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메틸 데메톤

Metasystox

HCID 24692
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
12767-20-3
표준 SMILES
CCSCCOP(=S)(OC)OC.CCSCCSP(=O)(OC)OC
InChIKey
KPNPDRFFWQBXGT-UHFFFAOYSA-N
분자식
C12H30O6P2S4
평균 분자량
460.6 g/mol
단동위원소 질량
460.04004736

개요

Methyl demeton is an oily colorless to pale yellow liquid with an unpleasant odor. Slightly water soluble.

이름 및 식별자

우선 이름
Metasystox
IUPAC
1-dimethoxyphosphorylsulfanyl-2-ethylsulfanylethane;2-ethylsulfanylethoxy-dimethoxy-sulfanylidene-λ5-phosphane
현지명
메틸 데메톤
영어명
Demeton methyl powder(content>10%)
분자식
2C6H15O3PS2
분자량
460.575

이름 및 동의어

Methyl demetonDemeton-methylDemeton methylMethyl systoxMetasystox forteDemeton MMethyl-mercaptophosMethylmerkaptofosMethyl demeton 25 EC8022-00-2Bayer 21/116B9PMD9I0FE
이름 더 보기
메틸데메톤디메톤-메틸메틸데메톤데메톤-메틸S(과 O)-2-(에틸싸이오)에틸 O,O-다이메틸 포스포로싸이오에이트S-2-에틸싸이오에틸 O,O-다이메틸 포스포로싸이오에이트메틸디메톤O,O-디메틸2-에틸티오에틸포스포로티오에이트포스포로싸이오산, O-(2-(에틸싸이오)에틸) O,O-다이메틸 에스터 (O 화합물)와 S-(2-(에틸싸이오)에틸) O,O-다이메틸 포스포로싸이오에이트 (S 화합물)의 혼합물포스포로싸이오산, O-[2-(에틸싸이오)에틸] O,O-다이메틸 에스터와 S-[2-(에틸싸이오)에틸] O,O-다이메틸 에스터의 혼합물포스포로싸이오산, O-[2-(에틸싸이오)에틸] O,O-다이메틸 에스터와 S-[2-(에틸싸이오)에틸] O,O-다이메틸 포스포로싸이오에이트의 혼합물Methyl 1059 powderDanazol Impurity 7Demetonmethylpowder(contenDemeton methyl powder(contentDemeton methyl powder(content>Demeton methyl powder(content>10%)Dimethylethylmercapto ethylthiophosphate

물성

구조 계산 물성

극성 표면적
171 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
10
회전 가능 결합 수
14
무거운 원자 수
24
형식 전하
0
복잡도
291

실험 및 물리화학적 성질

PesticidesPesticides -> Organophosphate Insecticides
LogP1.32
Density · 4건

1.2 at 68 °F (NTP, 1992) - Denser than water; will sink

Relative density (water = 1): 1.2

1.20

1.20

Solubility · 3건

Slightly soluble (NTP, 1992)

Solubility in water, g/100ml at 20 °C: 2.2

0.03-0.3%

Boiling Point · 3건

Decomposes (NIOSH, 2024)

decomposes

Decomposes

Vapor Pressure · 5건

0.0004 mmHg (NIOSH, 2024)

0.0004 [mmHg]

Vapor pressure, Pa at 20 °C: 0.04

0.0004 mmHg

0.0004 mmHg

Physical Description · 5건

Methyl demeton is an oily colorless to pale yellow liquid with an unpleasant odor. Slightly water soluble.

Oily, colorless to pale-yellow liquid with an unpleasant odor. [insecticide] [Note: Technical grade consists of 2 isomers: thiono & thiolo.]; [NIOSH]

COLOURLESS-TO-PALE YELLOW OILY LIQUID WITH CHARACTERISTIC ODOUR.

Oily, colorless to pale-yellow liquid with an unpleasant odor.

Oily, colorless to pale-yellow liquid with an unpleasant odor. [insecticide] [Note: Technical grade consists of 2 isomers: thiono & thiolo.]

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 3건

Danger

H300: Fatal if swallowed [Danger Acute toxicity, oral]

P203, P260, P261, P262, P264, P264+P265, P270, P271, P272, P280, P284, P301+P316, P302+P352, P304+P340, P305+P351+P338, P308+P316, P316, P318, P319, P320, P321, P330, P332+P317, P333+P317, P337+P317, P361+P364, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT LabelPoison
Fire Hazards · 2건

Flash point data for this chemical are not available. It is probably combustible. (NTP, 1992)

Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.

Health HazardsExcerpt from NIOSH Pocket Guide for Methyl demeton:
Hazards Summary · 1건

It is less toxic than demeton. [ACGIH] A cholinesterase inhibitor that may cause CNS effects; Can be absorbed through skin; [ICSC] The average of two baseline respective cholinesterase activity determinations three days apart, with no exposures to enzyme inhibiting pesticides for at least 30 days, is recommended for each worker prior to exposure to cholinesterase inhibitors because of large inter-individual differences in published baseline values. To be established at least once a year. Removal from workplace exposures is recommended until the cholinesterase activity returns to within 20% of baseline. [TLVs and BEIs]

Reactive GroupEsters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters

화학 및 산업

약리 정보

MeSH Pharmacological ClassificationPesticides designed to control insects that are harmful to man. The insects may be directly harmful, as those acting as disease vectors, or indirectly harmful, as destroyers of crops, food products, or textile fabrics.

