요오드 모노염화물(베타)

위이스시액,위스시액 · 요오드모노염화물(베타) · 요오드모노염화물 · 요오드클로라이드 · 요오드모노염화물(베타)(IODINEMONOCHLORIDE(BETA)) · ICl · IODINE CHLORIDE · WIJS REAGENT

https://huagongshe.com/ko/chemical/24640

식별자 및 물리적 특성

CAS No.	7790-99-0
분자식	ClI
평균 분자량	162.36 g/mol
단동위원소 질량	161.87332568 g/mol
SMILES	ClI
InChIKey	QZRGKCOWNLSUDK-UHFFFAOYSA-N
PubChem CID	24640
EC No.	232-236-7
DTXSID	DTXSID1064879
현지명	요오드 모노염화물(베타)

화학 및 물리적 성질

XLogP	1.7
극성 표면적	0
수소 결합 공여자 수	0
수소 결합 수용자 수	0
회전 가능 결합 수	0
무거운 원자 수	2
형식 전하	0
복잡도	2
물질 분류	Other Classes -> Halogenated Aliphatics, SaturatedCorrosives
밀도	3.10 @ 29 °C/4 °C3.24 g/mL at 25 °C (lit.)
Color/Form	BLACK CRYSTALS OR REDDISH-BROWN LIQ
용해도	SOL IN WATER, ALC, ETHER, CARBON DISULFIDE, ACETIC ACIDSOL IN HYDROCHLORIC ACID아세트산: 가용성(lit.)
끓는 점	97 °C, DECOMP97.4 °C (lit.)
Decomposition	When heated to decomposition, it emits highly toxic fumes of /hydrogen chloride and hydrogen iodide/ and may explode.
녹는점	ALPHA 27.2BETA 13.9 °C25-27°C
Food Contact Substances	FCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Physical Description	Iodine monochloride appears as black crystals or a reddish brown oily liquid with a pungent odor. Melting point 27 °C (alpha form) or 14 °C (beta form). Corrosive to metals and tissue.Black solid or reddish-brown liquidSolid occurs as alpha (mp = 27.2 deg C) and beta (mp = 13.9 deg C) formsSoluble in water[Merck Index] Black crystalline solid with an acrid odorInsoluble in water[MSDSonline]
Other Experimental Properties	CRYSTALS OCCUR IN ALPHA (STABLE) & BETA (LABILE) FORMSBLACK NEEDLES (RUBY RED BY TRANSMITTED LIGHT) /ALPHA FORM/BLACK PLATELETS (BROWNISH RED BY TRANSMITTED LIGHT) /BETA FORM/RHOMBIC 6-SIDED PLATES /BETA/NEEDLES, CUBIC /ALPHA/
증기 밀도	5.5 (vs air)
인화점	96-98°C
저장 조건	2-8°C
물리적 상태	액체
색상	적갈색
pH	<1 (H2O, 20°C)
용해도	물에서 분해되다
비열	Cp(gas): 0.22 J/(g·K), at 25℃
Merck	14,5017
BRN	3902972
헨리 상수	1.1×100 mol/(m3Pa) at 25℃, Wagman et al. (1982)
안정성	안정적인. 유기 물질, 강염기, 금속과 호환되지 않습니다. 공기, 빛, 습기에 민감합니다.
InChI	1S/ClI/c1-2
InChIKey	QZRGKCOWNLSUDK-UHFFFAOYSA-N
SMILES	ClI
NIST	Iodine monochloride(7790-99-0)
EPA	Iodine chloride (ICl) (7790-99-0)

화학적 성질

Iodine monochloride is a reddish brown liquid or black crystals, there are two variants of crystals. α-type is black needles, stable, ruby red under light. β-type is black flakes, unstable, brownish red under light. It has the odor of chlorine and iodine. It does not absorb moisture but can form iodine pentoxide when contacting air. Soluble in water, ethanol, ether, carbon disulfide, and acetic acid, relative density (d0) α-type 3.1822, (d34) β-type 3.24. Melting point α-type 27.2 ℃, β-type 13.9 ℃. Boiling point α-type 97.4°C, β-type 97.4, 100°C (decomposition). It also exhibits corrosive properties. It has the flavor of chlorine and iodine, and it is oxidative and strongly corrosive, and iodination with organic matter, it also shows chlorination, and it can be used for the substitution of the aromatic ring.

안전 및 규제

GHS 분류	DangerH226 (17.8%): Flammable liquid and vapor [Warning Flammable liquids]P210, P233, P240, P241, P242, P243, P260, P261, P262, P264, P264+P265, P270, P271, P280, P284, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P342+P316, P361+P364, P363, P370+P378, P403, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 73 reports by companies from 13 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
규제 정보	Chemical: Iodine chloride (ICl)Status: Active Update: 17-04-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/13573Iodine monochloride: Does not have an individual approval but may be used under an appropriate group standardThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
운송 라벨(DOT)	Corrosive
화재 위험	Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
화재 가능성	ALUMINUM FOIL, AFTER CONTINUED CONTACT WITH IODINE MONOCHLORIDE, IGNITES SPONTANEOUSLY & BURNS WITH BLUISH-WHITE FLAME.
건강 유해성	Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:· TOXIC and/or CORROSIVEinhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.
유해성 요약	Reacts with air forming iodine pentoxideCauses skin burns[Merck Index] A strong skin and eye irritant[Hawley] Reacts with water evolving heat and toxic and corrosive fumesExposure may cause severe injury, burns, or death[CAMEO] Corrosive to skin and eyes[eChemPortal: ERMA] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract

용도

Iodine monochloride is used to estimate theiodine values of fats and oils and as a topicalanti-infective (Merck 1996). For determination of iodine absorption number of fats Iodine monochloride is used as a catalyst in organic synthesis. It is the source of electrophilic iodine in the synthesis of certain aromatic iodides.

제조 및 합성 방법

제조 방법

Iodine monochloride is prepared by the action of liquid or dry chlorine on astoichiometric quantity of solid iodine. Aqueous solutions of ICl are preparedby passing chlorine gas into a suspension of iodine in moderately stronghydrochloric acid: 5I2 + 4HCl + 3Cl2 → 10ICl + 2H2 Alternatively, iodine monochloride may be made by oxidation of iodine withiodic acid in strong hydrochloric acid solution: 2I2 + HIO3 + 2HCl → 2ICl + 3HIO