22537-61-7[Np]LFNLGNPSGWYGGD-UHFFFAOYSA-NNeptunium atom is an actinoid atom and a f-block element atom.
22537-61-7、22541-66-8、22578-82-1、7439-99-8DTXSID5074840CHEBI:33387안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
Neptunium is toxic after ingestion or inhalation. Some of the isotopes also have a small risk of generating significant external radiation (Np-236 and Np-237). [Argonne] Most Important Radionuclide: Np-237 Half-Life: 2.1 million years Effective Half-Life: 200 years Specific Activity: 0.00071 Ci/g Decay Mode: Alpha GI Absorption: 0.05% Lung Clearance Half-Time: Weeks (10-100 days) for all compounds; Critical Organ: Bone Internal Toxicity: Very High Annual Limit on Intake: 0.000004 mCi Average Radiation Energy (MeV): Alpha 4.8; Beta 0.070; Gamma 0.035 [Argonne] [See Glossary for references.] See Radiation, ionizing.
Neptunium is usually produced in nuclear reactors as a byproduct of plutonium production. There are no commercial uses, but Np-237 has been used in instruments to detect neutrons. Of the 17 known isotopes, Np-237 is the most prevalent at DOE sites such as Hanford. [Argonne]
출처At one time, neptunium’s entire existence was synthesized by man. Sometime later, in themid-twentieth century, it was discovered that a very small amount is naturally produced inuranium ore through the actions of neutrons produced by the decay of uranium in the orepitchblende. Even so, a great deal more neptunium is artificially produced every year than everdid or does exist in nature. Neptunium is recovered as a by-product of the commercial productionof plutonium in nuclear reactors. It can also be synthesized by bombarding uranium-238with neutrons, resulting in the production of neptunium-239, an isotope of neptunium witha half-life of 2.3565 days.
역사Neptunium was first discovered in 1940 by Edwin Mattison McMillan and Philip Abelson during their research on nuclear fission. It is a decay product of uranium. When a uranium target is bombarded with slow neutrons, the target subsequently emits unusual beta rays, indicating the presence of a new isotope, thus generating its most famous isotope—neptunium-239.
용도The most important radioactive isotope of neptunium is Neptunium-237, with a half-lifeof 2.144×10+6years, or about 2.1 million years, and decays into protactinium-233 throughalpha decay. Neptunium’s most important use is in nuclear research and for instrumentsdesigned to detect neutrons.
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silvery metal; α: ortho-rhomb, a=0.4721 nm, b=0.4888 nm, c=0.6661nm, stable from room temp to 280°C; β: tetra, a=0.4895 nm, c=0.3386nm, stable from 280–577°C; γ: a=0.3518 nm; bcc, stable from 577–637°C; enthalpy of vaporization 418 kJ/mol; enthalpy of fusion 3.20 kJ/mol; 237Np, t1/2=2.14×10+6 years, t1/2 of 236Np 1.29×10+6 years; discovered in 1940; produced in kg amounts as a by-product of plutonium production [MER06] [KIR78] [CRC10]
생산 방법Neptunium-237 is obtained as a by-product of making plutonium from uranium isotopes in nuclear reactors. Significant amounts of this element may be recovered from plutonium plant nuclear wastes. Both the recovery and purification of neptunium can be carried out by various chemical processes, including precipitation, solvent extraction and ion exchange. Neptunium-237 may be synthesized by bombarding uranium-235 or uranium-238 with neutrons: Neptunium-239 may be obtained from uranium-238 by neutron bombardment as it was first produced: Neptunium may be prepared in the metallic state by the reduction of its trifluoride with barium vapor at 1,200°C followed by rapid cooling. Its tetrafluoride may be reduced with excess calcium metal at about 750°C under argon atmosphere.
정의A radioactive transuranic element having atomic number 93, first formed by bombarding uranium with high-speed deuterons aw 237.0482, valences of 3, 4, 5, 6; d 20.45. Neptunium-237, the longest-lived of the 11 isotopes, has been found naturally in extremely small amounts in uranium ores. It is produced in weighable amounts as a by-product in the production of plutonium.