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염화 코발트

Cobalt(II) chloride

HCID 24288
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인쇄 미리보기
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
7646-79-9
표준 SMILES
[Cl][Co][Cl]
InChIKey
GVPFVAHMJGGAJG-UHFFFAOYSA-L
분자식
Cl2Co
평균 분자량
129.84 g/mol
단동위원소 질량
128.870899

개요

Formerly approved as a food additive but now prohibited<br /> Cobaltous chloride belongs to the family of Transition Metal Chlorides. These are inorganic compounds in which the largest halogen atom is Chlorine, and the heaviest metal atom is a transition metal.

이름 및 식별자

우선 이름
Cobalt(II) chloride
IUPAC
dichlorocobalt
현지명
염화 코발트
영어명
Cobalt chloride
분자식
Cl2Co
분자량
129.84

이름 및 동의어

Cobalt(II) chlorideCobaltchlorideCobalt(II) chloride, ultra dryNSC 51149;Cobalt Chloride; Cobalt Dichloride; Cobalt Dichloride (CoCl2); Cobalt(2+) Chloride;Cobalt(II) Chloride; Cobaltous Chloride; Cobaltous Dichloride; Dichlorocobalt;cobalt(II)-chlorideCurator_000013Cobalt chloride anhydrousWLN: CO G2cobalt - (II) - chlorideSCHEMBL15589
이름 더 보기
염화코발트염화코발트(COBALTCHLORIDE)코발트다이클로라이드코발트다이클로라이드(코발트클로라이드)코발트클로라이드CoCl2COBALT DICHLORIDECOBALTOUS CHLORIDECobalt(Ⅱ)chlorideAnhydrous cobalt chlorideCobaltous chloride anhydrousCOBALT(II) CHLORIDE, ANHYDROUS, BEADS, - 10 MESH, 99.9%CobaLt(II) chL
COBALT (II) CHLORIDECobalt(II) chloride, 97%NSC51149AKOS015833210DB-254262DS-002654Cobalt(II) chloride, for synthesis, 98.0%Cobalt(II) chloride, Vetec(TM) reagent grade

데이터베이스 식별자

CAS
7646-79-9
PubChem CID
24288

물성

구조 계산 물성

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
0
무거운 원자 수
3
형식 전하
0
복잡도
2.8

물리화학적 성질

녹는점
724 °C · 724 °C(lit.)
끓는 점
1049 °C · 1049 °C
밀도
3.35 · 3.35
증기압
40 mm · 40 mm Hg ( 0 °C)
인화점
500 °C · 500°C
저장 조건
30 °C · Store below +30°C.
용해도
585.9 g/l · 585.9g/l 수용성
물리적 상태
염주
색상
옅은 파란색
Specific Gravity
3.356 · 3.356
수소이온지수(pH)
pH (50g/l, 25℃) : >=3.0
냄새
Slight sharp odor
Flame Color
White/sparks
수용성
녹는
비열
0.6 J/ · Cp(crystal): 0.6 J/(g·K), at 25℃
Merck
14 · 14,2437
안정성
흡습성
주요 응용
배터리 전구체촉매재료 합성 전구체
InChI
1S/2ClH.Co/h2*1H;/q;;+2/p-2
InChIKey
GVPFVAHMJGGAJG-UHFFFAOYSA-L
SMILES
Cl[Co]Cl

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

안전 및 보호

Minimum Risk LevelChronic Inhalation: 0.0001 mg/m3 (L134) Intermediate Oral: 0.01 mg/kg/day (L134)

독성 정보

TreatmentTreatment of cobalt poisoning is symptomatic. (L29)
Health EffectsExposure to high amount of cobalt can cause heart, lung, kidney, and liver damage. Skin contact is known to result in contact dermatitis. Cobalt may also have mutagenic and carcinogenic effects. (L29, L30)
Exposure RoutesInhalation (L29) ; oral (L29) ; dermal (L29)
Toxicity Summary · 1건