용도 및 제조

Uses · 3건

Used to kill insects on garden crops, fruit, and hops; [ACGIH]

Not registered for use in the US; [EPA PPIS]

Farming (Pesticides) [Category: Industry]

응용 분야

용도Systemic insecticide.

일반 설명Oily colorless to pale yellow liquid with an unpleasant odor. Slightly water soluble.

공급사3 곳

河北枫嘉新材料科技有限公司+86-0311-87836622 +86-18712993135 · [email protected]
爆牛贸易重庆有限公司+86-023-6139-8061 +86-86-13650506873 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]

관련 반응

0건
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현재 필터 조건에 해당하는 반응 기록이 없습니다.

화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
OXYDEMETON-METHYL=S-(2(ETHYL-SULPHINYL)-ETHYL)O,O-DIMETHY.
O,O-dimethyl-O-(2-(ethylthio)ethyl) thiophosphate mixed with-O,O-dimethyl-S-(2-(ethylthio)ethyl) thiophosphate
S(and O)-2-(Ethylthio)ethyl O,O-dimethyl phosphorothioatePhosphorothioic acid, O-(2-(ethylthio)ethyl) O,O-dimethyl ester, mixt. with S-(2-(ethylthio)ethyl) O,O-dimethyl esterPhosphorothioic acid, O-(2-(ethylthio)ethyl) O,O-dimethyl ester, mixt. with S-(2-(ethylthio)ethyl) O,O-dimethyl phosphorothioateMethylmercaptophosRefChem:157840DTXSID3040277BAYER-21/116Phosphorothioic acid, S-(2-(ethylthio)et hyl) O,O-dimethyl ester

데이터베이스 식별자

CAS
12767-20-3、8022-00-2
PubChem CID
24692
DTXSID
DTXSID10925932

물리화학적 성질

밀도
1.19 · 1.1900
굴절률
1.5063 · 1.5063
EPA
Demeton-methyl (8022-00-2)

화학적 성질

Slightly soluble in water. Soluble in mostorganic solvents.

EC ClassificationSymbol: T, N; R: 24/25-51/53; S: (1/2)-28-36/37-45-61
UN ClassificationUN Hazard Class: 6.1; UN Pack Group: III
Reactivity Profile · 1건

Organothiophosphates, such as METHYL DEMETON, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Chemical DangersDecomposes on burning. This produces phosphorous oxides and sulfur oxides.
Flammable LimitsCombustible Liquid
Packaging and LabellingDo not transport with food and feedstuffs.

안전 및 보호

Fire Fighting · 2건

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

Use water spray, powder, foam, carbon dioxide.

First Aid Measures · 4건

Fresh air, rest. Refer for medical attention.

Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention .

First Aid · 2건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

(General first aid procedures)

Safe StorageKeep in a well-ventilated room. Separated from food and feedstuffs. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.
Exposure Control and Personal Protection · 2건

Biological Exposure Indices (BEI) [ACGIH] - Acetylcholinesterase activity in red blood cells = 70% of individual's baseline; Butylcholinesterase activity in serum or plasma = 60% of individual's baseline; Sample at end of shift; [TLVs and BEIs]

4.8 [mg/m3]

Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Spillage Disposal · 1건

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

Isolation and EvacuationExcerpt from ERG Guide 152 [Substances - Toxic (Combustible)]:
Eye PreventionWear face shield or eye protection in combination with breathing protection.
Fire PreventionNO open flames.
Inhalation RiskEvaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying.
Skin PreventionProtective clothing. Protective gloves.

독성 정보

Target OrgansEyes, skin, respiratory system, central nervous system, cardiovascular system, blood cholinesterase
Adverse EffectsOther Poison - Organophosphate
Exposure Routes · 2건

The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

inhalation, skin absorption, ingestion, skin and/or eye contact

Signs and Symptoms · 5건

Convulsions. Dizziness. Laboured breathing. Nausea. Pupillary constriction, muscle cramp, excessive salivation. Sweating. Unconsciousness.

MAY BE ABSORBED! See Inhalation.

Pupillary constriction. Blurred vision.

See Inhalation. Abdominal cramps. Diarrhoea. Vomiting.

irritation eyes, skin; ache eyes, rhinorrhea (discharge of thin nasal mucus); nausea, headache, dizziness, vomiting

ICSC Environmental DataThe substance is toxic to aquatic organisms. This substance may be hazardous to the environment. Special attention should be given to bees, mammals and birds. Avoid release to the environment in circumstances different to normal use.
Toxicity DataLCLo (cat) = 20 mg/m3/4hr

안전 데이터

OEB
C
OEL
TWA: 0.5 mg/m3 [skin]
ridadr
3018
독성
LD50 in rats (mg/kg): 50-75 orally, 300-400 dermally (Edson)
포장분류
II
위험 등급
6.1(a)
기존화학 물질
KE-05-0399
함량 및 규제정보
물질구분: 유독물질; 혼합물(제품)함량정보: 디메톤-메틸 및 이를 1% 이상 함유한 혼합물
유해화학물질 필터링
97-1-31