1-뷰탄올, 타이타늄(4+) 염, 호모중합체(1-부탄올, 티타늄(4+) 염, 호모중합체)

Titanium tetrabutoxide

HCID 21801CAS 5593-70-4

기본 정보

표준 SMILES
CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-].[Ti+4]
InChIKey
YHWCPXVTRSHPNY-UHFFFAOYSA-N
분자식
C16H36O4Ti
평균 분자량
340.32 g/mol
단동위원소 질량
340.20930593

개요

Tetrabutyl titanate appears as a water-white to pale-yellow liquid with an alcohol-like odor. About the same density as water. Flash point 170 °F. Contact may irritate or cause burns.

이름 및 식별자

우선 이름
Titanium tetrabutoxide
IUPAC
tetrakis(butan-1-olate);titanium(4+)
현지명
테트라-n-부톡시티탄
영어명
Tetrabutyl titanate
분자식
C16H36O4Ti
분자량
340.32

이름 및 동의어

5593-70-4Titanium tetrabutoxideButyl titanateTETRABUTYL TITANATETitanium ButoxideTetrabutyltitanateTitanium butylateTetrabutyl orthotitanateOrgatics TA 25B 1 (titanate)Butyl titanate(IV)Butyl titanate monomer
이름 더 보기
n-부틸티타네이트,테트라-n-부틸티타네이트테트라-n-부톡시티탄테트라뷰틸타이타늄산테트라뷰틸타이타늄산(테트라뷰틸티탄산)테트라뷰틸타이타늄산1-뷰탄올, 타이타늄(4+) 염1-뷰탄올, 타이타늄(4+) 염 (4:1)오쏘타이타늄산 뷰틸타이타늄 테트라뷰탄올레이트타이타늄산 뷰틸 (IV) (((BuO)4Ti)타이타늄산 뷰틸 단량체타이타늄산 테트라뷰틸타이타늄산(IV) 뷰틸테트라뷰톡시 타이타늄테트라뷰톡시타이타늄TNBTTETRA-N-BUTYL TITANATEtetrabutoxytitaniumTITANIUM(IV) BUTOXIDETITANIUM(IV) N-BUTOXIDETitanium tetrabutanolate
Tyzor BPButyl orthotitanateTyzor TBTTetrabutoxy titaniumTitanium tetrabutylateTitanium, tetrabutoxy-Titanium(4+) butoxideTitanium tetrakis(butoxide)

데이터베이스 식별자

CAS
5593-70-4、9022-96-2
PubChem CID
21801
DTXSID
DTXSID6041262
UNII
FJS8Q2MX9I
EC Number
227-006-8

물성

구조 계산 물성

극성 표면적
92.2 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
4
회전 가능 결합 수
8
무거운 원자 수
21

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metal Alkoxides
OdorWEAK, ALCOHOL-LIKE ODOR
Density · 3건

0.998 at 77 °F (USCG, 1999) - Less dense than water; will float

0.998 @ 25 °C (liquid)

0.998 @25 °C

Color/Form · 2건

COLORLESS TO LIGHT-YELLOW LIQUID

Pale yellow, viscous liquid

Solubility · 2건

Sol in most organic solvents except ketones

Sol in aliphatic aromatic, chlorinated, and oxygenated solvents

Flash Point · 2건

170 °F (USCG, 1999)

170 °F (CLOSED CUP)

물리화학적 성질

녹는점
-55 °C · -55°C
끓는 점
206 °C/10 · 206 °C/10 mmHg (lit.)
밀도
1 g/mL · 1.00 g/mL at 20 °C (lit.)
증기압
5.6 hPa · 5.6 hPa (20 °C)
굴절률
20 · n20/D 1.491(lit.)
인화점
55 °F · 55 °F

화학적 성질

colourless to light yellow viscous liquid

안전 및 규제

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 6.5% (102 of 1561) of reports.

