식별자 및 물리적 특성
| CAS No. | 13598-57-7 |
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| 분자식 | Y |
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| 평균 분자량 | 88.9058 g/mol |
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| 단동위원소 질량 | 88.9058483 g/mol |
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| SMILES | [Y] |
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| InChIKey | VWQVUPCCIRVNHF-UHFFFAOYSA-N |
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| PubChem CID | 23993 |
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| ChEMBL | CHEMBL4650626 |
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| ChEBI | CHEBI:49978 |
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| EC No. | 231-174-8 |
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| DTXSID | DTXSID0049816 |
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화학 및 물리적 성질
| 극성 표면적 | 0 |
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| 수소 결합 공여자 수 | 0 |
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| 수소 결합 수용자 수 | 0 |
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| 회전 가능 결합 수 | 0 |
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| 무거운 원자 수 | 1 |
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| 형식 전하 | 0 |
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| 복잡도 | 0 |
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| 물질 분류 | Metals -> Rare Earth Metals |
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| SpringerMaterials Properties | electron density of states |
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| 냄새 | Odorless |
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| 밀도 | 4.47 (NIOSH, 2024) - Denser than waterwill sink4.47 g/cu cm4.47 @25 °C |
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| Color/Form | Iron-gray, lustrous powderdarkens on exposure to lightHexagonal, silvery-metallic colored element...gray-black when finely divided. Brittle...harder than zinc. |
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| 용해도 | Soluble in hot H2O (NIOSH, 2024)Decomposes in waterSoluble in dilute acids and potassium hydroxide solutionSoluble in hot H2O |
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| 끓는 점 | 5301 °F at 760 mmHg (NIOSH, 2024)3345 °C3345 °C @760 [mm Hg] |
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| 녹는점 | 2732 °F (NIOSH, 2024)1522 °C1526 °C |
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| 증기압 | 0 mmHg (approx) (NIOSH, 2024)6.66X10-11 Pa at 1000 K2.96x10-7 Pa at 1200 K1.17x10-4 Pa at 1400 K1.02x10-2 Pa at 1600 K0.316 Pa at 1800 K4.27 Pa at 2000 K35.9 Pa at 2200 K |
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| Physical Description | Soft silvery-white metal in bulk. Dark-gray to black odorless powder. Mp: 1509 °Cbp 2927 °C. Density: 4.47 g cm-3 at 20 °C. May irritate the respiratory tract if inhaled as a powder. May irritate the digestive tract if swallowed. Vapors may cause dizziness or suffocation.Dark-gray to black, odorless solid[CAMEO] Some compounds, e.g., nitrates, are soluble in water[ACGIH]Dark-gray to black, odorless powder. Soft silvery-white metal in bulk.Dark-gray to black, odorless solid. |
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| Other Experimental Properties | Natural yttrium contains but one isotope, yttrium-89. Forty-three other unstable isotopes and isomers have been characterized.Oxidizes on heating in air or oxygendecomposes on cold water slowly, in boiling water rapidly.Known only in the tripositive stateHeat of fusion = 11.43 kJ/molHeat of sublimation = 424.7 kJ/mol at 25 °CStandard enthalpy of formation at 298.15 K, 0.0 kJ/mol (crystal)entropy at 298.15 K, 44.4 J/mol-K (crystal)Heat capacity, 26.5 J/mol-K (crystal)Standard enthalpy of formation at 298.15 K, 421.3 kJ/mol (gas phase)Gibbs free energy of formation, 381.1 kJ/mol (gas phase)entropy at 298.15 K, 179.5 J/mol-K (gas phase)Heat capacity 25.9 J/mol-K (gas phase). |
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안전 및 규제
| GHS 분류 | This chemical does not meet GHS hazard criteria for 56.8% (180 of 317) of all reports.DangerH228 (31.2%): Flammable solid [Danger Flammable solids]P210, P222, P231, P233, P240, P241, P261, P264, P270, P271, P273, P280, P301+P317, P302+P335+P334, P302+P352, P304+P340, P317, P321, P330, P362+P364, P370+P378, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 317 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Warning |
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| 규제 정보 | Status: Active Update: 12-12-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/22904Yttrium, powder: Does not have an individual approval but may be used under an appropriate group standard |
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| 운송 라벨(DOT) | Flammable Solid |
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| 화재 위험 | Excerpt from ERG Guide 133 [Flammable Solids]: |
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| 건강 유해성 | Excerpt from NIOSH Pocket Guide for Yttrium: |
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| 유해성 요약 | TLV Basis: pulmonary fibrosis in rats after single intratracheal administration of a very large doseIn animal studies, it is moderately toxic by the intraperitoneal routeA dose of 50 mg/kg caused hepatic necrosis. Workers producing yttrium europium vanadate phosphor and inhaling an average of 1.4 mg/m3 complained of irritation of the skin, eyes and respiratory tractThis effect was attributed to vanadium. [ACGIH] See the radionuclide, Yttrium-90. See RARE EARTH METALS and linked occupational diseases. |
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| 반응성 그룹 | Metals, Elemental and Powder, Active |
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| Reactivity Alerts | Strong Reducing Agent |
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| Reactivity Profile | YTTRIUM in bulk is stable in air due to the formation of oxide films. Powder or dust is light-sensitive and air-sensitive and flammable in the air and (Hazardous Chemicals Desk Reference, p. 861 (1987)). Reacts with water to form gaseous hydrogen (H2). Reacts with strong oxidizing agents, strong acids, strong bases, and halogens. The products of these reactions are irritating and toxic. |
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| Flammable Limits | Noncombustible Solid in bulk form. |
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