Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
테트라암모니움 헥사사이아노페레이트
테트라암모니움헥사사이아노페레이트 · 페로시안화 암모늄 · 테트라암모늄페로시안화물 · AMMONIUM FERROCYANIDE · FERROUS AMMONIUM CYANIDE · Tetraammonium ferrocyanide · AMMONIUM HEXACYANOFERRATE II · tetraammoniumhexacyanoferrate
식별자 및 물리적 특성
| CAS No. | 14481-29-9 |
|---|---|
| 분자식 | C6H16FeN10 |
| 평균 분자량 | 284.1 g/mol |
| 단동위원소 질량 | 284.09087801 g/mol |
| SMILES | [C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[Fe+2].[NH4+].[NH4+].[NH4+].[NH4+] |
| InChIKey | ZXQVPEBHZMCRMC-UHFFFAOYSA-R |
| PubChem CID | 26708 |
| EC No. | 238-476-9 |
| DTXSID | DTXSID1051725 |
| 현지명 | 테트라암모니움 헥사사이아노페레이트 |
화학 및 물리적 성질
| 극성 표면적 | 147 |
|---|---|
| 수소 결합 공여자 수 | 4 |
| 수소 결합 수용자 수 | 12 |
| 회전 가능 결합 수 | 0 |
| 무거운 원자 수 | 17 |
| 형식 전하 | 0 |
| 복잡도 | 10 |
| 물질 분류 | Nitrogen Compounds -> Ammonium Compounds |
| Color/Form | Yellow crystalsTURNS BLUE IN AIR |
| 용해도 | Freely sol in waterpractically insol in alcohol /Trihydrate/soluble in H2Oinsoluble in ethanol |
| Physical Description | Yellow solidTurns blue in air[HSDB] Light green powder[MSDSonline] |
| Stability/Shelf Life | LOSES NH3 ON EXPOSURE TO AIR & LIGHTDECOMP ON HEATING /TRIHYDRATE/ |
| Other Experimental Properties | Yellow crystalline powder /Trihydrate/ |
| 녹는점 | >300°C |
| 물리적 상태 | 가루 |
| 색상 | 노란색에서 녹색으로 |
| 용해도 | 삼수화물 용해성 H2O [MER06] |
| Merck | 14,520 |
| EPA | Ferrate(4-), hexakis(cyano-.kappa.C)-, tetraammonium, (OC-6-11)- (14481-29-9) |
화학적 성질
green fine crystalline powder
안전 및 규제
| GHS 분류 | This chemical does not meet GHS hazard criteria for 2.2% (1 of 45) of reports.WarningH302 (88.9%): Harmful if swallowed [Warning Acute toxicity, oral]P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 45 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| 규제 정보 | Restricted substance: Tetraammonium hexacyanoferrate |
| 유해성 요약 | Emergency treatment: Irritants[HSDB] Ferrocyanide complexes are stable and practically nontoxic because of the strong bonding between iron and cyanide. Cyanide ions may be formed slowly when the chemical is irradiated with UV light. [Ullmann] May cause irritation[MSDSonline] |
| RCRA 요건 | /SRP:/ D003A solid waste containing ammonium ferrocyanide may become characterized as a hazardous waste when subjected to testing for reactivity as stipulated in 40 CFR 261.23, and if so characterized, must be managed as a hazardous waste. |
| EPA Hazardous Waste Number | D003/SRP:/ A waste containing ammonium ferrocyanide may (or may not) be characterized a hazardous waste following testing for the reactivity characteristics as prescribed by the Resource Conservation and Recovery Act (RCRA) regulations. |
| 청정수법 요건 | Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Cyanides/ |
| Hazard Classes and Categories | Acute Tox. 4 (88.9%) |
| Hazardous Reactivities and Incompatibilities | At 220 °C interaction with ammonium hexacyanoferrate is explosive in wet mixtures, or in dry mixtures if the nitrate is in excess. |
| 보관 조건 | PROTECT FROM LIGHT. |
| 처리 방법 | Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number D003, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste. |