Danger

H226 (84.2%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P305+P354+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 1561 reports by companies from 46 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

유해성 정보

Regulatory Information · 4건

Chemical: 1-Butanol, titanium(4+) salt

1-Butanol, titanium(4+) salt (4:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Butanol, titanium(4+) salt (4:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 27-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/14260

1-Butanol, titanium (IV) salt: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelCorrosive Flammable Liquid
Fire HazardsCombustible. Containers may explode in fire. May give off dense white smoke. Containers may explode. (USCG, 1999)
Fire PotentialFLAMMABLE WHEN EXPOSED TO HEAT OR FLAME.
Health HazardsLIQUID: Irritating to skin and eyes. If swallowed will cause nausea and vomiting. (USCG, 1999)
Hazards Summary · 1건

Decomposed by water producing butanol and titanium dioxide; A skin, eye, and respiratory tract irritant; May cause corneal damage; [HSDB] Reacts with water forming butanol and titanium dioxide; A skin and eye irritant; [CAMEO] A skin irritant; Corrosive to eyes; [eChemPortal: ERMA] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline]

안전 및 보호

Fire FightingExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
First AidINHALATION: move from contaminated atmosphere; if symptoms of respiratory discomfort persist, see a physician.
Firefighting HazardsMAY GIVE OFF DENSE WHITE SMOKE.
Fire Fighting ProceduresEXTINGUISH WITH DRY CHEM OR CARBON DIOXIDE. DO NOT USE WATER ON FIRE. COOL EXPOSED CONTAINERS WITH WATER.
Storage Conditions · 1건

IN GENERAL, MATERIALS ... TOXIC AS STORED OR WHICH CAN DECOMP INTO TOXIC COMPONENTS ... SHOULD BE STORED IN COOL ... VENTILATED PLACE, OUT OF ... SUN, AWAY FROM ... FIRE HAZARD ... BE PERIODICALLY INSPECTED & MONITORED. INCOMPATIBLE MATERIALS SHOULD BE ISOLATED ... .

Nonfire Spill ResponseExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

독성 정보

Adverse EffectsDermatotoxin - Skin burns.
Human Toxicity Excerpts · 1건

INHALATION CAUSES NONSPECIFIC IRRITATION OF THE UPPER RESP TRACT. CONTACT WITH LIQUID MAY CAUSE CORNEAL DAMAGE IN EYES AND LOCAL IRRITATION OF SKIN. INGESTION CAUSES NONSPECIFIC IRRITATION OF GI TRACT, NAUSEA, VOMITING, CRAMPS, AND DIARRHEA; IN SEVERE CASES, CENTRAL NERVOUS SYSTEM DEPRESSION MAY RESULT.

Non-Human Toxicity Values · 2건

LD50 Rat oral 3122 mg/kg

LD50 Mouse iv 180 mg/kg

안전 데이터

wgk
1
tsca
TSCA listed
rtecs
XR1585000
ridadr
UN 1993 3/PG 3
독성
LD50 orally in Rabbit: 3122 mg/kg
HS 번호
29051900

화학 및 산업

약리 정보

BionecessityThere is no evidence that titanium is an essential element for either man or animals. /Titanium/

용도 및 제조

Uses · 4건

Used in ester exchange reactions, heat-resistant paints, medical/dental bonding compositions, and anhydrous hair set compositions; Also used as an adhesion promoter (paints, rubber, and plastics-metal), curing agent (alkyl, epoxy, and silicon resins), catalyst, and glass coating; [HSDB]

Painting (Pigments, Binders, and Biocides) [Category: Paint]

Ester exchange reactions; heat-resistant paints (up to 500 °C); improving adhesion of paints, rubber, and plastics to metal surfaces; cross linking agent; condensation catalyst

Esterification/alcoholysis catalysts; alkyl/epoxy/silicon resin crosslinking agent; Ziegler catalyst component; high temperature coatings ingredient; glass surface treatment agent

U.S. Production2023: 1,000,000 - <5,000,000 lb
Consumer UsesCatalyst
Industry UsesCatalyst
Methods of ManufacturingReaction of titanium tetrachloride with butanol.
Formulations/PreparationsGrades of Purity: Technical

응용 분야

용도Ester exchange reactions; heat-resistant paints (up to 500C); improving adhesion of paints, rubber, and plastics to metal surfaces; cross-linking agent; condensation catalyst.

일반 설명A water-white to pale-yellow liquid with an alcohol-like odor. About the same density as water. Flash point 170°F. Contact may irritate or cause burns.

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
河北创海生物科技有限公司+86-86-13131129325 · [email protected]
湖北云镁科技有限公司027-59206672 18995657604 · [email protected]

관련 반응

69건

연결된 노트

불러오는 중…