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브로민화 주석(IV)(브롬화 주석(IV))

Stannane, tetrabromo-

HCID 24616
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인쇄 미리보기

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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
7789-67-5
표준 SMILES
[Br][Sn]([Br])([Br])[Br]
InChIKey
LTSUHJWLSNQKIP-UHFFFAOYSA-J
분자식
Br4Sn
평균 분자량
438.33 g/mol
단동위원소 질량
435.5755431

개요

Tin(IV) bromide is a bromide of tin. Tin is a chemical element with the symbol Sn and atomic number 50. It is a natural component of the earth's crust and is obtained chiefly from the mineral cassiterite, where it occurs as tin dioxide. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625, L307, L309)

이름 및 식별자

우선 이름
Stannane, tetrabromo-
IUPAC
tetrabromostannane
현지명
브로민화 주석(IV)(브롬화 주석(IV))
영어명
TIN(IV) BROMIDE
분자식
Br4Sn
분자량
438.32

이름 및 동의어

Tin(IV) bromideTetrabromostannaneTin tetrabromideStannane, tetrabromo-7789-67-5Stannic bromideTin perbromideSnBr4TIN(IV) BROMIDE (1:4)EINECS 232-184-5Tin (IV) bromideUNII-23C21BW281
이름 더 보기
브로민화주석(IV)(브롬화주석(IV))브로민화주석(IV)(브롬화주석(IV))(TIN(IV)BROMIDE)제2 주석의 브로마이드스탄브로마이드주석(IV)브롬화물주석테트라브롬화물테트라브롬주석TIN BROMIDEtinperbromidetetrabromo-stannan
23C21BW281TetrabromotinTin bromide (SnBr4)Stannic tetrabromidetin-(IV)-bromideTin(IV) bromide, 99%SCHEMBL52454STANNIC BROMIDE [MI]

데이터베이스 식별자

CAS
7789-67-5
PubChem CID
24616
DTXSID
DTXSID1064873
UNII
23C21BW281
EC Number
232-184-5

물성

구조 계산 물성보충 중

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
0
무거운 원자 수
5
형식 전하
0
복잡도
19.1

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metals, Inorganic Compounds
Physical DescriptionWhite solid; Fumes in air; mp = 31 deg C; [Merck Index] Colorless crystals; [Aldrich MSDS]

물리화학적 성질

녹는점
31 °C · 31 °C(lit.)
끓는 점
202 °C · 202 °C(lit.)
밀도
3.34 g/mL · 3.34 g/mL at 25 °C(lit.)
인화점
202 °C/734mm · 202°C/734mm
용해도
2 O; · very soluble in H2O; soluble in ethanol
물리적 상태
덩어리
Specific Gravity
3.34 · 3.34
색상
무색~백색
수용성
물에 매우 잘 녹습니다. 에틸알코올에 용해됩니다.
비열
0.24 J/ · Cp(gas): 0.24 J/(g·K), at 25℃
Merck
14 · 14,8773
InChI
1S/4BrH.Sn/h4*1H;/q;;;;+4/p-4
InChIKey
LTSUHJWLSNQKIP-UHFFFAOYSA-J
SMILES
Br[Sn](Br)(Br)Br

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 4건

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P261, P264, P271, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P319, P321, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 43 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 2건

Chemical: Stannane, tetrabromo-

Stannane, tetrabromo-: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryA skin and eye irritant; [Hawley] See Bromine.
Hazard Classes and CategoriesSkin Corr. 1B (100%)

안전 및 보호

Threshold Limit Values (TLV)2.0 [mg/m3], as Sn
Permissible Exposure Limit (PEL)2.0 [mg/m3], as Sn

독성 정보

Treatment · 1건

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Though tin metal is very poorly absorbed, tin compounds may be absorbed via oral, inhalation, or dermal routes, with organotin compounds being much more readily absorbed than inorganic tin compounds. Tin may enter the bloodstream and bind to hemoglobin, where it is distributed and accumulates mainly in the kidney, liver, lung, and bone. Tin and its metabolites are excreted mainly in the urine and feces. Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626, L308)

용도 및 제조

Uses · 2건

Used in metallurgy (separation of minerals); [Merck Index]

Metal Extraction and Refining [Category: Industry]

General Manufacturing InformationStannane, tetrabromo-: ACTIVE

응용 분야

용도In metallurgical separation of minerals.

상·하류 제품 정보

하류 제품

테트라알리주석트라이브로민화 비소(트리브롬화 비소)

관련 반응

5건
반응 기록 만들기
HRID 16725 반응식
HRID 16725반응물로uspto-grants-2010_06
HRID 43229 반응식
HRID 43229반응물로uspto-grants-2013_09
HRID 254606 반응식
HRID 254606반응물로uspto-grants-2011_01
HRID 974377 반응식
HRID 974377반응물로uspto-grants-1991_11
HRID 1093099 반응식
HRID 1093099반응물로uspto-grants-2012_03

화합물 노트

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EPA
Stannane, tetrabromo- (7789-67-5)

화학적 성질

WHITE TO LIGHT YELLOW CRYSTALLINE SOLID

Health Effects · 1건

Ingestion of large amounts of inorganic tin compounds can cause stomachache, anemia, and liver and kidney problems. Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627, L307, L308)

Exposure RoutesOral (L308) ; inhalation (L308) ; dermal (L308)
Toxicity Summary · 1건

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. Inorganic and organic tin compounds are weak inhibitors of alcohol dehydrogenase. (A183, L626, L627, A543)

Signs and Symptoms · 1건

Inorganic or organic tin compounds placed on the skin or in the eyes can produce skin and eye irritation. Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627, L308)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

안전 데이터

wgk
3
tsca
TSCA listed
rtecs
XP8300000
ridadr
UN 3260 8/PG 2
risk_code
14-34-37
hazard_code
C
safety_code
26-36/37/39-45-7/8
포장분류
II
위험 등급
8
기존화학 물질
KE-33875
F 고인화성물질
1-10
Hazard Classifications
Skin Corr. 1BSTOT SE 3
스토리지 클래스
8B - Non-combustible corrosive hazardous materials
함량 및 규제정보
물질구분: 유독물질; 혼합물(제품)함량정보: 무기주석 염류 및 이를 25% 이상 함유한 혼합물
유해화학물질 필터링
97-1-93