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초산납

Lead diacetate trihydrate

HCID 22456
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
6080-56-4
표준 SMILES
CC(=O)[O-].CC(=O)[O-].O.O.O.[Pb+2]
InChIKey
MCEUZMYFCCOOQO-UHFFFAOYSA-L
분자식
Pb(C2H3O2)2.3H2O.
평균 분자량
379 g/mol
단동위원소 질량
380.03495482

개요

Lead acetate trihydrate appears as white powder or white chunky solid. Slight odor. pH (5% aqueous solution at 77 °F) 5.5-6.5. (NTP, 1992)

이름 및 식별자

우선 이름
Lead diacetate trihydrate
IUPAC
lead(2+);diacetate;trihydrate
현지명
초산납
영어명
Lead acetate trihydrate
분자식
C4H12O7Pb
분자량
379.33

이름 및 동의어

6080-56-4Lead(II) acetate trihydrateLead diacetate trihydrateBleiazetatDTXSID3031521Acetic acid, lead(+2) salt trihydrateRefChem:1088392DTXCID501478104612-031-2CHEBI:33112LEAD ACETATE TRIHYDRATELead acetate [JAN]
이름 더 보기
납디아세트산트리수화물비스(아세트산)트리히드록시트리납아세트산,납염,트리수화물아세트산납삼수화물아세트산납(II)트리히드레이트초산납플룸보스아세트산초산납(Ⅱ)삼수화물아세트산납삼수화물리드 아세테이트납아세트산(3수화물)lead acetatLeaddiacetatetrihydrateLeadAcetatePureLeadAcetate3H2OAcsNormalleadacet-atePLATINIZING SOLUTIONLead(II) acetate triLead acetate hydrate
Plumbous Acetate TrihydrateLead acetate (II) trihydrateRX077P88RYLead acetate (JAN)Lead acetate paperLead acetate cottonlead(2+) diacetate trihydratelead diacetate-trihydrate

데이터베이스 식별자

CAS
6080-56-4
PubChem CID
22456
DTXSID
DTXSID3031521
UNII
RX077P88RY
EC Number
612-031-2

물성

구조 계산 물성보충 중

극성 표면적
83.3 Ų
수소 결합 공여자 수
3
수소 결합 수용자 수
7
회전 가능 결합 수
0
무거운 원자 수
12
형식 전하
0
복잡도
25.5

실험 및 물리화학적 성질

Chemical ClassesMetals -> Organic Acids, Metal Salts
Density · 2건

2.55 (NTP, 1992) - Denser than water; will sink

2.55 @25 °C

Solubilitygreater than or equal to 100 mg/mL at 68 °F (NTP, 1992)
Boiling Point392 °F at 760 mmHg (decomposes) (NTP, 1992)
Melting Point · 2건

167 °F (NTP, 1992)

Melting point equals 167 °F

Physical Description · 3건

Lead acetate trihydrate appears as white powder or white chunky solid. Slight odor. pH (5% aqueous solution at 77 °F) 5.5-6.5. (NTP, 1992)

Liquid

Water soluble white powder; [CAMEO]

물리화학적 성질

녹는점
75 °C · 75 °C (dec.)(lit.)
끓는 점
280 °C · 280°C
밀도
2 · 2,55 g/cm3
저장 조건
2 · 2-8°C
용해도
443 g/l · 443g/l
물리적 상태
고체
색상
흰색 또는 무색, 풍화성

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H302+H332 (43.1%): Harmful if swallowed or if inhaled [Warning Acute toxicity, oral; acute toxicity, inhalation]

P203, P260, P261, P264, P270, P271, P273, P280, P301+P317, P304+P340, P317, P318, P319, P330, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 283 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

H402: Harmful to aquatic life [Hazardous to the aquatic environment, acute hazard]

P273, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory Information · 3건

Chemical: Acetic acid, lead(2+) salt, trihydrate

Acetic acid, lead(2+) salt, trihydrate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Acetic acid, lead(2+) salt, trihydrate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Lead (II) acetate, trihydrate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Lead acetates: Human health tier II assessment
DOT LabelPoison
Fire HazardsLiterature sources indicate that this chemical is nonflammable. (NTP, 1992)
Health Hazards · 1건

SYMPTOMS: Symptoms of exposure to this compound include irritation of the skin, eyes and respiratory tract, nausea, vomiting, shock, weakness, headache, coma and death. Symptoms of mild exposure include lethargy, moroseness, constipation, flatulence and occasional abdominal pain. Advanced poisoning may cause loss of appetite, anemia and gradual paralysis of the muscles (especially in the arms). Other symptoms include metallic taste, muscle and joint pain or soreness, fine tremors, hyperactivity, colic and wrist drop. It may also cause a black or blue line on the gums, basophilic stippling on erythrocytes and, in pregnant women, tonic contractions of the uterus which may result in abortion. Exposure may cause convulsions, delirium, stupor, encephalopathy leading to blindness (due to injury to the optic nerves by pressure or direct toxic action), encrustations, opacities in previously injured corneas and optic atrophy.

화학 및 산업

용도 및 제조

Uses · 2건

Used as a cotton dye mordant, a water repellant, and as a raw material in cosmetics and to make other lead compounds; [Ullmann]

Textiles (Printing, Dyeing, or Finishing) [Category: Industry]

U.S. Production2023: 128,899 lb
Industry UsesAdsorbent
General Manufacturing InformationAll Other Basic Inorganic Chemical Manufacturing
응용 분야 · 2건

용도Lead acetate trihydrate, the usual commercial form, is used in the preparation of basic lead carbonate and lead chromate, as a mordant in cotton dyes, as a reagent for the manufacture of lead salts of higher fatty acids, as a water repellant, as a component in combined toning and fixing baths for daylight printing papers, and as a means of treating awnings and outdoor furniture to prevent removal of mildew- and rotproofing agents by rain or laundering. Other uses include preparation of rubber antioxidants; processing agent in the cosmetic, perfume, and toiletry industries; component of coloring agents for adhesives; and preparation of organic lead soaps as driers of paints and inks.

