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포름산암모늄

Ammonium formate

HCID 2723923
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
540-69-2
표준 SMILES
O=C[O-].[NH4+]
InChIKey
VZTDIZULWFCMLS-UHFFFAOYSA-N
분자식
CH2O2.H3N
평균 분자량
63.056 g/mol
단동위원소 질량
63.0320284

개요

Ammonium formate is a white solid with a weak odor of ammonia. Sinks and mixes slowly with water. (USCG, 1999)

이름 및 식별자

우선 이름
Ammonium formate
IUPAC
azanium formate
현지명
포름산암모늄
영어명
Ammonium formate
분자식
CH5NO2
분자량
63.06

이름 및 동의어

AMMONIUM FORMATE540-69-2Formic acid, ammonium saltMravencan amonnyFormic acid, ammonium salt (1:1)3801F9644EDTXSID6029624CHEBI:63050RefChem:5549DTXCID309624208-753-9azanium;formate
이름 더 보기
포름산암모늄폼산암모늄폼산암모늄HCOONH4AMMONIUM FORMATAmmomium formateHCOONH4 CH5NO2mravencanamonny97.0%， for HPLCFormiate ammoniaammmonium formate
Formic acid ammonium saltammoniumformateammonium formiateazanium formateMFCD00013103Mravencan amonny [Czech]Amoniumformiateammonia formate

데이터베이스 식별자

CAS
540-69-2、70179-79-2
PubChem CID
2723923
DTXSID
DTXSID6029624
ChEBI
CHEBI:63050
UNII
3801F9644E
EC Number
208-753-9

물성

구조 계산 물성보충 중

극성 표면적
41.1 Ų
수소 결합 공여자 수
1
수소 결합 수용자 수
2
회전 가능 결합 수
0
무거운 원자 수
4
형식 전하
0
복잡도
7.5

실험 및 물리화학적 성질

Chemical ClassesNitrogen Compounds -> Ammonium Compounds
Density · 3건

1.28 at 77 °F (USCG, 1999) - Denser than water; will sink

1.280

1.26 @25 °C

Color/FormWHITE MONOCLINIC CRYSTALS
SolubilityIN WATER: 102 G/100 CC @ 0 °C, 531 G/100 CC @ 80 °C; SOL IN ETHER, AMMONIA
Boiling Point · 2건

180 °C DECOMP

180 °C @760 [mm Hg]

DecompositionWhen heated to decomp ... emits toxic fumes of /nitrogen oxides and ammonia/.
Melting Point · 3건

241 °F (USCG, 1999)

116 °C

116 °C

Physical Description · 3건

Ammonium formate is a white solid with a weak odor of ammonia. Sinks and mixes slowly with water. (USCG, 1999)

Dry Powder; Liquid

Deliquescent solid; [Hawley] White in color, weak odor of ammonia; [CAMEO] Soluble in water; [MSDSonline]

Other Experimental PropertiesDELIQUESCES

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 17.6% (59 of 335) of reports.

Warning

H315 (66.3%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 335 reports by companies from 24 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Not Classified

유해성 정보

Regulatory Information · 5건

Chemical: Formic acid, ammonium salt

Regulation (EC) No 1831/2003 (amended)

Formic acid, ammonium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Formic acid, ammonium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 07-05-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/30306

Formic acid, ammonium salt: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Formic acid, ammonium salt: Environment tier I assessment
Fire HazardsSpecial Hazards of Combustion Products: Toxic and irritating ammonia and formic acid gases may form in fire. (USCG, 1999)
Health HazardsInhalation causes irritation of nose and throat. Ingestion irritates mouth and stomach. Contact with eyes or skin causes irritation. (USCG, 1999)
Hazards SummaryA skin and mucous membrane irritant; [HSDB]

화학 및 산업

용도 및 제조

Uses · 3건

Use in chemical analysis; [Merck Index] Used as a buffer; [CHEMINFO]

CHEM ANAL TO PPT BASE METALS FROM SALTS OF NOBLE METALS

BUFFER

U.S. Production2023: 550,000 - <1,000,000 lb
Consumer UsesSoil amendments (fertilizers)
Industry UsesPlating agent
Methods of ManufacturingPREPD FROM FORMIC ACID & AMMONIA: ZUFFANTI, J AM CHEM SOC 63, 3123 (1941).
General Manufacturing Information · 3건

Not Known or Reasonably Ascertainable

Formic acid, ammonium salt (1:1): ACTIVE

FORMATES ARE COMMONLY USED FOOD PRESERVATIVES.

