테트라-n-부톡시티탄
Titanium tetrabutoxide
기본 정보
- CAS
5593-70-4- 표준 SMILES
CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-].[Ti+4]- InChIKey
YHWCPXVTRSHPNY-UHFFFAOYSA-N- 분자식
- C16H36O4Ti
- 평균 분자량
- 340.32 g/mol
- 단동위원소 질량
- 340.2093003
개요
Tetrabutyl titanate appears as a water-white to pale-yellow liquid with an alcohol-like odor. About the same density as water. Flash point 170 °F. Contact may irritate or cause burns.
이름 및 식별자
- 우선 이름
- Titanium tetrabutoxide
- IUPAC
- tetrakis(butan-1-olate);titanium(4+)
- 현지명
- 테트라-n-부톡시티탄
- 영어명
- Tetrabutyl titanate
- 분자식
- C16H36O4Ti
- 분자량
- 340.32
이름 및 동의어
5593-70-4Titanium tetrabutoxideButyl titanateTETRABUTYL TITANATETitanium ButoxideTetrabutyltitanateTetrabutyl orthotitanateButyl titanate(IV)Titanium butylateTyzor BPButyl orthotitanateTyzor TBT
이름 더 보기
n-부틸티타네이트,테트라-n-부틸티타네이트테트라-n-부톡시티탄테트라뷰틸타이타늄산테트라뷰틸타이타늄산(테트라뷰틸티탄산)테트라뷰틸타이타늄산1-뷰탄올, 타이타늄(4+) 염1-뷰탄올, 타이타늄(4+) 염 (4:1)오쏘타이타늄산 뷰틸타이타늄 테트라뷰탄올레이트타이타늄산 뷰틸 (IV) (((BuO)4Ti)타이타늄산 뷰틸 단량체타이타늄산 테트라뷰틸타이타늄산(IV) 뷰틸테트라뷰톡시 타이타늄테트라뷰톡시타이타늄TNBTTETRA-N-BUTYL TITANATEtetrabutoxytitaniumTITANIUM(IV) BUTOXIDETITANIUM(IV) N-BUTOXIDETitanium tetrabutanolate
Tetrabutoxy titaniumOrgatics TA 25B 1 (titanate)Titanium tetrabutylateButyl titanate monomerTitanium, tetrabutoxy-Titanium(4+) butoxideTitanium tetrakis(butoxide)
데이터베이스 식별자
- CAS
5593-70-4、9022-96-2- PubChem CID
- 21801
- DTXSID
DTXSID6041262- UNII
- FJS8Q2MX9I
- EC Number
- 227-006-8
물성
구조 계산 물성
- 극성 표면적
- 92.2 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 4
- 회전 가능 결합 수
- 8
- 무거운 원자 수
- 21
- 형식 전하
- 0
- 복잡도
- 13.1
실험 및 물리화학적 성질
Chemical ClassesMetals -> Metal Alkoxides
OdorWEAK, ALCOHOL-LIKE ODOR
Density
0.998 at 77 °F (USCG, 1999) - Less dense than water; will float
0.998 @ 25 °C (liquid)
0.998 @25 °C
Color/Form
COLORLESS TO LIGHT-YELLOW LIQUID
Pale yellow, viscous liquid
Solubility
Sol in most organic solvents except ketones
Sol in aliphatic aromatic, chlorinated, and oxygenated solvents
Flash Point
170 °F (USCG, 1999)
170 °F (CLOSED CUP)
Boiling Point
593 °F at 760 mmHg (USCG, 1999)
312 °C
292.4 °C @760 [mm Hg]
DecompositionWhen heated to decomposition it emits acrid & irritating fumes.
Melting Point
-67 °F (USCG, 1999)
-55 °C
-55 °C
Vapor Density11.7 (Air= 1)
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 6.5% (102 of 1561) of reports.
Danger
H226 (84.2%): Flammable liquid and vapor [Warning Flammable liquids]
P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P305+P354+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 1561 reports by companies from 46 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Warning
유해성 정보
Regulatory Information
Chemical: 1-Butanol, titanium(4+) salt
1-Butanol, titanium(4+) salt (4:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Butanol, titanium(4+) salt (4:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
REACH registered substance: Titanium tetrabutanolate (EC: 227-006-8)
1-Butanol, titanium (IV) salt: Does not have an individual approval but may be used under an appropriate group standard
DOT LabelCorrosive Flammable Liquid
Fire HazardsCombustible. Containers may explode in fire. May give off dense white smoke. Containers may explode. (USCG, 1999)
Fire PotentialFLAMMABLE WHEN EXPOSED TO HEAT OR FLAME.
Health HazardsLIQUID: Irritating to skin and eyes. If swallowed will cause nausea and vomiting. (USCG, 1999)
Hazards Summary
Decomposed by water producing butanol and titanium dioxide; A skin, eye, and respiratory tract irritant; May cause corneal damage; [HSDB] Reacts with water forming butanol and titanium dioxide; A skin and eye irritant; [CAMEO] A skin irritant; Corrosive to eyes; [eChemPortal: ERMA] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline]
화학 및 산업
약리 정보
BionecessityThere is no evidence that titanium is an essential element for either man or animals. /Titanium/
용도 및 제조
Uses
Used in ester exchange reactions, heat-resistant paints, medical/dental bonding compositions, and anhydrous hair set compositions; Also used as an adhesion promoter (paints, rubber, and plastics-metal), curing agent (alkyl, epoxy, and silicon resins), catalyst, and glass coating; [HSDB]
Painting (Pigments, Binders, and Biocides) [Category: Paint]
Ester exchange reactions; heat-resistant paints (up to 500 °C); improving adhesion of paints, rubber, and plastics to metal surfaces; cross linking agent; condensation catalyst
Esterification/alcoholysis catalysts; alkyl/epoxy/silicon resin crosslinking agent; Ziegler catalyst component; high temperature coatings ingredient; glass surface treatment agent
U.S. Production2023: 1,000,000 - <5,000,000 lb
Consumer UsesCatalyst
Industry UsesCatalyst
Methods of ManufacturingReaction of titanium tetrachloride with butanol.
Formulations/PreparationsGrades of Purity: Technical
Household ProductsInformation on 6 consumer products that contain Titanium tetrabutanolate in the following categories is provided:
General Manufacturing Information
Petrochemical Manufacturing
1-Butanol, titanium(4+) salt (4:1): ACTIVE
IN DENTAL OR MEDICAL BONDING COMPOSITIONS
IN ANHYDROUS HAIR SET COMPOSITION
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