Dimethyl(methylene)ammounium iodide

HCID 2724133

기본 정보

CAS
33797-51-2
표준 SMILES
C=[N+](C)C.[I-]
InChIKey
VVDUZZGYBOWDSQ-UHFFFAOYSA-M
분자식
C3H8IN
평균 분자량
185.01 g/mol

이름 및 식별자

우선 이름
Dimethyl(methylene)ammounium iodide
IUPAC
dimethyl(methylidene)azanium iodide
영어명
N,N-DiMethylMethyleneaMMoniuM Iodide
분자식
C3H8IN
분자량
185.01

이름 및 동의어

33797-51-2Eschenmoser's saltN,N-Dimethylmethyleneammonium iodideN,N-Dimethylmethyleneiminium iodideN-methyl-N-methylenemethanaminium iodideDimethyl(methylene)ammounium iodide5C42I004S1Methanaminium, N-methyl-N-methylene-, iodideEINECS 251-680-2ESCHENMOSER'S REAGENTDIMETHYL(METHYLENE)AMMONIUM IODIDEMethylenedimethylammonium iodide
이름 더 보기
DIMETHYL METHYLENEIMMONIUM IODIDEeneammonium IodideEschenmoser's salt ,97%eschenmoser's iodide saltdimethyl(methylidene)azaniumdimethylmethylammonium iodideMethylenedimethyliminium·iodide
DIMETHYL(METHYLENE)AMMONIUM IODIDE [MI]N,N-DIMETHYLAMINOMETHYLENEAMMONIUM IODIDERefChem:588402DTXCID20320151N,NDimethylmethyleneammonium iodide36627-00-6DTXSID10369115dimethyl(methylidene)azanium iodide

데이터베이스 식별자

CAS
33797-51-2
PubChem CID
2724133
UNII
5C42I004S1
EC Number
251-680-2

물성

구조 계산 물성

극성 표면적
3 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
1
회전 가능 결합 수
0
무거운 원자 수
5

실험 및 물리화학적 성질

Chemical ClassesNitrogen Compounds -> Other Nitrogen Compounds
Physical DescriptionColorless solid; [Merck Index] Light yellow powder; [Sigma-Aldrich MSDS]

물리화학적 성질

녹는점
219 °C · 219 °C (dec.)(lit.)
밀도
1.7217 · 1.7217 (estimate)
저장 조건
2 · Keep in dark place,Inert atmosphere,2-8°C
용해도
디메틸포름아미드에 용해됩니다. 아세토니트릴, 테트라히드로푸란 및 디클로로메탄에 부분적으로 용해됩니다.
물리적 상태
결정성 분말
색상
크림색에서 노란색으로

화학적 성질

CREAM TO YELLOW CRYSTALLINE POWDER

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazards SummaryA skin and strong eye irritant; [Sigma-Aldrich MSDS] See Iodine for the TLV of Iodides.
Hazard Classes and CategoriesSkin Irrit. 2 (100%)

안전 및 보호

Threshold Limit Values (TLV)0.01 [ppm], inhalable fraction and vapor, (iodides)

안전 데이터

wgk
3
HS 번호
29239000
risk_code
36/37/38
hazard_code
Xi
safety_code
26-36
F 고인화성물질
8-10-21

화학 및 산업

용도 및 제조

UsesUsed in organic synthesis; [Merck Index]
응용 분야 · 3건

개요N, N-Dimethylmethyleneammonium iodide (DMMIA) is a versatile quaternary ammonium compound characterized by its unique chemical structure and widely utilized in scientific research. This colorless salt readily dissolves in water and has a melting point of 197°C. DMMIA is a crucial reagent in various laboratory experiments, contributing significantly to synthesis processes. Moreover, it finds application in biochemical studies, showcasing diverse biochemical and physiological effects. Its importance in scientific research is evident, as it serves as a reagent for organic synthesis, a catalyst for alcohol oxidation, and a key component in producing heterocyclic compounds. Additionally, it is utilized in synthesizing surfactants and other amphiphilic molecules. Furthermore, DMMIA aids in studying enzyme kinetics by effectively inhibiting certain enzyme activities.

용도In organic synthesis.

일반 설명N,N-Dimethylmethyleneiminium iodide is useful reagent for many synthetic applications, especially aminomethylation and conversion of ketones to α,βunsaturated enones.

공급사100 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
郑州阿尔法化工有限公司+86-18530059196 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
武汉英诺医药科技有限公司+86-027-59232304 15387063101 · [email protected]

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