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하이드라진, 모노수화물

Hydrazine hydrate (1:1)

HCID 24654
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
10217-52-4
표준 SMILES
NN.O
InChIKey
IKDUDTNKRLTJSI-UHFFFAOYSA-N
분자식
H4N2.H2O
평균 분자량
50.061 g/mol
단동위원소 질량
50.04801281

개요

Hydrazine hydrate is a hydrate. It contains a hydrazine.

이름 및 식별자

우선 이름
Hydrazine hydrate (1:1)
IUPAC
hydrazine;hydrate
현지명
하이드라진, 모노수화물
영어명
Hydrazine hydrate
분자식
H4N2.H2O
분자량
50.06

이름 및 동의어

Hydrazine hydrate7803-57-8Hydrazine hydroxideHYDRAZINE, MONOHYDRATEIdrazina idrataKYD297831PHydrazine hydrate (1:1)DTXSID9037240CHEBI:35511Hydrazine, hydrate (6CI,7CI)RefChem:5889DTXCID7017240
이름 더 보기
하이드라진수화물히드라진수산화물HYDRAZINEHYDRATE,HYDRAZINEHYDROXIDE,IDRAZINAIDRATA,수화물하이드라진,모노수화물하이드라진,모노수화물(히드라진,모노수화물)히드라지늄수산화물히드라진,수화물히드라진모노하이드레이트하이드라이진하이드라진하이드레이트하이드라진,모노수화물(히드라진,모노수화물)(HYDRAZINE,MONOHYDRATE)하이드라진 모노하이드레이트하이드라진 수화물하이드라진 하이드록사이드하이드라진, 1수화물하이드라진이움 하이드록사이드Diamid hydrateHydrazine, hydrate (1:1)DiamideHydrateDiamineHydrateidrazinaidrataJACS-7803-57-8HYDRAZINE1-HYDRATEhydrazinehydroxide
DTXSID901014833Hydrazinium hydroxideHydrazine monohydrate10217-52-4hydrazine;hydrateHydrazine, hydratehydraziniumhydroxideMFCD00149931

데이터베이스 식별자

CAS
10217-52-4、7803-57-8
PubChem CID
24654
DTXSID
DTXSID9037240
ChEBI
CHEBI:35511
UNII
KYD297831P
EC Number
600-285-7、616-584-0

물성

구조 계산 물성보충 중

극성 표면적
53 Ų
수소 결합 공여자 수
3
수소 결합 수용자 수
3
회전 가능 결합 수
0
무거운 원자 수
3
형식 전하
0
복잡도
0

실험 및 물리화학적 성질

Chemical Classes · 2건

Nitrogen Compounds -> Hydrazines

Corrosives

Density1.03 @ 21°C
Boiling Point119 °C @760 [mm Hg]
Melting Point-51.7 °C
Physical Description · 2건

Liquid; Other Solid; Liquid

A colorless fuming liquid with a faint ammonia-like odor; Corresponds to a 64% aqueous solution of hydrazine in water; [CAMEO]

물리화학적 성질

녹는점
51.7 °C · −51.7 °C(lit.)
끓는 점
120.1 °C · 120.1 °C(lit.)
밀도
1.03 g/mL · 1.03 g/mL at 20 °C
증기 밀도
1 · >1 (vs air)
증기압
5 mm · 5 mm Hg ( 25 °C)
굴절률
20 · n20/D 1.428(lit.)
인화점
204 °F · 204 °F
저장 조건
0 · 0-6°C
용해도
Acetonitrile (Sparingly), DMSO (Sparingly), Methanol (Slightly), Water (Sparingly)

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 0.5% (1 of 214) of reports.

Danger

H226 (95.3%): Flammable liquid and vapor [Warning Flammable liquids]

P203, P210, P233, P240, P241, P242, P243, P260, P261, P262, P264, P264+P265, P270, P271, P272, P273, P280, P284, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P318, P320, P321, P330, P333+P317, P361+P364, P362+P364, P363, P370+P378, P391, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 214 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

This chemical does not meet GHS hazard criteria for 11.1% (1 of 9) of reports.

