7790-44-5[I][Sb]([I])[I]KWQLUUQBTAXYCB-UHFFFAOYSA-KAntimony Triiodide is an antimony hydride and a mononuclear parent hydride that is used in many industrial processes. It is characterized as a toxic, colorless gas that is heavier than air with a disagreeable odor, and exposure occurs by inhalation, ingestion, or contact.
7790-44-5DTXSID10648754.92 g/cu cm at 25 °C
Density: 4.921 at 17 °C/4 °C
Density: 4.768
Ruby-red, trigonal crystals (yellowish-green modifications have been observed)
Red rhombic crystals
Red-to-yellow crystals
Reacts with water
Decomposes in water with precipitation of oxyiodide
Soluble in ethanol, acetone; insoluble in carbon tetrachloride
Souble in alcohol; acetone; carbon disulfide, hydrochloric acid, solution of potassium iodide; insoluble in carbon tetrachloride
Hazardous decomposition products formed under fire conditions. - Hydrogen iodide, Antimony oxide
Decomposed by water and air to SbOI (antimony oxyiodide).
When heated to decomposition it emits highly toxic Sb fumes and /hydrogen iodide/.
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
Warning
H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]
P261, P264, P270, P271, P273, P301+P317, P304+P340, P317, P330, P391, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 44 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Warning
H302: Harmful if swallowed [Warning Acute toxicity, oral]
Symptoms of iodide poisoning are mucous membrane irritation, rhinorrhea, headache, and skin rash; Antimony compounds can cause injury to the liver, kidneys, heart, and lungs; [HSDB] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline] See Antimony and linked occupational diseases. See Iodine for the TLV of Iodides.
Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Antimony compounds are included on this list. /Antimony Componds/
Used in medicine; [HSDB]
The greatest use of antimony compounds is in flame retardants for plastics, paints, textiles, and rubber. Antimony compounds used in flame retardants are antimony pentoxide, sodium antimonate ... and, most importantly, antimony trioxide. These compounds, when used alone, are poor flame retardants; however, when combined with halogen compounds, they produce mixtures that are effective. ... Glass articles coated with oxides and oxynitrides of antimony have been reported. The layers of antimony block uv radiation and can be used for windows.... Antimony compounds are also used in catalysts, pesticides, ammunition, medicines and lubricating grease. /Antimony compounds/
Laboratory chemicals; Synthesis of substances.
Antimony triiodide is prepared by reacting iodine with antimony or antimony sulfide in an organic solvent.
Prepared by the interaction of antimony and iodine in boiling benzene or tetrachloroethane.
Stibine, triiodo-: ACTIVE
Antimony can be trivalent or pentavalent in compounds. Both exist in antimony(IV) oxide, Sb2O4, and presumably in the deep violet haloantimonates (IV), such as Cs2(SbCl6). The pentavalent compounds, as well as most of the trivalent ones, are hydrolyzed by water to form antimony salts, e.g., SbOCl, and hydrated oxides. The only halides of antimony that have any industrial significance are the chlorides and fluorides. /Antimony compounds/
용도Antimony(III) iodide is used as a dopant in the preparation of thermoelectric materials.
It adds to ethers, aldehydes, and thiols. Antimony triiodide is prepared by reacting iodine with antimony or antimony sulfide in an organic solvent. The triiodide is used in medicine.
현재 필터 조건에 해당하는 반응 기록이 없습니다.
불러오는 중…
light brown powder
/GUIDE 157 SUBSTANCES - TOXIC and/or CORROSIVE (Non-Combustible/Water-Sensitive)/ Fire or Explosion: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. For UN1796, UN1826, UN2031 at high concentrations and for UN2032, these may act as oxidizers, also consult GUIDE 140. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Substance may react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. /Antimony compound, inorganic, solid, n.o.s.; Antimony compound, inorganic, liquid, n.o.s./
/GUIDE 157 SUBSTANCES - TOXIC and/or CORROSIVE (Non-Combustible/Water-Sensitive)/ Health: TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air may release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. /Antimony compound, inorganic, solid, n.o.s.; Antimony compound, inorganic, liquid, n.o.s./
/GUIDE 157 SUBSTANCES - TOXIC and/or CORROSIVE (Non-Combustible/Water-Sensitive)/ Public Safety: CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Keep unauthorized personnel away. Stay upwind, uphill and/or upstream. Ventilate enclosed areas. /Antimony compound, inorganic, solid, n.o.s.; Antimony compound, inorganic, liquid, n.o.s./
/GUIDE 157 SUBSTANCES - TOXIC and/or CORROSIVE (Non-Combustible/Water-Sensitive)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. /Antimony compound, inorganic, solid, n.o.s.; Antimony compound, inorganic, liquid, n.o.s./
For more DOT Emergency Guidelines (Complete) data for Antimony triiodide (8 total), please visit the HSDB record page.
