightly soluble in water
소화In case of fire in the surroundings, use appropriate extinguishing media.
응급 조치Fresh air, rest. Refer for medical attention.Rinse skin with plenty of water or shower.First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .
응급 처치For acute poisoning, oral administration of limewater, intravenous infusion of glucose, and intravenous injections of calcium gluconates. (USCG, 1999)
안전 보관Dry. Well closed.
노출 관리 및 개인 보호Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift(Repeated measurements recommended.)1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]
소화 절차Stop flow of liquid before extinguishing fire. Use dry chemical or carbon dioxide. DO NOT use water as straight stream directly on spilled material. Water fog can be used to control fire. DO NOT use halogenated extinguishing agents on spilled material. Violent reaction may result. Use water spray to keep fire-exposed containers cool. Fight fire from protected location or maximum possible distance. /Aluminum Alkyls/
보관 조건Extremely reactive with air, moisture and compounds containing active hydrogen and therefore must be kept under a blanket of inert gas. /Aluminum alkyls/In general, materials ... toxic as stored or which can decompose into toxic components ... Should be stored in cool ... ventilated place, out of ... sun, away from ... fire hazard ... be periodically inspected and monitored. Incompatible materials should be isolated ...All possibility of contact with water must be avoided. Solution containing not more than 20% of these compounds in non-reactive solvents, however, can be handled without risk of spontaneous ignition. /Aluminum alkyls/Must be stored in an inert atmospheresensitive to oxidation and hydrolysis in air. /Trialkylaluminums/Separate from air, water, halocarbons, alcohols. Store in a cool, dry, well-ventilated location. Outside or detached storage is preferred. Inside storage should be in a standard flammable liquid storage warehouse, room, or cabinet. /Aluminum alkyls/
처리 방법Aluminum compounds are treated under anhydrous conditions to prevent violent reactions, recover solvent, and form Al compounds suitable for landfill by reaction with anhydrous hydrolysis agent, eg calcium hydroxide. /Aluminum compounds/SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air qualitypotential migration in soil or watereffects on animal, aquatic, and plant lifeand conformance with environmental and public health regulations.
누출 처리Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting.
Preventive MeasuresSRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.Work clothing that becomes wet or significantly contaminated should be removed and replaced. /Aluminum (soluble salts and alkyls, as Al)/Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises. /Aluminum (soluble salts and alkyls, as Al)/The worker should immediately wash the skin when it becomes contaminated. /Aluminum (soluble salts and alkyls, as Al)/SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers. Contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.
Eye PreventionWear safety goggles.
Inhalation RiskEvaporation at 20 °C is negligiblea harmful concentration of airborne particles can, however, be reached quickly.
상호 작용In the gut, antacids form insoluble compounds with numerous substances. Interactions are especially prominent with aluminum-containing antacids. Aluminum forms insoluble aluminum phosphate, which decreases the bioavailability of phosphate. Although aluminum fluoride is somewhat soluble, aluminum-containing antacids interfere with the absorption of fluoride, probably through the formation of more complex compounds, such as fluoroapatite. Aluminum-containing antacids adsorb bile acids, lysolecithin, and various proteins. /Aluminum-Containing antacids/... Pretreatment of rats with fluoride increased their sensitivity to succinylcholine, demeton and parathion. /Fluoride/
생태독성 수치LC50 Chlorella vulgaris (Green algae) 100 uM/3 daysstatic /technical product/LC50 Chlorella vulgaris (Green algae) 180 uM/15 days
유해 작용Dermatotoxin - Skin burns.
노출 경로The substance can be absorbed into the body by inhalation of dust and by ingestion.
Signs and SymptomsCough. Shortness of breath. Sore throat.Pain. Redness.Redness. Pain.
Medical SurveillanceFluoride levels in urine should be checked periodically and all workers should be subjected to periodical skeletal X-ray exam particularly of the pelvis. /Fluoride and cmpd/
Human Toxicity Excerpts/SIGNS AND SYMPTOMS/ /Anhydrous aluminum fluoride is a/ strong irritant to tissue./SIGNS AND SYMPTOMS/ Symptoms Following Exposure /to aluminum fluoride/: Acute: respiratory irritation, possible nose bleeding or vomiting: Chronic: aggravates bronchitis/ asthmaincreased bone density./SIGNS AND SYMPTOMS/ Fluorosis. Inhalation of fluoride poses a potential hazard in workers in primary aluminium production, but the majority of workers are clinically unaffected. Clinical fluorosis, which is rare, commences with stiffness in the lower back followed by pain and then limitation of rotation of the trunk. Later, the spine becomes rigid and stiff, with restriction of chest movement and of the large joints, particularly the hip, that is accompanied by osteosclerosis. /Aluminum fluorides//SIGNS AND SYMPTOMS/ Variable degrees of bony fluorosis have been seen. The first stage of this condition consists simply of an increase in bone density, particularly marked in the vertebral bodies and pelvis. As fluoride is further absorbed into bone, calcification of the ligaments of the pelvis may be seen ... In the event of extreme and protracted exposure to fluoride, calcification of the paraspinal and other ligamentous structures as well as about joints are noted. /Aluminum fluorides/For more Human Toxicity Excerpts (Complete) data for ALUMINUM FLUORIDE (12 total), please visit the HSDB record page.
