기본 정보
- CAS
6921-34-2- 표준 SMILES
[CH2-]c1ccccc1.[Cl-].[Mg+2]- InChIKey
NRAFPLGJPPJUNB-UHFFFAOYSA-M- 분자식
- C7.H7.Cl.Mg
- 평균 분자량
- 150.89 g/mol
- 단동위원소 질량
- 150.0086696
이름 및 식별자
- 우선 이름
- Magnesium, chloro(phenylmethyl)-
- IUPAC
- magnesium;methanidylbenzene;chloride
- 영어명
- Benzylmagnesium chloride
- 분자식
- C7H7ClMg
- 분자량
- 150.89
이름 및 동의어
Benzylmagnesium chloride6921-34-2Magnesium, chloro(phenylmethyl)-Chloro(phenylmethyl)magnesiumDTXSID00884302RefChem:800672Magnesium, chloro(phenylmethyl)DTXCID501023753230-039-0EC 230-039-0EINECS 230-039-0PhCH2MgCl
이름 더 보기
Benzylmagnesium chloride solutionBENZYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURANENCL-004BenzylchloromagnesiumChlorobenzylmagnesiumBenzylmagnesiumchloridChloro(benzyl) magnesiumchloro(phenylmethyl)-magnesiu
BnMgClmagnesium;methanidylbenzene;chlorideBenzylchloridomagnesiumphenylmethyl magnesium chlorideBenzylmagnesium chloride 1.0 M in THFBENZYLMAGNESIUM CHLORIDE 2M in THFbenzylmagnesiumchloridebenzyl magnesium chloride
데이터베이스 식별자
- CAS
6921-34-2- PubChem CID
- 2733352
- DTXSID
DTXSID00884302- EC Number
- 230-039-0
물성
구조 계산 물성
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 2
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 9
- 형식 전하
- 0
- 복잡도
- 50.9
실험 및 물리화학적 성질
Chemical ClassesMetals -> Metals, Organic Compounds
Density0.794 @25 °C
Physical Description30-50% solution in tetrahydrofuran: Clear liquid; [Sigma-Aldrich MSDS]
물리화학적 성질
- 끓는 점
- 182 °C · 182 °C(Press: 16 Torr)
- 밀도
- 1.031 g/mL · 1.031 g/mL at 25 °C
- 인화점
- 1 °F · 1 °F
- 저장 조건
- water-free area
- 물리적 상태
- 액체
- 색상
- 갈색에서 보라색까지
- 수용성
- 폭력적인 반응
- BRN
- 878506 · 878506
- InChI
- InChI=1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
- InChIKey
- NRAFPLGJPPJUNB-UHFFFAOYSA-M
- SMILES
- C1(C[Mg]Cl)=CC=CC=C1
- EPA
- Magnesium, chloro(phenylmethyl)- (6921-34-2)
화학적 성질
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
Danger
H225 (40.5%): Highly Flammable liquid and vapor [Danger Flammable liquids]
P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 74 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Regulatory Information
REACH registered substance: Benzylmagnesium chloride (EC: 230-039-0)
Magnesium, chloro(phenylmethyl)-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Hazards SummaryCauses burns; [Sigma-Aldrich MSDS] See Phenylmagnesium chloride.
Hazard Classes and CategoriesFlam. Liq. 2 (40.5%)
안전 및 보호
Protective Action Criteria (PAC)
1.2 [mg/m3]
13 [mg/m3]
79 [mg/m3]
독성 정보
Adverse EffectsDermatotoxin - Skin burns.
안전 데이터
- wgk
- 1
화학 및 산업
용도 및 제조
UsesUsed to make fine chemicals; [ExPub: ECHA REACH Registrations]
General Manufacturing InformationMagnesium, chloro(phenylmethyl)-: ACTIVE
응용 분야
용도Benzylmagnesium chloride (Grignard reagent) can be used as an alkylating reagent:For alkylating quinolyl-functionalized Cpchromium(III) complexes which are used as precursors for the preparation of active olefin polymerization catalysts. In the synthesis of 2,3-disubstituted benzopyran-4-ones, 6-chloro-8-methylpurine derivative, and phenylalanine derivatives.
일반 설명This product has been enhanced for energy efficiency.
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하류 제품
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