3-메트록시-4-메탄올린

3-Methoxy-4-methylaniline

HCID 27882CAS 16452-01-0

기본 정보

표준 SMILES
COc1cc(N)ccc1C
InChIKey
ONADZNBSLRAJFW-UHFFFAOYSA-N
분자식
C8H11NO
평균 분자량
137.18 g/mol
단동위원소 질량
137.08406397

개요

O-cresidine is a brown chunky solid. (NTP, 1992)

이름 및 식별자

우선 이름
3-Methoxy-4-methylaniline
IUPAC
3-methoxy-4-methylaniline
현지명
3-메트록시-4-메탄올린
영어명
3-Methoxy-4-methylaniline
분자식
C8H11NO
분자량
137.18

이름 및 동의어

3-Methoxy-4-methylanilineBenzenamine, 3-methoxy-4-methyl-O-CRESIDINECCRIS 4606EINECS 240-500-8DTXSID9024855UNII-V82SCC5X3QV82SCC5X3Q4-METHYL-M-ANISIDINEBRN 0742602(3-METHOXY-4-METHYLPHENYL)AMINE4-AMINO-2-METHOXYTOLUENE
이름 더 보기
3-메트록시-4-메탄올린ORTHO-CRESIDINE2-METHYL-5-ANISIDINE5-AMINO-2-METHYLANISOLE2-METHOXY-4-AMINOTOLUENE4-Methyl-m-anisidine (NH2=1)3-METHOXY-4-METHYLBENZENAMINE
CRESIDINE, O-4-methyl-3-methoxyanilineDTXCID504855M-ANISIDINE, 4-METHYL-4-13-00-01666 (Beilstein Handbook Reference)3-METHOXY-P-TOLUIDINERefChem:945874-AMINO-6-METHOXYTOLUENE

데이터베이스 식별자

CAS
16452-01-0
PubChem CID
27882
DTXSID
DTXSID9024855
ChEMBL
CHEMBL3188424
UNII
V82SCC5X3Q
EC Number
240-500-8
Nikkaji
J141.483F

물성

구조 계산 물성

XLogP
2.1
극성 표면적
35.3 Ų
수소 결합 공여자 수
1
수소 결합 수용자 수
2
회전 가능 결합 수
1
무거운 원자 수
10

실험 및 물리화학적 성질

Solubilityless than 1 mg/mL at 59 °F (NTP, 1992)
Flash Pointgreater than 235 °F (NTP, 1992)
Boiling Point482 to 486 °F at 760 mmHg (NTP, 1992)
Melting Point124 to 129 °F (NTP, 1992)
Physical DescriptionO-cresidine is a brown chunky solid. (NTP, 1992)

물리화학적 성질

녹는점
57 · 57-59 °C
끓는 점
252.03 °C · 252.03°C (rough estimate)
밀도
1.063 · 1.0630 (rough estimate)
굴절률
1.5647 · 1.5647 (estimate)
인화점
113 ℃ · >113℃
저장 조건
Keep in dark place,Sealed in dry,Room Temperature

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H302 (97.7%): Harmful if swallowed [Warning Acute toxicity, oral]

P203, P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P317, P318, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 44 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory InformationBenzenamine, 3-methoxy-4-methyl-: Does not have an individual approval but may be used under an appropriate group standard
DOT LabelPoison
Fire HazardsThis chemical is probably combustible. (NTP, 1992)
Health HazardsSYMPTOMS: Symptoms of exposure to this compound may include drowsiness, skin and eye irritation, nausea, vomiting, weakness, somnolence, methemoglobinemia, liver damage, unconsciousness, and cyanosis.
Reactive GroupAmines, Aromatic
Reactivity Profile · 1건

O-CRESIDINE neutralizes acids in weakly exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides. Reacts with oxidizing agents (NTP, 1992).

안전 및 보호

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide, or Halon extinguisher. (NTP, 1992)
First Aid · 1건

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1건

SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Personal Protective Equipment (PPE)MINIMUM PROTECTIVE CLOTHING: If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves.

안전 데이터

wgk
3
rtecs
CY0888000
ridadr
UN2811
HS 번호
2922500090
risk_code
36/37/38-20/21/22
hazard_code
Xn

화학 및 산업

응용 분야 · 2건

용도3-Methoxy-4-methylaniline, afforded by an electrophilic substitution, using the 2-methoxy-substituted iron complex sail followed by oxidative cyclization with concomitant aromation of the resulting iron complex. It is used to produce 8-methoxy-7-methylalloxazine. This reaction will need solvent ethanol, H2O

일반 설명Brown chunky solid.

공급사50 곳

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
合肥曼奇诺生物医药技术有限公司19719236623 · [email protected]
毕佳索(上海毕得医药科技股份有限公司)400-6005915 · [email protected]
Changzhou Anxuan Chemical Co., Ltd+86-0519-89882563 +86-18961279162 · [email protected]

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