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브롬(취소)산 은

Silver bromate

HCID 22763417
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
7783-89-3
표준 SMILES
[Ag+].[O-][Br+3]([O-])([O-])[O-]
InChIKey
BVUZULNXSIDAFI-UHFFFAOYSA-N
분자식
AgBrO4
평균 분자량
251.77 g/mol
단동위원소 질량
249.80309

개요

Silver bromate is a chemical compound of silver and bromine. It is used as an oxidant for the transformation of tetrahydropyranyl ethers to carbonyl compounds. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. Silver is a metallic element with the chemical symbol Ag and atomic number 47. It occurs naturally in its pure, free form, as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite. (L808, L809, L625, L636)

이름 및 식별자

우선 이름
Silver bromate
IUPAC
silver perbromate
현지명
브롬(취소)산 은
영어명
SILVER BROMATE
분자식
AgBrHO3
분자량
236.78

이름 및 동의어

DTXSID60999042argentio bromateRefChem:886277DTXCID101426020232-032-87783-89-3Silver bromateSilver(1+) perbromateEINECS 232-032-8브롬(취소)산은브롬산 은Silver(I) bromate
이름 더 보기
Silver bromate,97%Bromic acid silver(I) saltSILVER BROMATE ISO 9001:2015 REACHSILVER BROMATE, 97%SILVER BROMATE, 97%SILVER BROMATE, 97%

데이터베이스 식별자

CAS
7783-89-3
PubChem CID
22763417
DTXSID
DTXSID60999042
EC Number
232-032-8

물성

구조 계산 물성

극성 표면적
74.3 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
4
회전 가능 결합 수
0
무거운 원자 수
6
형식 전하
0
복잡도
95.8

물리화학적 성질

밀도
5.206 g/mL · 5.206 g/mL at 25 °C(lit.)
물리적 상태
백색 정방형 결정
색상
white tetragonal crystals, crystalline
수용성
100 g · g/100g 용액 H2O: 0.193(25°C), 1.325(90°C) [KRU93]

화학적 성질

White powder and lumps

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 4건

Danger

H272 (100%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesOx. Sol. 2 (100%)

독성 정보

Treatment · 1건

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1건

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. Bromate is also a potential carcinogen. Exposure to high levels of silver for a long period of time may result in a condition called arygria, a blue-gray discoloration of the skin and other body tissues. Argyria is a permanent effect but does not appear to be harmful to health. While silver itself is not toxic, most silver salts are, and may damage the liver, kidney, and central nervous system, as well as be carcinogenic. (L808, L809, L810, L625, L626, L627, L638)

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. Silver compounds can also be absorbed orally and dermally. It distributes throughout the body in the blood, particularily to the liver. Insoluble silver salts are transformed into soluble silver sulfide albuminates, bind to amino or carboxyl groups in RNA, DNA, and proteins, or are reduced to metallic silver by ascorbic acid or catecholamines. Metallic silver is oxidized and may deposit in the tissues, causing arygria. Silver is eliminated primarily in the faeces. (L808, L626)

용도 및 제조

UsesSilver bromate is used as an oxidant for the transformation of tetrahydropyranyl ethers to carbonyl compounds. (L636)

응용 분야

용도Silver bromate is useful oxidant for the transformation of tetrahydropyranyl ethers to carbonyl compounds.1

상·하류 제품 정보

상류 원료

황산은

하류 제품

브롬산

공급사8 곳

上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
上海景颜化工科技有限公司13817811078 · [email protected]

관련 반응

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화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1건

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. Metallic silver is oxidized and may deposit in the tissues, causing arygria. The silver ion is known to inhibit glutathione peroxidase and NA+,K+-ATPase activity, disrupting selenium-catalyzed sulfhydryl oxidation-reduction reactions and intracellular ion concentrations, respectively. Silver nanoparticles are believed to disrupt the mitochondrial respiratory chain, causing oxidative stress, reduced ATP synthesis, and DNA damage. (L808, A243, A244, A245, A246, L626, L627, A543)

Signs and Symptoms · 1건

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. Exposure to high levels of silver for a long period of time may result in a condition called arygria, a blue-gray discoloration of the skin and other body tissues. Argyria is a permanent effect but does not appear to be harmful to health. Exposure to high levels of silver in the air has resulted in breathing problems, lung and throat irritation, and stomach pains. Skin contact with silver can cause mild allergic reactions such as rash, swelling, and inflammation in some people. (L808, L626, L627)

Carcinogen ClassificationPotassium bromate: 2B, possibly carcinogenic to humans. (L135)

안전 데이터

wgk
3
ridadr
UN 1450 5.1/PG 2
HS 번호
28432900
risk_code
8-36/37/38
hazard_code
O,Xi
safety_code
17-26-36
포장분류
II
위험 등급
5.1
기존화학 물질
KE-31263
F 고인화성물질
8
함량 및 규제정보
물질구분: 유독물질; 혼합물(제품)함량정보: 무기은 염류 및 이를 25% 이상 함유한 혼합물. 다만, 염화 은(Silver chloride) 및 뇌산 은(Silver fulminate)은 제외
유해화학물질 필터링
97-1-92
赛默飞世尔科技(中国)有限公司
800-810-5118 · [email protected]
Shaanxi Didu New Materials Co. Ltd+86-86-17392712779 +86-13289823923 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
陕西缔都医药化工有限公司029-029-029-81148696 18161915376 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]