질산 바륨
질산,바륨염BARIUMDINITRATE · 이질산바륨 · 질산바륨 · 질산 바륨 · 이질산 바륨, 바륨염 · XSB · Barium(II) nitrate 99.999% · nitrobarite
식별자 및 물리적 특성
| CAS No. | 10022-31-8 |
|---|---|
| 분자식 | Ba(NO3)2 |
| 평균 분자량 | 261.34 g/mol |
| 단동위원소 질량 | 261.88088292 g/mol |
| SMILES | O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Ba+2] |
| InChIKey | IWOUKMZUPDVPGQ-UHFFFAOYSA-N |
| PubChem CID | 24798 |
| ChEMBL | CHEMBL3184584 |
| ChEBI | CHEBI:190440 |
| EC No. | 233-020-5 |
| DTXSID | DTXSID8049200 |
| 현지명 | 질산 바륨 |
화학 및 물리적 성질
| 극성 표면적 | 126 |
|---|---|
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 6 |
| 회전 가능 결합 수 | 0 |
| 무거운 원자 수 | 9 |
| 형식 전하 | 0 |
| 복잡도 | 18.8 |
| 물질 분류 | Metals -> Metals, Inorganic Compounds |
| SpringerMaterials Properties | dielectric constant |
| 농약 | RepellantsActive substance -> EU Pesticides database: Not approved |
| 냄새 | Odorless냄새 없는 |
| 밀도 | 3.24 at 73.4 °F (USCG, 1999) - Denser than waterwill sink3.24 g/cu cm3.24 g/cm³3.24 @25 °C3.23 |
| Color/Form | White cubic crystalsLustrous white crystalsCrystals or crystalline powder |
| 용해도 | 9 % (NIOSH, 2024)10.3 g/100 g water at 25 °CSlightly soluble in ethanol and acetoneSolubility in water as weight %: 4.72%, 0 °C9.27%, 25 °C12.35%, 40 °C16.9%, 60 °C21.4%, 80 °C25.6%, 100 °C32.0%, 135 °CSolubility in water, g/100ml at 20 °C: 8.7 (moderate)94g/L |
| 끓는 점 | Decomposes (NIOSH, 2024) |
| Decomposition | The substance decomposes on heating producing nitrogen oxides. |
| 녹는점 | 1098 °F (USCG, 1999)590 °C1094 °F592 °C (dec.)(lit.) |
| 증기압 | Low (NIOSH, 2024) |
| Physical Description | Barium nitrate appears as a white crystalline solid. Noncombustible, but accelerates burning of combustible materials. If large quantities are involved in fire or the combustible material is finely divided, an explosion may result. May explode under prolonged exposure to heat or fire. Toxic oxides of nitrogen produced in fires.Dry PowderLarge CrystalsCBIColorless or white odorless solid[HSDB] White odorless crystalline solidSlightly soluble in water[MSDSonline]COLOURLESS-TO-WHITE CRYSTALS OR CRYSTALLINE POWDER.White, odorless solid. |
| 저장 조건 | Store at +5°C to +30°C. |
| 물리적 상태 | 고체 |
| 비중 | 3.24 |
| 색상 | 하얀색 |
| pH | 5.0-8.0 (50g/l, H2O, 25℃) |
| Flame Color | Pale Green |
| 용해도 | 9g/100mL(20℃) |
| 비열 | Cp(crystal): 0.58 J/(g·K), at 25℃ |
| Merck | 14,983 |
| 유전율 | 5.8(0.0℃) |
| 안정성 | 안정적인. 강산화제 - 가연성 물질과 접촉하면 화재가 발생할 수 있습니다. 가연성 물질, 환원제, 산, 산무수물과 혼합할 수 없습니다. 수분에 민감합니다. |
| InChI | 1S/Ba.2NO3/c2*2-1(3)4/q+22*-1 |
| InChIKey | IWOUKMZUPDVPGQ-UHFFFAOYSA-N |
| SMILES | [Ba++].[O-][N+]([O-])=O.[O-][N+]([O-])=O |
| EPA | Barium nitrate (10022-31-8) |
화학적 성질
Barium nitrate is a shiny, white crystalline solid. It forms white crystals that are soluble in water at 20℃. It is formed by the reaction of barium carbonate or barium hydroxide with nitric acid. It is hazardous as magnesium plus barium oxide plus zinc, aluminum and magnesium alloys, combustibles (paper, oil, wood), acids, and oxidizers. Mixtures with nely divided aluminum-magnesium alloys are easily ignitable and extremely sensitive to friction or impact. Barium nitrate on contact with combustible materials will ignite. Barium nitrate mixed with aluminum powder, a formula for l ash powder is highly explosive.