응용 분야 · 3건

용도분석용 시약 : 중금속 이온과 염기성염의 침전을 만든다. 그들 중 (A) 비스무트와의 침전 반응은 중량법에 의한 비스무트의 정량에, (B) 철(Ⅲ)과의 침전 반응은 다른 금속 원소에서 철을 분리 제거할 때에, (C) 토륨과의 침전 반응은 란탄족 원소에서 토륨을 분리할 때에 이용된다.

용도포름아마이드(Formamide) 또는 메탄아마이드는 포름산에서 나오는 아마이드이다. 물과 섞일 수 있으며 암모니아와 같은 냄새가 나는 투명한 액체이다. 의약품, 다른 의약품, 제초제, 살충제 및 시안화 수소산의 제조를 위한 화학 원료로 쓰이며, 종이와 섬유의 연화제로 사용되어 왔다. 또 여러 가지 이온화합물에 용매로 쓰이며, 수지 및 가소제의 용제로도 사용되었다.

용도Pure ammonium formate decomposes into formamide and water when heated, and this is its primary use in industry. Formic acid can also be obtained by reacting ammonium formate with a dilute acid, and since ammonium formate is also produced from formic acid, it can serve as a way of storing formic acid. In chemical analysis, especially to ppt base metals from salts of the "noble" metals. Ammonium formate can also be used in palladium on carbon (Pd / C) reduction of functional groups. In the presence of Pd / C, ammonium formate decomposes to hydrogen, carbon dioxide, and ammonia. Ammonium formate can be used for reductive amination of aldehydes and ketones (Leuckart reaction) Ammonium formate can be used as a buffer in high performance liquid chromatography (HPLC), and is suitable for use with liquid chromatography/mass spectrometry (LC/MS). .

관련 반응

3,036건
반응 기록 만들기
HRID 1252 반응식
HRID 1252반응물로uspto-grants-1998_03
HRID 1885 반응식
HRID 1885반응물로uspto-grants-1998_03
HRID 1976 반응식
HRID 1976반응물로uspto-grants-1998_03
HRID 5652 반응식
HRID 5652반응물로uspto-grants-1993_09
HRID 5653 반응식
HRID 5653반응물로uspto-grants-1993_09
HRID 5866 반응식
HRID 5866반응물로uspto-grants-1993_09
HRID 5867 반응식
HRID 5867반응물로uspto-grants-1993_09
HRID 5962 반응식
HRID 5962반응물로uspto-grants-1993_09
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물리화학적 성질

녹는점
119 · 119-121 °C (lit.)
끓는 점
103.28 °C · 103.28°C (rough estimate)
밀도
1.26 g/mL · 1.26 g/mL at 25 °C (lit.)
증기압
0.033 Pa · 0.033Pa at 25℃
굴절률
1.4164 · 1.4164 (estimate)
인화점
104 ℃ · 104℃
저장 조건
Inert atmosphere,Room Temperature
용해도
2 O: · H2O: 10 M at 20 °C, 투명, 무색
물리적 상태
고체
색상
하얀색
냄새
약간의 포름산 냄새
수소이온지수(pH)
6.53 · 6.53(1 mM solution);6.5(10 mM solution);6.49(100 mM solution);6.45(1000 mM solution)
수용성
녹는
Merck
14 · 14,523
BRN
3625095 · 3625095
안정성
안정적인. 흡습성. 강산, 강산화제와 호환되지 않습니다.
InChI
1S/CH2O2.H3N/c2-1-3;/h1H,(H,2,3);1H3
InChIKey
VZTDIZULWFCMLS-UHFFFAOYSA-N
SMILES
N.OC=O
LogP
-3.34 at · -3.34 at 25℃
EPA
Ammonium formate (540-69-2)
화학적 성질 · 1건

Ammonium formate, NH4HCO2, is the ammonium salt of formic acid. It is a colorless, hygroscopic, crystalline solid. It can be synthesized through treating ammonium carbonate with 85% formic acid. It is widely used in many organic reactions such as Leuckart reaction which is the reductive amination of aldehydes and ketones. It can also be used as a buffer in HPLC and LC/MS test. Moreover, it is also used in palladium on carbon (Pd/C) reduction of functional group. It can also be used for the preparation of formic acid in situ as well as being used to store formic acid.Common HPLC Buffers: Ammonium formate (2.7<PH<3.7) does a fairly good job of filling the gap at the low-pH end.

