기본 정보
- CAS
13465-09-3- 표준 SMILES
[Br][In]([Br])[Br]- InChIKey
JKNHZOAONLKYQL-UHFFFAOYSA-K- 분자식
- Br3In
- 평균 분자량
- 354.53 g/mol
- 단동위원소 질량
- 351.65889
개요
Indium(III) bromide is a chemical compound of indium and bromine. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625)
이름 및 식별자
- 우선 이름
- Indium tribromide
- IUPAC
- tribromoindigane
- 현지명
- 인듐(III)브로마이드
- 영어명
- INDIUM(III) BROMIDE
- 분자식
- Br3In
- 분자량
- 354.53
이름 및 동의어
Indium tribromidetribromoindiganeIndium bromide (InBr3)DTXSID50654850099V88160RefChem:1087290DTXCID8034243236-692-813465-09-3Indium(III) bromidetribromoindiumInBr3
이름 더 보기
인듐(III)브로마이드INDIUM BROMIDEIndium(Ⅲ) bromideindiumbromide(inbr3)Indium(III) tribromideIII)Indium(III bromide
MFCD00011057Indium(III) bromide, anhydrousIndium bromideIndium(III) bromide, 99%SCHEMBL151438EINECS 236-692-8UNII-0099V88160AKOS040765860
데이터베이스 식별자
- CAS
13465-09-3- PubChem CID
- 26046
- DTXSID
DTXSID5065485- EC Number
- 236-692-8
물성
구조 계산 물성
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 0
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 4
- 형식 전하
- 0
- 복잡도
- 8
실험 및 물리화학적 성질
Chemical ClassesMetals -> Metals, Inorganic Compounds
Physical DescriptionWhite solid; [Merck Index] Yellowish odorless crystalline powder; [MSDSonline]
물리화학적 성질
- 녹는점
- 220 °C · 220 °C(lit.)
- 끓는 점
- 656 °C · 656 °C(lit.)
- 밀도
- 4.96 g/mL · 4.96 g/mL at 25 °C(lit.)
- 증기 밀도
- 1 · >1 (vs air)
- 저장 조건
- Inert atmosphere,Room Temperature
- 물리적 상태
- 결정성 분말
- 색상
- 흰색에서 노란색으로
- Specific Gravity
- 4.74 · 4.74
- 수용성
- 물에 용해됩니다.
- 안정성
- 흡습성
- InChI
- InChI=1S/3BrH.In/h3*1H;/q;;;+3/p-3
- InChIKey
- JKNHZOAONLKYQL-UHFFFAOYSA-K
- SMILES
- [In](Br)(Br)Br
- EPA
- Indium bromide (InBr3) (13465-09-3)
화학적 성질
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
Danger
H314 (14%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
P260, P261, P264, P264+P265, P271, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P319, P321, P332+P317, P337+P317, P362+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 50 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Hazards SummaryA corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline] See Bromine. See Indium.
Hazard Classes and CategoriesSkin Corr. 1B (14%)
안전 및 보호
Threshold Limit Values (TLV)0.1 [mg/m3], as In
독성 정보
Treatment
EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.
화학 및 산업
약리 정보
Metabolism/Metabolites
Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)
용도 및 제조
UsesUsed as regio-, chemo-, and stereoselective Lewis acid catalyst in organic synthesis; [Merck Index]
General Manufacturing InformationIndium bromide (InBr3): ACTIVE
응용 분야
용도"Indium(III) bromide is used in organic synthesis as a water tolerant Lewis acid.It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones. It is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells."
제조 방법
According to Thiel, metallic In is heated in a fast air-free stream of CO2, which is saturated with Br2 vapor by passage through a wash bottle containing Br2 (the bottle should be placed in a warm water bath). A melt of InBr and InBr3 forms first. This melt is brown at first, but gradually becomes lighter. Finally it turns to solid InBr3. The latter can be readily sublimed to form lustrous crystalline spangles.
공급사86 곳
阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]
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