Non-Human Toxicity Excerpts/LABORATORY ANIMALS: Acute Exposure/ /Acute poisoning/ if sufficient fluoride is absorbed ... Fluoride ion increases capillary permeability and also produces a coagulation defect. These actions lead to hemorrhagic gastroenteritis and hemorrhages, congestion, and edema in various organs including the brain. Clinical manifestations include excitability, muscle tremors, weakness, urination, defecation, salivation, emesis, sudden collapse, clonic convulsions, coma, and death due to respiratory and cardiac failure. Cyanosis and early rigor mortis ... /Fluoride//LABORATORY ANIMALS: Acute Exposure/ After intraperitoneal administration of a single large dose of fluoride (sodium fluoride, 35 mg/kg body weight), the calcium contents of the renal cortex and medulla of fluoride intoxicated rats were increased by 33 and 10 times, respectively. /Sodium Fluoride//LABORATORY ANIMALS: Acute Exposure/ The ionic fluoride levels in plasma following intraperitoneal administration of 15, 20, or 25 mg of fluoride per kg body weight to 200 g rats /was studied/. In animals given 25 mg/kg, the mean ionic fluoride level in plasma was 38 mg/liter after 10 min and the animals invariably died within 1 hr. All animals receiving 15 or 20 mg/kg survived, despite mean ionic fluoride levels in plasma of 22.9 and 29.2 mg/l, respectively. /Sodium Fluoride//LABORATORY ANIMALS: Acute Exposure/ The acute and subacute physiological and pathological effects of fluoride (as sodium fluoride) administered intravenously and orally to male and female dogs /were described/. When fluoride was infused intravenously in four dogs at the rate of 5.4 mg Fluoride/min, the mean acute lethal dose was 36.0 + or - 0.5 mg Fluoride/kg with death occurring after 59 to 64 minutes of infusion. The principal effects observed were a progressive decline in blood pressure, heart rate, central nervous system activity (pupil size, response to light, tendon reflexes) with vomiting and defecation. /Sodium Fluoride/For more Non-Human Toxicity Excerpts (Complete) data for ALUMINUM FLUORIDE (14 total), please visit the HSDB record page.
Populations at Special RiskPopulations that appear to be at increased risk from the effects of fluoride are individuals that suffer from diabetes insipidus or some forms of renal impairment. /Fluoride/
Evidence for CarcinogenicityA4: Not classifiable as a human carcinogen. /Aluminum metal and insouble compound/Not classifiable as a human carcinogen. /Fluorides as F/
Probable Routes of Human ExposureChronic fluorosis generally develops after prolonged (10-20 years) exposure to industrial dusts, insecticides, or water where fluorides exceed 3 to 4 ppm. This is especially true in workers involved in the production of aluminum, steel, or glass. /Aluminum fluorides/Production of aluminum sulfate and aluminum fluoride is associated with exposure to several irritant substances. Such production has been connected with reversible bronchial obstruction or asthma. In an aluminum plant in Sweden, 6 cases of asthma occurred in 1975, and 7 in 1976. The number of exposed workers was 35-40. The levels of aluminum fluoride (personal sampling) were measured during these two years, and the mean concentrations were 3-6 mg/cu m. In 1977, improvements were made at this plant thereby reducing the mean levels of aluminum fluoride to 0.4-1.0 mg/cu m. During the years 1978-1980, only two cases of asthma occurred. /Aluminum fluorides/Electrolytic production of aluminum can lead to a substantial exposure to fluorides and carcinogenic tar oils, including polyaromatic hydrocarbons. /Aluminum fluorides/Primary aluminum production plants are located in about 40 countries. The two main methods used for aluminum production are Soderberg and prebake, which encompass a number of processes and job categories. Substantial exposures to airborne polynuclear aromatic compounds have been measured in certain occupational settings in this industry. Exposures have been higher in potrooms of plants using the Soderberg process than in those using the prebake processsome workers may have exposed to both process. Exposures to fluorides and a variety of other contaminants also occur in potrooms. /Aluminum fluorides/
Antidote and Emergency Treatment/Exposure to aluminum fluoride/ dust: If inhaled, irritating to nose and throat. Move to fresh air.
State Drinking Water Standards(CA) CALIFORNIA 1000 ug/l /Aluminum/
주 식수 지침(AZ) ARIZONA 73 ug/l /Aluminum/(CA) CALIFORNIA 200 ug/l /Aluminum/(ME) MAINE 1430 ug/l /Aluminum/
연방 식수 지침EPA 50-200 ug/l /Aluminum/
수질 위해 등급(WGK)1
TSCA 등재 상태TSCA listed
RTECS 번호BD0725000
운송 번호(UN)3260
관세 코드28261210
위험 문구(R)22-36/37/38
위험 표시Xn,T,Xi
안전 문구(S)26-37/39
포장분류III
위험 등급8
기존화학 물질KE-00970
위험 참고 사항Highly Toxic/Irritant
저장 분류13 - Non Combustible Solids
유해 물질 데이터7784-18-1(Hazardous Substances Data)