모노황산 납

Lead sulfate

HCID 24008CAS 15739-80-7

기본 정보

표준 SMILES
O=S(=O)([O-])[O-].[Pb+2]
InChIKey
KEQXNNJHMWSZHK-UHFFFAOYSA-L
분자식
PbSO4
평균 분자량
303 g/mol
단동위원소 질량
303.92838158

개요

Lead sulfate appears as a white crystalline solid. Insoluble in water and sinks in water. Contact may irritate skin, eyes, and mucous membranes. May be mildly toxic by ingestion, inhalation and skin absorption. Used to make other chemicals. Use: in lithography, battery acid solution treated fabrics, used in varnishes.

이름 및 식별자

우선 이름
Lead sulfate
IUPAC
lead(2+) sulfate
현지명
모노황산 납
영어명
LEAD(II) SULFATE
분자식
O4PbS
분자량
303.26

이름 및 동의어

LEAD SULFATELead sulphateAnglisliteanglesiteMulhouse WhiteLead BottomsLead monosulfateFast WhiteMilk WhiteNatural anglesiteFreemans White LeadLead(+2) sulfate
이름 더 보기
모노황산납납모노황산염황산납C.I.염료화이트3안젤리시트황산납모노황산납3% 이상의 유리산을 가진 황산납(DOT)CI 염료 흰색 3UN1794(DOT)염료 흰색 3황산 납ci77630milkwhitec.i.77630fastwhiteC.I. 77630Bleisulfat
Tetrabasic lead sulfateSulfate de plombTS 100 (sulfate)Lead(II) Sulfate (1:1)Lead sulfate, tetrabasicHB 2000CI 77630PbSO4

데이터베이스 식별자

CAS
15739-80-7、52732-72-6、7446-14-2、90583-07-6
PubChem CID
24008
DTXSID
DTXSID50883502
UNII
C516H654O8
EC Number
231-198-9、239-831-0、258-142-6、292-204-3
Nikkaji
J3.738I

물성

구조 계산 물성

극성 표면적
88.6 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
4
회전 가능 결합 수
0
무거운 원자 수
6

실험 및 물리화학적 성질

Chemical Classes · 2건

Metals -> Lead Compounds, Inorganic

Carcinogens

Density · 3건

6.2 at 68 °F (USCG, 1999) - Denser than water; will sink

6.2 g/cu cm

6.2 @25 °C

Color/Form · 2건

White, heavy crystal powder

White monoclinic or rhombic crystals

Solubility · 3건

In water, 0.0404 g/100 mL at 25 °C; slightly soluble in alkaline solutions.

Soluble in about 2225 parts water; more soluble in nitric acid; soluble in sodium hydroxide, ammonium acetate or tartrate solution; soluble in concentrated hydriodic acid; insoluble in alcohol.

In water, 32 mg/L at 15 °C

DecompositionWhen heated to decomposition it emits very toxic fumes /of lead and sulfur oxides./
Melting Point · 3건

2138 °F (USCG, 1999)

1170 °C

1087 °C

물리화학적 성질

녹는점
1170 °C · 1170 °C
밀도
6.2 g/mL · 6.2 g/mL at 25 °C(lit.)
용해도
insoluble in acid solutions; slightly soluble in alkaline solutions
물리적 상태
분말/덩어리
Specific Gravity
6.2 · 6.2
색상
하얀색

화학적 성질

white crystals or powder

안전 및 규제

GHS 분류

GHS Classification · 6건

Danger

H302+H332 (59.1%): Harmful if swallowed or if inhaled [Warning Acute toxicity, oral; acute toxicity, inhalation]

P203, P260, P261, P264, P270, P271, P273, P280, P301+P317, P304+P340, P317, P318, P319, P330, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 215 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H351: Suspected of causing cancer [Warning Carcinogenicity]

유해성 정보

Regulatory Information · 6건

Chemical: Sulfuric acid, lead(2+) salt (1:1)