일반 설명Lead acetate trihydrate appears as white powder or white chunky solid. Slight odor. pH (5% aqueous solution at 77°F) 5.5-6.5. It is water soluble and stable under normal conditions.

상·하류 제품 정보

상류 원료

황화 수소황화 납산화납(II)루모갈리온아세트산(빙초산)

관련 반응

52건
반응 기록 만들기
HRID 27578 반응식
HRID 27578반응물로uspto-grants-1980_09
HRID 408755 반응식
HRID 408755반응물로uspto-grants-2014_06
HRID 538187 반응식
HRID 538187반응물로uspto-grants-2014_10
HRID 726418 반응식
HRID 726418반응물로uspto-grants-1998_01
HRID 750441 반응식
HRID 750441반응물로uspto-grants-2008_07
HRID 1014794 반응식
HRID 1014794반응물로uspto-grants-2011_07
HRID 1087300 반응식
HRID 1087300반응물로uspto-grants-1991_07
HRID 1095206 반응식
HRID 1095206반응물로uspto-grants-2012_03
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화합물 노트

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더보기
새 노트새 반응견적 요청하기
Specific Gravity
2.55 · 2.55
수소이온지수(pH)
5.5 · 5.5-6.5 (50g/l, H2O, 20℃)
수용성
625 g/L · 625g/L
Merck
14 · 14,5397
BRN
3730298 · 3730298
InChI
1S/2C2H4O2.3H2O.Pb/c2*1-2(3)4;;;;/h2*1H3,(H,3,4);3*1H2;/q;;;;;+2/p-2
InChIKey
DYRQFRHCGBQJII-UHFFFAOYSA-M
SMILES
O.O.O.CC(=O)O[PbH2]OC(C)=O
EPA
Lead(II) acetate trihydrate (6080-56-4)
화학적 성질 · 1건

Lead acetate trihydrate, also known as plumbous acetate trihydrate, has the chemical formula Pb(C2H3O2)2·3H2O. It appears as a white, monoclinic crystalline solid. Upon heating it loses some of its water of crystallization, and after melting, decomposes at 200 °C. The trihydrate is highly soluble in water but insoluble in ethyl alcohol. It has an intensely sweet taste, hence it is sometimes called sugar of lead, but it is poisonous. The trihydrate is made by dissolving lead monoxide in hot dilute acetic acid solution; on cooling, large crystals separate, sometimes up to 60-cm long.

Hazards SummarySee Lead and linked occupational diseases.
Reactive GroupSalts, Basic
Reactivity Profile · 1건

LEAD ACETATE TRIHYDRATE may react with acids and oxidizing agents. Is incompatible with sulfates, citrates, tartrates, chlorides, carbonates, alkalis, tannin, resorcinol, salicylic acid, phenol, chloral hydrate, sulfites, vegetable infusions and tinctures. Incompatible with phosphates (NTP, 1992). Incompatible with KBrO3 and with EDTA.

Air and Water ReactionsSlowly effloresces in air. Water soluble but solutions absorb carbon dioxide from the air and to give incompletely soluble products.
Hazard Classes and Categories · 4건

Acute Tox. 4 (71.7%)

Acute toxicity - category 4

Acute toxicity (Oral) - Category 5

Hazardous to the aquatic environment (Acute) - Category 3

안전 및 보호

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)
First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Exposure Control and Personal ProtectionBiological Exposure Indices (BEI) [ACGIH] - Lead in blood = 200 ug/L (20 ug/100 ml); sampling time not critical; [ACGIH]
Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Threshold Limit Values (TLV)0.05 [mg/m3], as Pb
Permissible Exposure Limit (PEL)0.05 [mg/m3], as Pb
Protective Action Criteria (PAC) · 3건

0.73 [mg/m3]

150 [mg/m3]

920 [mg/m3]

Personal Protective Equipment (PPE)MINIMUM PROTECTIVE CLOTHING: If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves.

독성 정보

Adverse EffectsNeurotoxin - Predominantly motor

안전 데이터

wgk
2
tsca
Yes
rtecs
OF8050000
ridadr
UN 1616 6.1/PG 3
독성
LD50 orally in Rabbit: 4665 mg/kg
HS 번호
29152900
risk_code
61-33-48/22-50/53-62
hazard_code
T,N
safety_code
53-45-60-61
포장분류
III
위험 등급
6.1
Hazard Classifications
Aquatic Acute 1Aquatic Chronic 1Carc. 2Eye Dam. 1Lact.Repr. 1ASTOT RE 1
스토리지 클래스
6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
함량 및 규제정보
물질구분: 유독물질; 혼합물(제품)함량정보: 사산화납(lead tetraoxide), 황산납(lead sulfate), 염기성탄산납(basic lead carbonate)을 제외한 납화합물(Lead compounds) 및 이를 25% 이상 함유한 혼합물. 다만, 초산납(lead acetate), 알킬화납(lead alkyls), 아지드화납(lead azide), 이초산납(lead di(acetate)), 메탄술폰산납(lead(Ⅲ) methansulfonate), 인산납(lead phosphate(3:2)), 스티핀산납(lead styphate)의 경우는 이를 0.5% 이상 함유한 혼합물
유해화학물질 필터링
97-1-9
SOD EDTA
Complexing agent
납

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