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아황산칼륨

Potassium Sulfite

HCID 24958
노트반응
기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
10117-38-1
표준 SMILES
O=S([O-])[O-].[K+].[K+]
InChIKey
BHZRJJOHZFYXTO-UHFFFAOYSA-L
분자식
K2O3S
평균 분자량
158.26 g/mol
단동위원소 질량
157.884228

이름 및 식별자

우선 이름
Potassium Sulfite
IUPAC
dipotassium;sulfite
현지명
아황산칼륨
영어명
POTASSIUM SULFITE
분자식
H3KO3S
분자량
122.18

이름 및 동의어

POTASSIUM SULFITE10117-38-1Dipotassium sulfitePotassium sulphiteSulfurous acid, dipotassium saltPotassium sulfite (K2SO3)Sulfurous acid, potassium saltDIPOTASSIUM SULPHITEUNII-015KZC652EINS NO.225HSDB 5052015KZC652E
이름 더 보기
아황산칼륨아황산칼리(무수)아황산칼륨(POTASSIUMSULFITE)포타슘설파이트아황산칼륨(IV)KaliumsulfitdipotassiumsulfitePotassium sulfide anPotassium sulfite,ARPotassium sulfite ,95%potassiumsulfite(k2so3)POTASSIUMSULFITE,POWDERPotassiumsulfite,anhydrous
EINECS 233-321-1POTASSIUM SULFITE [MI]POTASSIUM SULFITE [FCC]POTASSIUM SULFITE [HSDB]DTXSID80889532INS-225EC 233-321-1E-225

데이터베이스 식별자

CAS
10117-38-1
PubChem CID
24958
DTXSID
DTXSID80889532
UNII
015KZC652E
EC Number
233-321-1
Nikkaji
J43.951G

물성

구조 계산 물성

극성 표면적
82.4 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
4
회전 가능 결합 수
0
무거운 원자 수
6
형식 전하
0
복잡도
18.8

실험 및 물리화학적 성질

Chemical ClassesOther Classes -> Sulfites
Cosmetics · 2건

Cosmetic ingredients (Potassium Sulfite) -> CIR (Cosmetic Ingredient Review)

Reducing; Preservative

Food AdditivesUse unspecified -> FDA Substance added to food
Solubility · 2건

White crystals or crystalline powder; sol in about 3.5 parts water; decomposed by diluted acids with evolution of sulfur dioxide; pH about 8 /dihydrate/

White-yellowish, hexagonal form; insol in ammonia; slightly sol in alcohol /dihydrate/

Physical Description · 2건

Liquid

Dihydrate: White solid; Slowly oxidized by air to sulfate; [Merck Index] White powder; [MSDSonline]

Stability/Shelf LifeGRADUALLY OXIDIZES IN AIR TO SULFATE. /DIHYDRATE/
Other Experimental PropertiesDecomposes on heating /dihydrate/

물리화학적 성질

밀도
2.353 · 2.353[at 20℃]
용해도
에탄올에 약간 용해됨

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 81.5% (242 of 297) of all reports.

Warning

H315 (16.5%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 297 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

유해성 정보

Regulatory Information · 4건

Chemical: Sulfurous acid, dipotassium salt

Sulfurous acid, potassium salt (1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfurous acid, potassium salt (1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Potassium sulphite (EC: 233-321-1)

Sulfurous acid, dipotassium salt: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Other Safety InformationIMAP assessments - Sulfurous acid, dipotassium salt: Environment tier I assessment
Hazards SummaryAn irritant; [MSDSonline] See SULFITES.
Hazard Classes and Categories · 2건

Skin Irrit. 2 (16.5%)

Acute toxicity - category 4

안전 및 보호

Storage Conditions

화학 및 산업

용도 및 제조

Uses · 6건

CIR ingredient: Potassium Sulfite

Used in photography, food and cosmetics (preservative and antioxidant), and drugs (cathartic and diuretic); [HSDB]

Photographic Processing [Category: Other]

Photography; preservative and antioxidant in foods

Medication: cathartic, diuretic

COMPONENT OF PHOTOGRAPHIC DEVELOPERS; FOOD ADDITIVE (EG, PRESERVATIVE & ANTIOXIDANT); INGREDIENT IN COSMETICS (EG, HAIR PREPARATIONS)