Chemical: Sulfuric acid, lead salt

Chemical: Sulfuric acid, lead salt, tetrabasic

Sulfuric acid, lead(2+) salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, lead(2+) salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Sulfuric acid, lead salt, tetrabasic is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, lead salt, tetrabasic are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Sulfuric acid, lead salt (1:?) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, lead salt (1:?) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Other Safety Information · 3건

IMAP assessments - Selected lead-based pigments: Human health tier II assessment

IMAP assessments - Selected lead-based pigments: Human health tier II assessment

IMAP assessments - Selected lead-based pigments: Human health tier II assessment

DOT LabelCorrosive
Fire Hazards · 2건

Special Hazards of Combustion Products: Toxic metal fumes (USCG, 1999)

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Fire PotentialNot flammable
Health Hazards · 2건

INHALATION: Joint and muscle pains, headache, dizziness and insomnia. Weakness, frequently of extensor muscles of hand and wrist (unilateral or bilateral). Heavy contamination. Brain damage. Stupor progressing to coma - with or without convulsion, often death. Excitation, confusion, and mania less common. Cerebrospinal pressure may be increased. EYES: Caused a moderat purulent reaction and general inflammation of the rabbit eye. INGESTION: Abdominal pain, diarrhea, constipation, loss of appetite, muscular weakness, headache, blue line on gums, metallic taste, nausea and vomiting. (USCG, 1999)

· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.

안전 및 보호

Fire FightingExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2건

Get medical aid.

General First Aid:

Exposure Control and Personal Protection · 2건

· Wear positive pressure self-contained breathing apparatus (SCBA).

Biological Exposure Indices (BEI) [ACGIH] - Lead in blood = 200 ug/L (20 ug/100 ml); sampling time not critical; [ACGIH]

Fire Fighting Procedures · 3건

If material involved in fire: Extinguish fire using agent suitable for type of surrounding fire (material itself does not burn or burns with difficulty). Use water in flooding quantities as fog. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible.

Use water in flooding quantities as fog. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. /Lead sulfate (containing more than 3% free acid)/

Lead sulfate is not combustible. Use dry chemical, carbon dioxide, water spray, or foam extinguishers ... If material or contaminated runoff enters waterways, notify downstream health and fire officials and pollution control agencies. From a secure, explosion-proof location, use water spray to cool exposed containers. If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure position.

Storage Conditions · 1건

Lead sulfate must be stored to avoid contact with oxidizers (such as perchlorates, peroxides, permanganates, chlorates, and nitrates) and chemically active metals (such as potassium, sodium, magnesium, and zinc) since violent reactions occur ... A regulated, marked area should be established with this chemical is handled, used, or stored ...

독성 정보

TreatmentLead poisoning is usually treated with chelation therapy using DMSA, EDTA, or dimercaprol. (L21)
Health Effects · 1건

Lead is a neurotoxin and has been known to cause brain damage and reduced cognitive capacity, especially in children. Lead exposure can result in nephropathy, as well as blood disorders such as high blood pressure and anemia. Lead also exhibits reproductive toxicity and can results in miscarriages and reduced sperm production. (L21)

Ecotoxicity Values · 5건

LC50; Species: Chlorella pyrenoidosa (Green algae, strain No. 366); Conditions: freshwater, static, 24 °C, pH 6.5; Concentration: 25 ug/L for 14 days /100% purity/

LC50; Species: Daphnia magna (Water flea, <24 hr neonate); Conditions: freshwater, static, pH 7.5-9.1; Concentration: 392 ug/L for 48 hr /100% purity finely ground dust/

LC50; Species: Daphnia magna (Water flea, <24 hr neonate); Conditions: freshwater, static, pH 7.5-9.1; Concentration: 3166000 ug/L for 48 hr /as total lead ion/

LC50; Species: Cynoglossus joyneri (Red Tongue Sole, larvae); Conditions: saltwater, static; Concentration: 1000 ug/L for 72 hr /total lead ion/

For more Ecotoxicity Values (Complete) data for LEAD SULFATE (7 total), please visit the HSDB record page.

