CAS 65201-77-6 Tetrabutylammonium Periodate (HCID 2724292)

기본 정보

CAS: 65201-77-6
표준 SMILES: CCCC[N+](CCCC)(CCCC)CCCC.[O-][I+3]([O-])([O-])[O-]
InChIKey: PYVXLMQALOZKES-UHFFFAOYSA-M
분자식: C16H36INO4
평균 분자량: 433.37 g/mol

이름 및 식별자

우선 이름: Tetrabutylammonium Periodate
IUPAC: tetrabutylazanium periodate
현지명: 테트라부틸암모늄 (메타)퍼아이오데이트
영어명: Tetrabutylammonium periodate
분자식: C16H36INO4
분자량: 433.37

이름 및 동의어

Tetrabutylammonium periodate65201-77-6EINECS 265-614-5RefChem:188414265-614-5tetrabutylazanium;periodateMFCD00011852tetrabutylazanium periodaten-tetrabutylammonium periodateN,N,N-Tributyl-1-butanaminium Periodate; N,N,N-Tributyl-1-butanaminium Salt With Periodic Acid (HIO4); N,N,N-Tributyl-1-butanaminium Periodate (IO41-); Tetrabutylammonium Metaperiodate; Tetrabutylammonium Periodatetetrabutylammonium;periodateTetra-n-butylammonium periodate

이름 더 보기

테트라부틸암모늄(메타)퍼아이오데이트테트라뷰틸암모늄 퍼아이오데이트etrabutylazanium,periodateTetra-n-butylammoniumperiodateTETRABUTYLAMMONIUM(META)PERIODATTetrabutylammonium periodate,99%TETRABUTYLAMMONIUM (META)PERIODATETetrabutylaminium·periodic acidanionTetra-n-butylaMMoniuM (Meta)periodate, 97%TETRABUTYLAMMONIUM (META)PERIODATE, MOIS T. W. ~10% WATER

C16H36INO4CHEMBL1078235Tetra-n-butylammonium (meta)periodateAKOS025243447CS-W011619AS-75489SY107079DB-054773

데이터베이스 식별자

CAS: 65201-77-6
PubChem CID: 2724292
ChEMBL: CHEMBL1078235
EC Number: 265-614-5

물성

구조 계산 물성

극성 표면적: 74.3 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 4
회전 가능 결합 수: 12
무거운 원자 수: 22
형식 전하: 0
복잡도: 212

물리화학적 성질

녹는점: 175 °C · 175 °C (dec.) (lit.)
밀도: 1.2302 · 1.2302 (estimate)
저장 조건: 2 · Storage temp. 2-8°C
용해도: 클로로포름 (약간 용해됨), DMSO (약간 용해됨)
물리적 상태: 고체
BRN: 4621593 · 4621593
InChI: 1S/C16H36N.HIO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
InChIKey: PYVXLMQALOZKES-UHFFFAOYSA-M
SMILES: [O-]I(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC

화학적 성질

yellow crystalline powder

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H272 (97.5%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesOx. Sol. 2 (97.5%)

안전 데이터

wgk: 3
ridadr: UN 1479 5.1/PG 2
HS 번호: 29239000
risk_code: 8-36/37/38-20/22
hazard_code: O,Xi,Xn
safety_code: 17-26-36-37/39
포장분류: II
위험 등급: 4.1
F 고인화성물질: 8
Hazard Classifications: Eye Irrit. 2Ox. Sol. 2Skin Irrit. 2STOT SE 3
스토리지 클래스: 5.1B - Oxidizing hazardous materials

화학 및 산업

응용 분야

개요Tetrabutylammonium periodate is useful reagent in oxidation of sulfides, phenacyl bromides, benzyl halides, phosphites; oxidative decarboxylation; co-oxidant in metal-catalyzed oxidation.

용도Tetrabutylammonium (meta)periodate (DCM) can be oxidated for the synthesis of aryl nitroso derivatives. It can also be used in the formation of an ionic liquid for the synthesis of aromatic carboxylic acids.