유해성 정보

Regulatory Information · 5건

Chemical: Hydrazine, monohydrate

Hydrazine, monohydrate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Hydrazine, monohydrate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Hydrazine, monohydrate: HSNO Approval: HSR007167 Approved with controls

Hydrazine, monohydrate: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Hydrazine: Human health tier II assessment
Hazards Summary · 1건

Corrosive to skin; [Quick CPC] Highly toxic by inhalation, ingestion, or skin absorption; [CAMEO] A very strong reducing agent and violent poison; May cause delayed eye irritation; [Merck Index] Causes methemoglobinemia and liver injury in 28-day oral study of rats at 30 mg/kg/day; [JECDB] Causes excitement and muscle contraction or spasticity in oral lethal-dose studies of guinea pigs, mice, rabbits, and rats; [RTECS] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; May cause skin sensitization; Toxic by ingestion, inhalation, and skin absorption; [Alfa Aesar MSDS] See Hydrazine.

화학 및 산업

약리 정보

MeSH Pharmacological Classification · 2건

Substances that inhibit or prevent the proliferation of NEOPLASMS.

Substances that increase the risk of NEOPLASMS in humans or animals. Both genotoxic chemicals, which affect DNA directly, and nongenotoxic chemicals, which induce neoplasms by other mechanism, are included.

용도 및 제조

UsesUsed as a reducing agent and solvent for organic materials; Also used to make Helman catalyst (80% hydrazine hydrate that is used in V-2 type rockets) and mixed with methanol for rocket engine propulsion; [Merck Index]
U.S. Production2023: 75,000 - <500,000 lb
Consumer UsesIntermediate
Industry UsesIntermediate
General Manufacturing InformationPesticide, Fertilizer, and Other Agricultural Chemical Manufacturing
응용 분야 · 4건

용도제품의 권고 용도와 사용상의 제한 본 제품은 실험실 및 연구용 시약 외의 용도로는 사용할 수 없음.

용도사용상의 제한 실험연구용 시약, 합성 및 공정약품 외 사용금지.

용도Hydrazine hydrate is used as a reducing agent in synthetic and analytical reactions and as a solvent for many inorganic compounds. It also is used with methanol as a propellant for rocket engines. Another application is catalytic decomposition of hydrogen peroxide.

일반 설명A colorless fuming liquid with a faint ammonia-like odor. Corresponds to a 64% aqueous solution of hydrazine in water. Combustible but may require some effort to ignite. Contact with oxidizing materials may cause spontaneous ignition. Toxic by inhalation and by skin absorption. Corrosive to tissue. Produces toxics oxides of nitrogen during combustion.

관련 반응

9,961건
반응 기록 만들기
HRID 1078 반응식
HRID 1078반응물로uspto-grants-1998_03
HRID 1088 반응식
HRID 1088반응물로uspto-grants-1998_03
HRID 1186 반응식
HRID 1186용매로uspto-grants-1998_03
HRID 1202 반응식
HRID 1202반응물로uspto-grants-1998_03
HRID 1318 반응식
HRID 1318용매로uspto-grants-1998_03
HRID 1338 반응식
HRID 1338반응물로uspto-grants-1998_03
HRID 1491 반응식
HRID 1491반응물로uspto-grants-1998_03
HRID 1559 반응식
HRID 1559반응물로uspto-grants-1998_03
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화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
더보기
새 노트새 반응견적 요청하기
산도 계수 (pKa)
8.2 · 8.20
물리적 상태
발연 액체
Specific Gravity
1.032 · 1.032
색상
연기가 나는 액체
수소이온지수(pH)
10 · 10-11 (10g/l, H2O, 20℃)
폭발한계
3.4 · >3.4-99%(V)
수용성
에 용해됨클로로포름, DMSO, 메탄올에 용해됩니다. 물에 약간 용해됩니다.
Merck
14 · 14,4771
BRN
878137 · 878137
안정성
Stability Incompatible with a wide variety of materials, including oxidizing agents, heavy metal oxides, dehydrating agents, alkali metals, rust, silver salts. Combustible. Contact with many materials may cause fire or explosive decomposition. May react explosively with a variety of materials, including dehydrating agents, heavy metal ox
InChI
1S/H4N2.H2O/c1-2;/h1-2H2;1H2
InChIKey
IKDUDTNKRLTJSI-UHFFFAOYSA-N
SMILES
O.NN
EPA
Hydrazine monohydrate (7803-57-8)

화학적 성질

colourless fuming liquid

Hazard Classes and Categories · 6건

Flam. Liq. 3 (44.4%)

