CAS 21324-40-3 Lithium hexafluorophosphate (HCID 23688915)

이름 및 식별자

우선 이름: Lithium hexafluorophosphate
IUPAC: lithium hexafluorophosphate
현지명: 리튬 포스포헥사플루오르화
영어명: Lithium hexafluorophosphate
분자식: F6LiP
분자량: 151.91

이름 및 동의어

Lithium hexafluorophosphate21324-40-3Lithium hexafluorophosphate(V)LiPF6lithium,hexafluorophosphatelithium;hexafluorophosphatePhosphate(1-), hexafluoro-, lithiumT9T8DY51J3Lithium hexafluorophosphate(1-)MFCD00011096UNII-T9T8DY51J3Phosphate(1-), hexafluoro-, lithium (1:1)

이름 더 보기

리튬 포스포헥사플루오르화플루오르화 리튬 인 (LiPF6)플루오인산 리튬헥사플루오로인산 리튬헥사플루오로인산 리튬 (LiPF6)헥사플루오로인산(1-) 리튬헥사플루오로인산(1-) 리튬 (1:1)리튬헥사플루오로포스페이트1.0 M LiPF6 DMCPurelytePowerlyte1.0 M LiPF6 PC1.0 M LiPF6 DEC1.0 M LiPF6 EMC1.0 M LiPF6 MEC1.0 M LiPF6 EC/DMC

EINECS 244-334-7Lithium hexafluorophosphate (Battery Grade)EC 244-334-7F6LiPLithium phosphorus fluorideLithiumhexafluorophosphate(V)hexafluorophosphate lithium saltDTXSID2066698

데이터베이스 식별자

CAS: 21324-40-3
PubChem CID: 23688915
DTXSID: DTXSID2066698
ChEBI: CHEBI:172376
UNII: T9T8DY51J3
EC Number: 244-334-7

물성

구조 계산 물성

극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 7
회전 가능 결합 수: 0
무거운 원자 수: 8
형식 전하: 0
복잡도: 67

실험 및 물리화학적 성질

Density1.5 @25 °C

Melting Point200 °C

Physical Description · 2건

Liquid; CBI; Other Solid; Dry Powder

White to almost white hygroscopic powder; [Acros Organics MSDS]

물리화학적 성질

녹는점: 200 °C · 200 °C (dec.) (lit.)
끓는 점: 90 °C · 90°C
밀도: 1.5 g/mL · 1.5 g/mL (lit.)
인화점: 25 °C · 25 °C
저장 조건: Inert atmosphere,Room Temperature
용해도: 2 O: · H2O: 약간 용해됨(lit.)
물리적 상태: 가루
Specific Gravity: 1.5 · 1.50
색상: 50 · APHA: <50
수용성: 녹는
안정성: 안정적이지만 물이나 습한 공기에 노출되면 쉽게 가수분해됩니다. 강한 산화제, 강산과 호환되지 않습니다.
InChI: 1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1
InChIKey: AXPLOJNSKRXQPA-UHFFFAOYSA-N
SMILES: [Li+].F[P-](F)(F)(F)(F)F
EPA: Phosphate(1-), hexafluoro-, lithium (21324-40-3)

화학적 성질

white crystalline powder

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H301 (79.7%): Toxic if swallowed [Danger Acute toxicity, oral]；H302 (20.3%): Harmful if swallowed [Warning Acute toxicity, oral]；H311 (16.2%): Toxic in contact with skin [Danger Acute toxicity, dermal]；H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H318 (69.9%): Causes serious eye damage [Danger Serious eye damage/eye irritation]；H372 (81.8%): Causes damage to organs through prolonged or repeated exposure [Danger Specific target organ toxicity, repeated exposure]

P260, P262, P264, P264+P265, P270, P280, P301+P316, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P361+P364, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 296 reports by companies from 22 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 4건

Chemical: Phosphate(1-), hexafluoro-, lithium

Phosphate(1-), hexafluoro-, lithium (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phosphate(1-), hexafluoro-, lithium (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 02-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13201

Hazards SummaryCauses burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Harmful by ingestion; Toxic by skin absorption; [Acros Organics MSDS] See FLUORIDES.

Hazard Classes and CategoriesAcute Tox. 3 (79.7%)；Acute Tox. 4 (20.3%)；Acute Tox. 3 (16.2%)；Skin Corr. 1A (100%)；Eye Dam. 1 (69.9%)；STOT RE 1 (81.8%)

안전 및 보호

Exposure Control and Personal Protection · 2건

Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)

1.0 [mg/m3], inhalable fraction, as F (0.2 mg/m3, inhalable fraction, as Li)[German Research Foundation (DFG)]

Threshold Limit Values (TLV)2.5 [mg/m3], as F

Permissible Exposure Limit (PEL)2.5 [mg/m3], as F

Protective Action Criteria (PAC) · 3건

0.90 [mg/m3]

9.9 [mg/m3]

59 [mg/m3]

Immediately Dangerous to Life or Health (IDLH)250.0 [mg/m3], as F

독성 정보

Adverse EffectsDermatotoxin - Skin burns.；Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.

규제 정보

Regulatory Information · 4건

Chemical: Phosphate(1-), hexafluoro-, lithium

Phosphate(1-), hexafluoro-, lithium (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phosphate(1-), hexafluoro-, lithium (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 02-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13201

안전 데이터

wgk: 3
tsca: TSCA listed
ridadr: UN 3260 8/PG 1
HS 번호: 28269020
risk_code: 34-24-22-37-10-48/23/24/25-35-11
hazard_code: C,Xi,T,F
safety_code: 26-36/37/39-45-28A-16
포장분류: II
위험 등급: 8
기존화학 물질: KE-22564
F 고인화성물질: 3-10
위험 참고 사항: Irritant/Hygroscopic
Hazard Classifications: Acute Tox. 3 OralSkin Corr. 1ASTOT RE 1 Inhalation
스토리지 클래스: 6.1B - Non-combustible acute toxic Cat. 1 and 2very toxic hazardous materials

화학 및 산업

용도 및 제조

U.S. Production2023: 10,000,000 - <25,000,000 lb；2022: 8,500,000 - <10,000,000 lb；2021: 4,000,000 - <5,500,000 lb；2020: 1,000,000 - <5,000,000 lb

Consumer UsesIon exchange agent；Conductive agent

Industry UsesConductive agent；Ion exchange agent

General Manufacturing Information · 2건

Services；Other (requires additional information)；All Other Chemical Product and Preparation Manufacturing；Transportation Equipment Manufacturing；Electrical Equipment, Appliance, and Component Manufacturing

Phosphate(1-), hexafluoro-, lithium (1:1): ACTIVE

응용 분야 · 2건

용도Lithium hexafluorophosphate (LiPF6) is the most widely used solute in liquid and gelled-type electrolytes，which has good solubility in various solvents such as PC (propylene carbonate) .

일반 설명Lithium hexafluorophosphate solution in ethylene carbonate and ethyl methyl carbonate is a class of electrolytic solution that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.