안전 및 규제
| GHS 분류 | This chemical does not meet GHS hazard criteria for 1.2% (5 of 403) of reports.DangerH272 (68.7%): May intensify fireoxidizer [Danger Oxidizing liquidsOxidizing solids]P210, P220, P261, P264, P264+P265, P270, P271, P280, P301+P316, P301+P317, P304+P340, P305+P351+P338, P317, P321, P330, P337+P317, P370+P378, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 403 reports by companies from 16 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| 규제 정보 | Chemical: Nitric acid, barium saltNitric acid, barium salt (2:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Nitric acid, barium salt (2:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)2004/129/ECStatus: Active Update: 31-01-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/15841Nitric acid, barium salt: HSNO Approval: HSR001312 Approved with controlsThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| 기타 안전 정보 | Evaluation - Chemicals that are unlikely to require further regulation to manage risks to human health |
| 운송 라벨(DOT) | Oxidizer Poison |
| 화재 위험 | Special Hazards of Combustion Products: Yields toxic gaseous oxides of nitrogen when involved in fire.· These substances will accelerate burning when involved in a fire.Not combustible but enhances combustion of other substances. Risk of fire and explosion on contact with combustible substances or reducing agents. |
| 화재 가능성 | Not combustible but enhances combustion of other substances. |
| 건강 유해성 | Inhalation or contact with eyes or skin causes irritation. Ingestion causes excessive salivation, vomiting, colic, diarrhea, convulsive tremors, slow, hard pulse, elevated blood pressure. Hemorrhages may occur in the stomach, intestines, and kidneys. Muscular paralysis may follow. (USCG, 1999) |
용도
개요
Barium nitrate is a stable, strong oxidiser. It is incompatible with combustible material, reducing agents, acids, acid anhydrides, and moisture-sensitive substance. Barium nitrate is poisonous, is a respiratory irritant, and is hazardous if mixed with flammable materials. Barium oxide plus zinc, aluminium and magnesium alloys are combustibles (paper, oil, wood), acids, and oxidisers and is hazardous. Mixtures with finely divided aluminium–magnesium alloys are easily ignitable and extremely sensitive to friction or impact. Barium nitrate mixed with aluminium powder, a formula for flash powder, is highly explosive. However, barium nitrate is noncorrosive in presence of glass. It is used in military thermite grenades, in the manufacturing process of barium oxide, in the vacuum tube industry, and in pyrotechnics for green flame.
용도
Barium nitrate is used in industry in the production of green signal lights, to remove gases from vacuum tubes, and in the production of barium oxide.
일반 설명
A white crystalline solid. Noncombustible, but accelerates burning of combustible materials. If large quantities are involved in fire or the combustible material is finely divided, an explosion may result. May explode under prolonged exposure to heat or fire. Toxic oxides of nitrogen produced in fires.
제조 및 합성 방법
제조 방법
Barium Nitrate can be prepared by a number of methods. The reaction between nitric acid and barium metal is one way and reaction with BaO or BaCO3 is another. Barium hydroxide and ammonium nitrate also form the product but ammonia is released as a by-product: 2HNO3＋ Ba→Ba(NO3)2＋H2 2HNO3＋ BaO→Ba(NO3)2＋H2O Ba(OH)2＋ 2NH4NO3→Ba(NO3)2＋ 2NH3＋ 2H2O Barium nitrate can also be prepared by the reaction of barium carbonate or barium carbonate with nitric acid: BaCO3＋ 2HNO3→Ba(NO3)2＋ CO2＋H2O In this method, barium carbonate is suspended in nitric acid. The solution is filtered and the product crystallizes out. Alternatively, barium carbonate and nitric acid are added to a saturated solution of barium nitrate. The product is then obtained by crystallization. Barium nitrate may also be prepared by adding sodium nitrate to a saturated solution of barium chloride. Barium nitrate precipitates out from the solution. The precipitate is filtered, washed with alcohol and dried.