No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./
The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials. Antimony compound, inorganic, solid, not otherwise specified and antimony compound, inorganic, liquid, not otherwise specified are included on the dangerous goods list. /Antimony compound, inorganic, solid, not otherwise specified; Antimony compound, inorganic, liquid, not otherwise specified/
The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article. Antimony compound, inorganic, solid, not otherwise specified and antimony compound, inorganic, liquid, not otherwise specified are included on the dangerous goods list. /Antimony compound, inorganic, solid, not otherwise specified; Antimony compound, inorganic, liquid, not otherwise specified/
UN 3141; Antimony compound, inorganic, liquid, not otherwise specified
UN 1549; Antimony compound, inorganic, solid, not otherwise specified
IMO 6.1; Antimony compound, inorganic, solid, not otherwise specified; Antimony compound, inorganic, liquid, not otherwise specified
A mixture of potassium and ... the metallic halide ... antimony triiodide ... produces a strong explosion on impact.
Incompatible with sodium, potassium.
... Antimony triiodide ... readily hydrolyzes, forms complex halide ions and forms a wide variety of adducts with ethers, aldehydes, mercaptans ... .
Acids, Water, Strong bases, Sodium/sodium oxides, Potassium
Strong oxidizers, acids, halogenated acids [Note: Stibine is formed when antimony is exposed to nascent (freshly formed) hydrogen.] /Antimony/
ACCIDENTAL RELEASE MEASURES; Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Avoid breathing dust. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials: for containment and cleaning up: Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
SRP: Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in air, soil or water; effects on animal, aquatic and plant life; and conformance with environmental and public health regulations. If it is possible or reasonable use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination.
Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging: Dispose of as unused product.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.
ACCIDENTAL RELEASE MEASURES; Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Avoid breathing dust. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
For more Preventive Measures (Complete) data for Antimony triiodide (8 total), please visit the HSDB record page.
0.5 [mg/m3], as Sb (0.01 ppm, inhalable fraction and vapor (iodides))
8 hr Time Weighted Avg (TWA): 0.5 mg/cu m. /Antimony and compounds, as Sb/
Peak Exposure Recommendation: Transient increases in workers' exposure levels may exceed 3 times the value of the TLV-TWA level for no more than 15 minutes at a time, on no more than 4 occasions spaced 1 hour apart during a workday, and under no circumstances should they exceed 5 times the value of the TLV-TWA level. In addition, the 8-hour TWA is not to be exceeded for an 8-hour work period. /Antimony and compounds, as Sb/
Eye/face protection: Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection: Handle with gloves.
Body Protection: Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection: For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator. For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
For more Personal Protective Equipment (PPE) (Complete) data for Antimony triiodide (12 total), please visit the HSDB record page.
50.0 [mg/m3]
50 mg/cu m, as Sb /Antimony/
IDENTIFICATION AND USE: Antimony triiodide is a solid. It is used as laboratory chemical and in the synthesis of substances. HUMAN STUDIES: Antimony halides are hydrolyzed to oxides which are not absorbed but cause severe irritation and caustic action on alimentary mucosa. Antimony halides produce irritant effects on the mucous membranes of the eyes, nose, mouth, throat, and upper respiratory tract. ANIMAL STUDIES: Chronic inhalation of subtoxic doses of antimony salts causes interstitial pneumonitis, intraalveolar lipoid deposits, and liver and cardiac damage.
/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on the left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Poisons A and B/
/SRP:/ Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if needed. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Cover skin burns with dry sterile dressings after decontamination ... . /Poisons A and B/
/SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Positive-pressure ventilation techniques with a bag valve mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Consider administering a beta agonist such as albuterol for severe bronchospasm ... . Monitor cardiac rhythm and treat arrhythmias as necessary ... . Start IV administration of D5W TKO /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Watch for signs of fluid overload ... . Treat seizures with diazepam or lorazepam ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Poisons A and B/
/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Iodine and related compounds/
For more Antidote and Emergency Treatment (Complete) data for Antimony triiodide (6 total), please visit the HSDB record page.
Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Antimony compounds are included on this list. /Antimony Componds/