Cobalt is believed to exhibit its toxicity through a oxidant-based and free radical-based processes. It produces oxygen radicals and may be oxidized to ionic cobalt, causing increased lipid peroxidation, DNA damage, and inducing certain enzymes that lead to cell apoptosis. Cobalt has also been shown to block inorganic calcium channels, possibly impairing neurotransmission. Cobalt can also chelate lipoic acids, impairing oxidation of pyruvate or fatty acids. In addition, cobalt may inhibit DNA repair by interacting with zinc finger DNA repair proteins, and has also been shown to inhibit heme synthesis and glucose metabolism. Cobalt may activate specific helper T-lymphocyte cells and interact directly with immunologic proteins, such as antibodies (IgA and IgE) or Fc receptors, resulting in immunosensitization. (L29)

Signs and SymptomsCobalt inhalation can cause asthma-like breathing problems. Skin contact is known to result in contact dermatitis, which is characterized by irritation and rashes. Ingesting large amounts of cobalt may cause nausea and vomiting. (L2090)
Carcinogen Classification2B, possibly carcinogenic to humans. (L135)
Toxicity Data

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Cobalt is absorbed though the lungs, gastrointestinal tract, and skin. Since it is a component of the vitamin B12 (cyanocobalamin), it is distributed to most tissues of the body. It is transported in the blood, often bound to albumin, with the highest levels being found in the liver and kidney. Cobalt is excreted mainly in the urine and faeces. (L29)

용도 및 제조

UsesCobalt(II) chloride is used to detect the prescence of water. (L32)
응용 분야 · 4건

용도계측기 생산에서는 기압계, 습도계, 습식 및 건식 지표 등의 생산에 사용됩니다. 도자기 업계에서는 착색제로 사용됩니다. 페인트 산업에서 페인트 건조기를 만드는 데 사용됩니다. 축산업에서는 복합 사료를 구성하는 데 사용됩니다. 양조 업계에서는 맥주 거품 안정제로 사용됩니다. 방위 산업에서는 방독 마스크를 만드는 데 사용됩니다. 화학 반응에서 촉매로 사용됩니다. 분석 화학에서는 아연의 단일 분석, 단일 번식, 또한 숨겨진 잉크, 염화 코발트 시험지, 색이 변하는 실리카 겔 등의 생산에도 사용할 수 있습니다. 암모니아 흡착제로도 사용됩니다.

개요blue crystals (anhydrous) violet-blue (dihydrate) rose red crystals (hexahydrate) Sinks and mixes with water. Pale blue leaflets, turns pink upon exposure to moist air.

용도Cobalt chloride (CoCl2) is used to manufacture vitamin B12, even though the compound itself can cause damage to red blood cells. It is also used as a dye mordant (to fix the dye to the textile so that it will not run). It is also of use in manufacturing solid lubricants, as an additive to fertilizers, as a chemical reagent in laboratories, and as an absorbent in gas masks, electroplating, and the manufacture of vitamin B12.

일반 설명Cobalt(II) chloride is an anhydrous cobalt salt. Cobalt(II) chloride participates in the synthesis of various esters in the presence of acetonitrile.

상·하류 제품 정보

상류 원료

암모니아수과산화 수소

관련 반응

176건
반응 기록 만들기
HRID 6307 반응식
HRID 6307촉매로uspto-grants-1993_09
HRID 6308 반응식
HRID 6308촉매로uspto-grants-1993_09
HRID 6309 반응식
HRID 6309촉매로uspto-grants-1993_09
HRID 12134 반응식
HRID 12134촉매로uspto-grants-2010_06
HRID 12135 반응식
HRID 12135촉매로uspto-grants-2010_06
HRID 12163 반응식
HRID 12163촉매로uspto-grants-2010_06
HRID 12164 반응식
HRID 12164촉매로uspto-grants-2010_06
HRID 93439 반응식
HRID 93439반응물로Training data from https://doi.org/10.1039/C8SC04228D (2/10)
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화합물 노트