Environmental Fate · 3건

TERRESTRIAL FATE: It was reported that after adding 3,000-4,000 mg/kg of lead in the form of PbSO4 to soil, subsequent extractions revealed that the lead sulfate was rapidly transformed to other lead compounds in the soil(1).

AQUATIC FATE: If released into water, lead sulfate will mostly precipitate out due to its low solubility. (SRC)

ATMOSPHERIC FATE: In the atmosphere, lead most likely exists primarily as PbSO4 and PbCO3 and is deposited onto soil as lead sulfates and lead carbonates(1). Lead sulfate is a major species of lead in the atmosphere, either being emitted in that form or possibly being formed from the sulfide or other lead species with atmospheric SO2 and oxygen. Lead sulfate is expected to exist solely in the particulate phase in the ambient atmosphere, and will be subject to washout and gravitational settling. Transformations in the atmosphere to the carbonate and oxide may be expected(2).

Adverse EffectsNeurotoxin - Predominantly motor
Exposure RoutesOral (L136) ; inhalation (L136); dermal (L136)

규제 정보

RCRA Requirements · 2건

D008; A solid waste containing lead may or may not become characterized as a hazardous waste when subjected to the Toxicity Characteristic Leaching Procedure listed in 40 CFR 261.24, and if so characterized, must be managed as a hazardous waste. /Lead/

The Environmental Protection Agency is ... /promulgated/ regulations concerning ground-water monitoring with regard to screening suspected contamination at land based hazardous waste treatment, storage, and disposal facilities. ... /There are/ new requirements to analyze for a specified core list of chemicals plus those chemicals specified by the Regional Administrator on a site-specific basis. ... /Total lead (all species) is included on this list./ /Total lead (all species)/

Atmospheric Standards · 2건

National primary and secondary ambient air quality standards for lead and its compounds, measured as elemental lead by a reference method based on appendix G to this part, or by an equivalent method, are: 1.5 micrograms per cubic meter, maximum arithmetic mean averaged over a calendar quarter. /Lead and its compounds, as Pb/

Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Lead compounds are included on this list. /Lead compounds/

CERCLA Reportable Quantities · 1건

Persons in charge of vessels or facilities are required to notify the National Response Center (NRC) immediately, when there is a release of this designated hazardous substance, in an amount equal to or greater than its reportable quantity of 10 lb or 4.54 kg. The toll free number of the NRC is (800) 424-8802. The rule for determining when notification is required is stated in 40 CFR 302.4 (section IV. D.3.b).

Clean Water Act Requirements · 2건

Lead sulfate is designated as a hazardous substance under section 311(b)(2)(A) of the Federal Water Pollution Control Act and further regulated by the Clean Water Act Amendments of 1977 and 1978. These regulations apply to discharges of this substance. This designation includes any isomers and hydrates, as well as any solutions and mixtures containing this substance.

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Lead and compounds/

State Drinking Water Standards(AZ) ARIZONA 50 ug/L /Lead/
State Drinking Water Guidelines · 2건

(AZ) ARIZONA 20 ug/L /Lead/

(ME) MAINE 10 ug/L /Lead/

안전 데이터

wgk
3
tsca
TSCA listed
rtecs
OG4375000
ridadr
UN 1794 (LEAD SULPHATE with more than 3 % free acid)
HS 번호
28332960
risk_code
61-20/22-33-50/53-62

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Lead is absorbed following inhalation, oral, and dermal exposure. It is then distributed mainly to the bones and red blood cells. In the blood lead may be found bound to serum albumin or the metal-binding protein metallothionein. Organic lead is metabolized by cytochrome P-450 enzymes, whereas inorganic lead forms complexes with delta-aminolevulinic acid dehydratase. Lead is excreted mainly in the urine and faeces. (L136)