U.S. Exports · 2건

(1977) No Data

(1979) No Data

U.S. Imports · 2건

(1977) No Data

(1979) No Data

U.S. Production · 3건

2023: 100,000,000 - <250,000,000 lb

(1977) No Data

(1979) No Data

Consumer UsesEtching agent
Industry UsesReducing agent
Methods of ManufacturingPROBABLY BY THE ABSORPTION OF SULFUR DIOXIDE IN POTASSIUM CARBONATE OR POTASSIUM HYDROXIDE
Formulations/PreparationsGrades: technical; CP; FCC.
Use Classification · 2건

Food Additives -> ANTIOXIDANT; PRESERVATIVE -> JECFA Functional Classes

Cosmetics -> Reducing; Preservative

General Manufacturing Information · 2건

Pesticide, Fertilizer, and Other Agricultural Chemical Manufacturing

Sulfurous acid, potassium salt (1:2): ACTIVE

응용 분야

관련 반응

3건
반응 기록 만들기
HRID 1074217 반응식
HRID 1074217반응물로uspto-grants-1990_11
HRID 1947213 반응식
HRID 1947213반응물로uspto-grants-2013_03
HRID 2206963 반응식
HRID 2206963반응물로uspto-grants-2016_06

화합물 노트

불러오는 중…

이 페이지에서기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
물리적 상태
powder
색상
colorless hexagonal, hexane crystals, crystalline
냄새
냄새 없는
수용성
1060 g/L · 1060g/L at 25℃
Merck
13 · 13,7761
화장품 원료 기능
헤어 웨이브 또는 스트레이트피부의 산화 스트레스를 줄이세요항균 방부제항산화제
InChI
InChI=1S/K.H2O3S.H/c;1-4(2)3;/h;(H2,1,2,3);
InChIKey
FOWJHTPNXPDZQJ-UHFFFAOYSA-N
SMILES
S(O)(O)=O.[KH]
EPA
Potassium sulfite (10117-38-1)

화학적 성질

Potassium sulfite, K2SO3·2H2O; potassium hydrogen sulfite, KHSO3; white solids, similar in properties and formation to the corresponding sodium sulfites.

KEEP WELL CLOSED IN COOL PLACE. /DIHYDRATE/
Disposal Methods · 1건

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

독성 정보

Adverse EffectsAsthma - Reversible bronchoconstriction (narrowing of bronchioles) initiated by the inhalation of irritating or allergenic agents.
Toxicity SummarySafe in the present practices of use and concentration. Ingredient, concentration, and use information are available in documents discoverable at https://cir-reports.cir-safety.org
Human Toxicity Excerpts · 1건

WHEN INGESTED, SOLN CAUSE GASTRIC IRRITATION BY LIBERATION OF SULFUROUS ACID. BECAUSE OF RAPID OXIDATION TO SULFATE, SULFITES ARE WELL TOLERATED UNTIL LARGE DOSES ARE REACHED; THEN VIOLENT COLIC & DIARRHEA, CIRCULATORY DISTURBANCES, CENTRAL NERVOUS DEPRESSION, & DEATH ARE DESCRIBED. /SULFITE SALTS/

Populations at Special RiskSome asthmatics are said to be dangerously sensitive to minute amounts of sulfites in foods. /Sulfites/
Antidote and Emergency Treatment · 3건

TREATMENT IS SYMPTOMATIC & SUPPORTIVE. /SULFITE SALTS/

Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 m1/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Administer activated charcoal ... . Cover skin burns with dry sterile dressings after decontamination ... . /Sulfur and related compounds/

Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious. Early intubation at the first sign of upper airway obstruction may be necessary. Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start an IV with D5W /SRP: "To keep open", minimal flow rate/. Use lactated Ringer's if signs of hypovolemia are present. Watch for signs of fluid overload. Consider drug therapy for pulmonary edema ... . Treat seizures with diazepam (Valium) ... . For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors for hypotension with a normal fluid volume. Watch for signs of fluid overload ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Sulfur and related compounds/

안전 데이터

wgk
1
tsca
TSCA listed
HS 번호
2832200000
risk_code
36/37/38-31
hazard_code
Xi
safety_code
26-36
기존화학 물질
KE-29203
F 고인화성물질
9
스토리지 클래스
11 - Combustible Solids
유해 물질 데이터
10117-38-1(Hazardous Substances Data)

용도Potassium Sulfite is used as a fabric treatment chemical.

상·하류 제품 정보

상류 원료

탄산 칼륨이산화 황탄산나트륨(경회)

공급사100 곳

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추가 설명 · 1건

정의potassium sulphite: A white crystallinesolid, K2SO3, soluble in waterand very sparingly soluble inethanol; r.d. 1.51; decomposes onheating. It is a reducing agent and isused as such in photography and inthe food and brewing industries,where it prevents oxidation.