[1,3- 비스 (디 페닐 포스 피노) 프로판] 디클로로 니켈 (II)

Dichloro(1,1'-(1,3-propanediyl)bis(1,1-diphenylphosphine-kappaP))nickel

HCID 2724937CAS 15629-92-2
부분 구조 검색유사 구조 찾기

기본 정보

표준 SMILES
[Cl][Ni][Cl].c1ccc(P(CCCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1
InChIKey
ZBQUMMFUJLOTQC-UHFFFAOYSA-L
분자식
C27H26Cl2NiP2
평균 분자량
542 g/mol
단동위원소 질량
540.024022

이름 및 식별자

우선 이름
Dichloro(1,1'-(1,3-propanediyl)bis(1,1-diphenylphosphine-kappaP))nickel
IUPAC
dichloronickel;3-diphenylphosphanylpropyl(diphenyl)phosphane
현지명
[1,3- 비스 (디 페닐 포스 피노) 프로판] 디클로로 니켈 (II)
영어명
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
분자식
C27H26Cl2NiP2
분자량
542.04

이름 및 동의어

15629-92-2RefChem:586663Dichloro(1,1'-(1,3-propanediyl)bis(1,1-diphenylphosphine-kappaP))nickel1,3-Bis(diphenylphosphino)propane nickel(II) chloride[1,3-Bis(diphenylphosphino)propane]nickel(II) chlorideNi(dppp)Cl2[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)(1,3-dppp)NiCl21,3-Bis(diphenylphosphino)propane nickel (II) chloride1,3-Bis(diphenylphosphino)propane nickel(II)chloridedichloronickel;3-diphenylphosphanylpropyl(diphenyl)phosphaneNiCl2(dppp)
이름 더 보기
[1,3-비스(디페닐포스피노)프로판]디클로로니켈(II)1,3-비스(디페닐포스피노)프로판니켈디염화물1,3-비스(디페닐포스피노)프로판니켈디염화물(1,3-BIS(DIPHENYLPHOSPHINO)PROPANEN...NiCl2(DPPP)NiCl2(DPPP)1.3-Bis(dipheny phosphine) propane nickel(II)chlorideDichloro[bis(1,3-diphenylphosphino)propane]nickel(II)1,3-Bis(diphenyl phosphine)propane nickel(II)dichloride1,3-B
C27H26Cl2NiP2(1,3-Bis(diphenylphosphino)propane)dichloronickel; 1,3-Bis(diphenylphosphino)nickel Dichloride; Dichloro[1,3-bis(diphenylphosphino)propane]nickel; Nickel 1,3-Bis(diphenylphosphino)propane Dichloride; (1,3-dppp)NiCl2;SCHEMBL6328AKOS005259144AC-4982FD14035[1,3-Bis(diphenylphosphino)propane] dichloronickel?3-diphenylphosphanylpropyl(diphenyl)phosphane dichloronickel

데이터베이스 식별자

CAS
15629-92-2
PubChem CID
2724937
EC Number
605-052-3

물성

구조 계산 물성

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
8
무거운 원자 수
32

물리화학적 성질

녹는점
213 °C · 213 °C (dec.)(lit.)
저장 조건
Inert atmosphere,Room Temperature
물리적 상태
수정 같은
색상
빨간색
수용성
불용성
InChI
InChI=1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2

화학적 성질

red to red-brown powder or crystals

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H315 (99.2%): Causes skin irritation [Warning Skin corrosion/irritation]；H317 (100%): May cause an allergic skin reaction [Warning Sensitization, Skin]；H319 (99.2%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H334 (34.7%): May cause allergy or asthma symptoms or breathing difficulties if inhaled [Danger Sensitization, respiratory]；H335 (98.3%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]；H350 (92.6%): May cause cancer [Danger Carcinogenicity]

P203, P233, P260, P261, P264, P264+P265, P271, P272, P280, P284, P302+P352, P304+P340, P305+P351+P338, P318, P319, P321, P332+P317, P333+P317, P337+P317, P342+P316, P362+P364, P403, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 121 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory InformationRestricted substance: Nickel, dichloro[1,1'-(1,3-propanediyl)bis[1,1-diphenylphosphine-[?]P]]-；EC: 605-052-3；Restriction condition document: PDF link
Hazard Classes and CategoriesSkin Irrit. 2 (99.2%)；Skin Sens. 1 (100%)；Eye Irrit. 2 (99.2%)；Resp. Sens. 1 (34.7%)；STOT SE 3 (98.3%)；Carc. 1A (92.6%)

규제 정보

Regulatory InformationRestricted substance: Nickel, dichloro[1,1'-(1,3-propanediyl)bis[1,1-diphenylphosphine-[?]P]]-；EC: 605-052-3；Restriction condition document: PDF link

안전 데이터

wgk
3
tsca
No
ridadr
3282
HS 번호
29319090
risk_code
49-36/37/38-42/43-40
hazard_code
T,Xn

화학 및 산업

응용 분야 · 1건

용도[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.

상·하류 제품 정보

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]

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