Absorption, Distribution and Excretion · 1건

... The lead content on the skin surface of 10 lead-battery workers was measured by the method of skin stripping, and urinary lead content of rats was measured with epicutaneous application of four lead compounds: lead sulfate, lead oxide, lead powder, and lead stearate. There were significant amounts of lead on the 9th and 10th skin strippings of the dorsal hand and the back of lead workers. The amount of lead on the dorsal hand was significantly correlated with the amount in the blood (n = 10, r 2 = 0.66, p < 0.05, linear regression). In rats, after lead compounds were applied for 12 days, total lead amount in urine significantly increased to 146.0 +/- 6.4 ng (SD) for lead stearate, 123.1 +/- 7.2 ng for lead sulfate, 115.9 +/- 5.3 ng for lead oxide, 47.8 +/- 6.9 ng for lead powder, and 10.3 ng for the control, which indicated significant skin absorption. It was concluded that significant amounts of inorganic lead compounds can be absorbed through the skin, and skin protection in lead-working or any contaminated environment should be carefully considered.

용도 및 제조

Uses · 6건

Used to stabilize clay soils, and to weight fabrics; Also used in galvanic batteries and rapidly drying varnishes; Has been used in lithography and with silver bromide in photography; [HSDB] Used in storage batteries and paint (pigment); [Hawley] Workers are exposed in mines and smelters and during production of lead storage batteries; [HSDB]

Battery Manufacturing [Category: Industry]

Has been used in photography in combination with silver bromide and is used in the stabilization of clay soil for adobe structures, in earth-fill dams, and roads.

Instead of white lead as pigment; with zinc in galvanic batteries; manuf minium, in lithography; preparing rapidly drying oil varnishes; weighting fabrics.[The Merck Index, Fourteenth Edition (2006)

Storage batteries, paints, ceramics, pigments, electrical and other vinyl compounds requiring high heat stability.

Lead sulphate is found in lead-acid batteries. (L416)

U.S. Production · 4건

2023: 100,000,000 - <500,000,000 lb

2023: 10,953,825 lb

2023: 178,623,686 lb

Production volume for non-confidential chemicals reported under the 2006 Inventory Update Rule. Chemical: Sulfuric acid, lead(2+) salt (1:1). Aggreated National Production Volume: 500 million to <1 billion pounds.

Consumer Uses · 3건

Chemical reaction regulator

Intermediate

Intermediate

Industry Uses · 3건

Intermediate

Other

Intermediate

Methods of Manufacturing · 2건

Treating lead oxide, hydroxide, or carbonate with warm sulfuric acid, or by treating a soluble lead salt with sulfuric acid.

Interaction of solutions of lead nitrate and sodium sulfate.

General Manufacturing Information · 6건

Other (requires additional information)

Electrical Equipment, Appliance, and Component Manufacturing

Electrical Equipment, Appliance, and Component Manufacturing

Sulfuric acid, lead(2+) salt (1:1): ACTIVE

Sulfuric acid, lead salt (1:?): ACTIVE

Sulfuric acid, lead salt, tetrabasic: ACTIVE

응용 분야 · 2건

용도Lead(II) sulfate is used in pigments, galvanic batteries, lithography, weighting fabrics. It is also used as intermediates.

일반 설명A white crystalline solid. Insoluble in water and sinks in water. Contact may irritate skin, eyes, and mucous membranes. May be mildly toxic by ingestion, inhalation and skin absorption. Used to make other chemicals. Use: in lithography, battery acid solution treated fabrics, used in varnishes.

제조 방법

생산 방법Lead sulfate, PbSO4, is soluble in concentrated acids and alkalies, forming hydroxyplumbites. It is prepared by treating lead oxide, hydroxide, or carbonate with warm sulfuric acid, or by treating a soluble lead salt with sulfuric acid.

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
北京华美互利生物化工010-56205725 · [email protected]
江西益众化工有限公司15307925109 15350027073 · [email protected]
阿诺西(上海)生物技术有限公司400-1107768 15058188853 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

추가 설명

정의anglesite: A mineral form oflead(II) sulphate, PbSO4.

관련 반응

2건

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