Flam. Liq. 3 (95.3%)

Acute toxicity - category 3

Flammable liquids - Category 4

Carcinogenicity - Category 1B

Flammable liquids - Category 4

안전 및 보호

Protective Action Criteria (PAC) · 3건

0.10 [ppm]

13 [ppm]

35 [ppm]

독성 정보

Adverse EffectsNeurotoxin - Other CNS neurotoxin

안전 데이터

wgk
3
tsca
Yes
rtecs
MV8050000
ridadr
UN 2030 8/PG I/II/III (HYDRAZINE AQUEOUS SOLUTION with more than 37 % hydrazine, by mass)
독성
LD50 orally in Rabbit: 169 mg/kg
HS 번호
28251000
risk_code
45-20/21/22-34-43-51/53-50/53-23/24/25-10
hazard_code
T,N
safety_code
53-45-60-61-36/37/39-26
포장분류
II
위험 등급
8
기존화학 물질
KE-05-0709
F 고인화성물질
23
자연 발화 온도
280 °C
Hazard Classifications
Acute Tox. 2 InhalationAcute Tox. 3 DermalAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1Carc. 1BEye Dam. 1Flam. Liq. 3Skin Corr. 1BSkin Sens. 1
스토리지 클래스
3 - Flammable liquids
함량 및 규제정보
물질구분: 유독물질; 혼합물(제품)함량정보: 히드라진 수화물 및 이를 25% 이상 함유한 혼합물
유해화학물질 필터링
97-1-410
중점관리물질 필터링
별표1-140
암, 돌연변이성물질 필터링
353
제조 방법 · 1건

Hydrazine hydrate is prepared by treating hydrazine sulfate, N2H4•H2SO4 with sodium hydroxide. The product is collected by distillation under nitrogen. It also is obtained as a by-product in the Bayer Ketazine process for producing hydrazine in which hydrazine solution is hydrolysed under pressure in a ketazine column.

상·하류 제품 정보

상류 원료

염소산용액차아염소산나트륨Ketone과산화 수소염소(기체)요소물Bone glue클로르아민 T과망간산칼륨수산화나트륨Sieve tower

하류 제품

6-플루오로-4-(트리플루오로메틸)퀴놀린-2-아민1H-인다졸-3-일라민3-Bromopropylamine hydrobromide3-Hydrazinyl-N-methylpropanamide(1,3-Dimethyl-butyl)-hydrazine에틸5-(2-FURYL)-1H-PYRAZOLE-3-CARBOXYLATE메틸4-아미노-3-메틸벤조에이트4,5-디클로로-3(2H)-피리다지논3-Amino-2-methylthieno[2,3-d]pyrimidin-4(3H)-one(1,1-Dimethyl-propyl)-hydrazine3-Hydrazinylpropanamide(2,2-디메틸-프로필)-하이드라진Benzylhydrazine dihydrochloride9-PHENANTHROL5-(2-Furyl)-4H-pyrazole-3-carboxylic acid2,6-Diamino-4-chloropyridine2-Hydrazinyl-N,N-dimethylacetamide1-hydroxybenzotriazole monohydrate4-클로로피리딘-2,6-디카르보하이드라지드2-Hydrazinylacetamide1-(2-Methoxyethyl)hydrazine4-Chloro-6-hydrazino-pyrimidin-5-ylamine3-(Furan-2-yl)-1H-pyrazole-5-carbohydrazide ,97%2,5-BIS(4-아미노페닐)-1,3,4-옥사디아졸(1,2-Dimethyl-propyl)-hydrazine4-Hydrazino-6-methylpyrimidin-2-aminePyridazine말레인 하이드라자이드5-브로모티오펜-2-카보히드라지드3-Hydrazinyl-N,N-dimethylpropanamide3,3'-다이클로로벤지딘 이수화염화물2-Hydrazinyl-N-methylacetamide1-(3-Methoxypropyl)hydrazine4-Amino-N,N-dimethylbenzylamine6-클로로-1H-인다졸-3-아민2-클로로벤즈히드라지드4-tert-Butylbenzhydrazide6-Boc-hydrazinonicotinic acid6-(Aminomethyl)-2-pyridine carboxylic acid4,6-디메틸-1H-피라졸로[3,4-B]피리딘-3-아민