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새 노트새 반응견적 요청하기
NIST
Cobalt dichloride(7646-79-9)
EPA
Cobalt chloride (CoCl2) (7646-79-9)
화학적 성질 · 1건

Cobalt chloride (CoCl₂) is a purplish-red or red monoclinic crystal that is slightly weathered and easily deliquescent. It has a melting point of 724°C and is soluble in water, ethanol, ether, and acetone. The anhydrous compound has the molecular formula CoCl₂, containing 45.4% cobalt and 54.6% chlorine. The monohydrate compound has the molecular formula CoCl₂·H₂O, containing 39.9% cobalt. The hexahydrate compound has the molecular formula CoCl₂·6H₂O, containing 24.8% cobalt. Cobalt chloride crystals are stable at room temperature but lose water of crystallization and turn blue when heated. They turn red in humid air. When heated or when concentrated hydrochloric acid, chloride, or organic solvents are added, its aqueous solution becomes blue. The compound crystallizes at 30–45°C and begins to weather, becoming turbid. It forms a tetrahydrate when heated at 45–50°C for 4 hours, and becomes anhydrous when heated to 110°C. It is obtained through the reaction of cobalt powder, cobalt oxide, cobalt hydroxide, or cobalt carbonate with hydrochloric acid.

LD50: 80 mg/kg (Oral, Rat) (T14) LD50: 17 mg (Intraperitoneal, Rat) (T14) LD50: 20 mg/kg (Intravenous, Rat) (T14)

안전 데이터

wgk
2
tsca
TSCA listed
rtecs
GF9800000
ridadr
UN 2923 8/PG 3
독성
LD50 in mice, rats (mg/kg): 360.0, 171.0 orally; 92.6, 36.9 i.p.; 23.3, 4.3 i.v. (Singh, Junnarkar)
HS 번호
28273930
risk_code
49-42/43-52/53-50/53-22-68-41-60-51/53
hazard_code
T,N
safety_code
53-23-36/37-45-60-61-22-39-26
포장분류
III
위험 등급
8
기존화학 물질
KE-06095
F 고인화성물질
9-21
Hazard Classifications
Acute Tox. 4 OralAquatic Acute 1Aquatic Chronic 1Carc. 1B InhalationEye Dam. 1Muta. 2Repr. 1BResp. Sens. 1Skin Sens. 1
스토리지 클래스
6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
유해 물질 데이터
7646-79-9(Hazardous Substances Data)
중점관리물질 필터링
별표1-126
코발트 염화물, 헥사수화물
염산
질산
암모늄 비카보네이트
코발트분

하류 제품

디메틸티오린산클로라이드코발트(II) 하이드록사이드실리카겔N,N,N',N'-에틸렌디아민테트라(메틸렌인 산)클로에스테롤 아세트산3-페녹시벤즈알데하이드소르빈산Phosphorus-containing intermediates of asymmetric organophosphorus pesticidesColor changing silica gelsodium [2,4-dihydro-4-[(2-hydroxy-5-nitrophenyl)azo]-5-methyl-2-phenyl-3H-pyrazol-3-onato(2-)][1-[(2-hydroxy-4-nitrophenyl)azo]-2-naphtholato(2-)]cobaltate(1-)탄산코발트(II)황산 스트렙토마이신황색 116 산염료Sulfonated cobalt phthalocyanine디캄바산성황색128가죽스프레이잉BLUERL시아노코발아민옥토산 코발트코발트 염화물, 헥사수화물4-아미노-1-부탄올산성레드2131,2-헥사데칸디올클로르피리포스-메틸아염소나트륨산화코발트퀴날포스1,4-헥사다이엔C.I. 산성 황색 059
추가 설명 · 1건

정의ChEBI: Cobalt dichloride is a cobalt salt in which the cobalt metal is in the +2 oxidation state and the counter-anion is chloride. It is used as an indicator for water in desiccants. It has a role as a two-colour indicator, an allergen, a calcium channel blocker and a sensitiser. It is a cobalt salt and an inorganic chloride. It contains a cobalt(2+).