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기본 정보
- CAS
10026-11-6- 표준 SMILES
[Cl][Zr]([Cl])([Cl])[Cl]- InChIKey
DUNKXUFBGCUVQW-UHFFFAOYSA-J- 분자식
- Cl4Zr
- 평균 분자량
- 233.036 g/mol
- 단동위원소 질량
- 229.78011512
이름 및 식별자
- 우선 이름
- Zirconium(IV) chloride
- IUPAC
- Zirconium(4+) tetrachloride
- 현지명
- 사염화 지르코늄, 고체
- 영어명
- Zirconium tetrachloride
- 분자식
- Cl4Zr
- 분자량
- 233.04
이름 및 동의어
사염화지르코늄,고체사염화지르코늄,고체사염화지르코늄ZrCl4ZIRCONIUM(IV) CHLORIDEZIRCONIUM CHLORIDE(beta-4)-zirconiumchloride(zrcl4Zirconium(IV) Chloride 99.5%Zirconium(IV) chloride, anhydrous, powder, 99.99% metals basisZirconium(IV) chLZirconiuM(IV) chlortetrachlorozirconium
이름 더 보기
Zirconium tetrachlor
데이터베이스 식별자
- CAS
10026-11-6- PubChem CID
- 24817
- DTXSID
DTXSID1044142- ChEBI
CHEBI:77566- UNII
- Z88176T871
- EC Number
- 233-058-2
물성
물리화학적 성질
- 녹는점
- 437 °C · 437 °C
- 끓는 점
- 331 °C · 331°C
- 밀도
- 2.8 g/mL · 2.8 g/mL at 25 °C(lit.)
- 증기압
- 1 mm · 1 mm Hg ( 190 °C)
- 저장 조건
- 30 °C · Store below +30°C.
- 용해도
- 알코올, 에테르, 염산에 용해됩니다.
- 물리적 상태
- 가루
- 색상
- 하얀색
- Specific Gravity
- 2.803 · 2.803
- 수소이온지수(pH)
- 1 · <1 (H2O, 20℃)(saturated aqueous solution)
- 수용성
- 물과 반응합니다.
- 비열
- 0.51 J/ · Cp(crystal): 0.51 J/(g·K), at 25℃
- Merck
- 14 · 14,10174
- InChI
- 1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4
- InChIKey
- DUNKXUFBGCUVQW-UHFFFAOYSA-J
- SMILES
- Cl[Zr](Cl)(Cl)Cl
- NIST
- Zirconium tetrachloride(10026-11-6)
- EPA
- Zirconium tetrachloride (10026-11-6)
화학적 성질
Zirconium tetrachloride forms lustrous, white, monoclinic crystals that melt at 437 ℃. It is a corrosive powder. It is hygroscopic, and thus soluble in cold water, alcohol, ether, and concentrated hydrochloric acid. It reacts vigorously with water forming hydrogen chloride (irritating vapor) and zirconium oxychloride. When moist, zirconium tetrachloride reacts with common materials to form hydrochloric acid that is corrosive to many metals. Through hydrolysis to HCl, zirconium tetrachloride can irritate the respiratory tract and other superficial surfaces of the body on exposure. Zirconium tetrachloride readily forms coordinate bonds with oxygen and nitrogen in organic molecules.
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
안전 데이터
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- ZH7175000
- ridadr
- UN 2503
- 독성
- LD50 in mice, rats (mg/kg): 665, 1688 orally (Zhilova, Kasparov)
- HS 번호
- 2827 39 85
- risk_code
- 14-22-34-35
- hazard_code
- C
- safety_code
- 26-36/37/39-45-8
- 포장분류
- III
- 위험 등급
- 8
- 기존화학 물질
- KE-35654
- F 고인화성물질
- 19
- Hazard Classifications
- Met. Corr. 1Skin Corr. 1B
- 스토리지 클래스
- 8A - Combustible corrosive hazardous materials
- 유해 물질 데이터
- 10026-11-6(Hazardous Substances Data)
화학 및 산업
응용 분야
용도Zirconium tetrachloride is commonly utilized as a Lewis acid catalyst in many organic synthesis reactions. It is an important source for organometallic complexes of zirconium. It is practiced in many areas like nuclear industry, metal industry, photography, glass, and ceramic industry.
일반 설명White lustrous crystalline solid. Used as a source of pure zirconium, as a tanning agent, in analytical chemistry and in treating textiles. Zirconium tetrachloride is decomposed by water. Corrosive to metals in the presence of moisture and to tissue.
제조 방법
Zirconium tetrachloride is obtained as an intermediate in recovering zirconium metal from zircon and other minerals (See Zirconium, Recovery). The tetrachloride is obtained by heating a mixture of zirconium hydroxide and car 1004 bon with chlorine gasAlso, tetrachloride can be made by reacting zirconium hydroxide with hydrochloric acid: Zr(OH)4 + 4HCl → ZrCl4 + 4H2O.
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