Reactive Group
Salts, Acidic
Reactivity Profile · 1건

Acidic salts, such as AMMONIUM FORMATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Air and Water ReactionsWater soluble.
Hazard Classes and CategoriesSkin Irrit. 2 (66.3%)

안전 및 보호

Fire FightingFire Extinguishing Agents: Water, foam (USCG, 1999)
First AidINHALATION: remove to fresh air.
Storage ConditionsKEEP TIGHTLY CLOSED.
Protective Action Criteria (PAC) · 3건

3.7 [mg/m3]

41 [mg/m3]

240 [mg/m3]

Personal Protective Equipment (PPE)Dust mask; goggles or face shield; rubber gloves (USCG, 1999)

독성 정보

Human Toxicity Excerpts · 2건

STRONG SOLN MAY BE IRRITATING TO SKIN AND MUCOUS MEMBRANES.

...WITH LARGE DOSES OF...AMMONIUM /SALTS/, THERE ARISES THE POSSIBILITY OF SUFFICIENT ABSORPTION TO PRODUCE DIURESIS & SYSTEMIC AMMONIA POISONING, PARTICULARLY IF MATERIAL IS ADMIN PARENTERALLY. /AMMONIUM SALTS/

안전 데이터

wgk
2
tsca
TSCA listed
rtecs
BQ6650000
독성
LD50 orl-mus: 2250 mg/kg ZERNAL 9,332,69
HS 번호
2915120000
risk_code
36/37/38
hazard_code
Xi
safety_code
26-36-37/39
기존화학 물질
KE-17235
F 고인화성물질
3-10
Hazard Classifications
Eye Irrit. 2
스토리지 클래스
11 - Combustible Solids
유해 물질 데이터
540-69-2(Hazardous Substances Data)

상·하류 제품 정보

상류 원료

p-클로로벤즈알데히드개미산암모니아(가스)

하류 제품

3-Azetidinecarboxylic acid4-(트리플루오로메틸)피리딘-3-카복실산(R)-(-)-2-아미노헵탄5-Fluoro-2-picolinic acid(1,3,5-트리메틸-1H-피라졸-4-일)메틸아민1-N-Boc-3-하이드록시아제티딘C-(1-메틸-피페리딘-2-YL)-메틸아민4-METHYL-1,3-OXAZOLE-5-카르복실산1,2,4-트리아졸시트라진산4-메틸록사졸-5-카르보닐염화물3,4,5-Trimethoxybenzylamine5-(아미노메틸)-2,3-디하이드로벤조[B]푸란4-Chloro-7-methylthieno[3,2-d]pyrimidineTeicoplanin A2클로로(3-)벤질아민페닐에틸아민4-Aminotetrahydropyran5-Chloro-1H-indazole-3-carboxylic acid4-Chloro-2-methylbenzylamine7-Methylthieno[3,2-d]pyrimidin-4(3H)-one(4S)-Hydroxy-3-methyl-2-(2-propenyl)-2-cyclopentene-1-one3-(4-모르폴리닐)아닐린5-amino-1H-Indole-2-carboxylic acid ethyl ester5-Azaindole(1H-INDAZOL-3-YL)-아세트산4-히드록시-3-메톡시벤질아민 염화수소산염3-Amino-5-fluoropyridine1-페닐에틸아민1-(4-클로로페녹시)-3,3-다이메틸-1-(1H-1,2,4-트리아졸-1-일)-2- 부타논Ethyl 5-amino-1H-indole-2-carboxylate3,5-Bis(trifluoromethyl)benzylamine3-Amino-4-methoxybenzoic acid2,5-디메톡시벤질아민

추가 설명

정의ChEBI: Ammonium formate is the ammonium salt of formic acid. It has a role as a buffer. It is functionally related to a formic acid.