1,3-Dioxolan-2-one, 4-ethenyl-

HCID 2735038

기본 정보

CAS
4427-96-7
표준 SMILES
C=CC1COC(=O)O1
InChIKey
BJWMSGRKJIOCNR-UHFFFAOYSA-N
분자식
C5H6O3
평균 분자량
114.1 g/mol
단동위원소 질량
114.03169405

이름 및 식별자

우선 이름
1,3-Dioxolan-2-one, 4-ethenyl-
IUPAC
4-ethenyl-1,3-dioxolan-2-one
영어명
4-Vinyl-1,3-dioxolan-2-one
분자식
C5H6O3
분자량
114.1

이름 및 동의어

4427-96-7Vinylethylene Carbonate1,3-Dioxolan-2-one, 4-ethenyl-DTXSID60883553RefChem:414856DTXCID9010230744-Vinyl-1,3-dioxolan-2-one4-ethenyl-1,3-dioxolan-2-oneMFCD001433152-Oxo-4-vinyl-1,3-dioxolaneSCHEMBL480134-vinyl-[1,3]dioxolan-2-one
이름 더 보기
Vinyl Ethylene CarbonateVinyl Ethylene Carbonate(VEC)VEC)4-Vinyl-1,3-d4-VINYL-1 3-DIOXOLAN-2-ONE 994-VINYL-1,3-DIOXOLAN-2-ONE 99%4-Vinyl-1,3-dioxolan-2-one(VEC)
4-vinyl-1,3-dioxaolane-2-one4-Vinyl-1,3-dioxolan-2-one, stabilized with 0.1% hydroquinoneAKOS0158911174-Vinyl-1,3-dioxolan-2-one, 99%CS-W011250AS-11362DB-051205D92787

데이터베이스 식별자

CAS
4427-96-7
PubChem CID
2735038
DTXSID
DTXSID60883553
EC Number
700-261-7
Nikkaji
J770.330I

물성

구조 계산 물성

XLogP
1
극성 표면적
35.5 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
3
회전 가능 결합 수
1
무거운 원자 수
8

물리화학적 성질

끓는 점
237 °C/733 · 237 °C/733 mmHg (lit.)
밀도
1.188 g/mL · 1.188 g/mL at 25 °C (lit.)
증기압
4.58 Pa · 4.58Pa at 25℃
굴절률
20 · n20/D 1.45(lit.)
인화점
206 °F · 206 °F
저장 조건
2 · 2-8°C

화학적 성질

Colorless liquid

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 19.7% (13 of 66) of reports.

Danger

H301 (80.3%): Toxic if swallowed [Danger Acute toxicity, oral]

P260, P261, P264, P270, P272, P280, P301+P316, P302+P352, P319, P321, P330, P333+P317, P362+P364, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 66 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 2건

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 28-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/30074

Hazard Classes and CategoriesAcute Tox. 3 (80.3%)

안전 데이터

wgk
1
tsca
TSCA listed
ridadr
UN 2810 6.1/PG 3
HS 번호
29209090
risk_code
25
hazard_code
T

화학 및 산업

용도 및 제조

General Manufacturing Information1,3-Dioxolan-2-one, 4-ethenyl-: ACTIVE
응용 분야 · 2건

용도4-Vinyl-1,3-dioxolan-2-one may be used in the preparation of 2-arylbenzo[d]thiazole scaffolds.It may be used in the synthesis of the following multi-functional cyclic carbonates:4,4′-((hexane-1,6-diylbis(sulfanediyl))bis-(ethane-2,1-diyl))bis(1,3-dioxolan-2-one) (Bis-CC)2-ethyl-2-(((3-((2-(2-oxo-1,3-dioxolan-4-yl)-ethyl)thio)propanoyl)oxy) methyl)propane-1,3-diyl bis(3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)thio)propanoate) (Tris-CC)2,2-bis(((3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)-thio)propanoyl)oxy) methyl)propane-1,3-diyl bis(3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)thio)propanoate) (Tetra-CC)

일반 설명4-Vinyl-1,3-dioxolan-2-one (VEC) is a cyclic carbonate, that can be synthesized from acrolein by reacting with sulfur ylide and CO2. The ruthenium-catalyzed transfer hydrogenation (TH) of VEC in the presence of 2-propanol forms 1,2-butanediol. Indolines and indoles undergo selective C-H allylation with VEC in the presence of rhodium(III) catalyst.

공급사100 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
郑州阿尔法化工有限公司+86-18530059196 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
上海策嵘生物科技有限公司[email protected]
武汉鹏垒生物科技有限公司15871464247 · [email protected]

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4건

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