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2,2-디니트로프로필아크릴레이트

2,2-Dinitropropyl acrylate

HCID 28860
노트반응
기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
17977-09-2
표준 SMILES
C=CC(=O)OCC(C)([N+](=O)[O-])[N+](=O)[O-]
InChIKey
BGPPMVLBKMPVQR-UHFFFAOYSA-N
분자식
C6H8N2O6
평균 분자량
204.14 g/mol
단동위원소 질량
204.03823598

이름 및 식별자

우선 이름
2,2-Dinitropropyl acrylate
IUPAC
2,2-dinitropropyl prop-2-enoate
현지명
2,2-디니트로프로필아크릴레이트
영어명
2,2-dinitropropyl acrylate
분자식
C6H8N2O6
분자량
204.14

이름 및 동의어

2,2-DINITROPROPYL ACRYLATE2,2-Dinitropropyl 2-propenoateUNII-W5F83UPW7DW5F83UPW7DAcrylic acid, 2,2-dinitropropyl esterHSDB 61122-Propenoic acid, 2,2-dinitropropyl esterEINECS 241-897-0NSC 166462NSC-166462DTXSID10662892,2-DINITROPROPYL 2-PROPENOATE [HSDB]
이름 더 보기
2,2-디니트로프로필아크릴레이트Propenoic acid 2,2-dinitropropyl ester
1-PROPANOL, 2,2-DINITRO-, ACRYLATE (ESTER)RefChem:811112,2Dinitropropyl 2propenoateDTXCID4035708Acrylic acid, 2,2dinitropropyl ester2Propenoic acid, 2,2dinitropropyl esterAcrylic acid, 2,2-dinitropropyl ester (8CI)241-897-0

데이터베이스 식별자

CAS
17977-09-2
PubChem CID
28860
DTXSID
DTXSID1066289
UNII
W5F83UPW7D
EC Number
241-897-0
Nikkaji
J260.813H

물성

구조 계산 물성

XLogP
0.8
극성 표면적
118 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
6
회전 가능 결합 수
4
무거운 원자 수
14
형식 전하
0
복잡도
261

실험 및 물리화학적 성질

PolymersPlastics & Rubber -> (Meth)acrylates
Vapor Pressure0.00106 [mmHg]
Other Experimental PropertiesReacts readily with electrophilic, free-radical, and nucleophilic agents /Acrylic acid & esters/

물리화학적 성질

EPA
2 · 2,2-Dinitropropyl acrylate (17977-09-2)

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

유해성 정보

Hazards SummarySee ACRYLIC RESINS (MONOMERS).
Skin, Eye, and Respiratory IrritationsTHE LOWER-MOL-WT ESTERS OF ACRYLIC ACIDS ARE IRRITANTS TO SKIN, EYES & MUCOUS MEMBRANES. /ACRYLIC ACID ESTERS/

안전 및 보호

Storage Conditions · 1건

The effectiveness of phenolic inhibitors is dependent on the presence of oxygen and the monomers must be stored under air rather than an inert atmosphere. Temp must be kept low to minimize formation of peroxides and other products. ... The acrylic esters may be stored in mild or stainless steel, or aluminum. /Acrylic acid & derivatives/

Disposal Methods · 1건

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Preventive Measures · 3건

Awareness of the dangers and of good engineering design are essential to safety. Employees should be instructed about the necessity of cleansing the skin if it is contaminated by materials which are irritants or skin-absorbed. With careful design, however, and complete enclosure of those processes where toxic chemicals or intermediates occur, dangerous exposures can be avoided. /Acrylic acid & derivatives/

SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers. Contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.

SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

화학 및 산업

용도 및 제조

Uses · 3건

Used as a monomer (e.g., for polymers used in rocket propellants); [HSDB]

Plastic Composites Manufacturing [Category: Industry]

MONOMER, EG, FOR POLYMERS USED IN ROCKET PROPELLANTS

U.S. Imports(1983) 1.36X10+9 g /Acrylates & Acrylic Acid/
Methods of Manufacturing · 2건

The acrylates can be prepared by a number of procedures. These incl dehydration of corresponding hydroxyalkanoic acid, saponification of alkene nitrile, catalytic hydration of acetylene & carbon monoxide, or the reaction of acetone with hydrocyanic acid. /Acrylates/

In ... propylene oxidation process acrolein is first formed by the catalytic oxidation of propylene vapor at high temp in the presence of steam. The acrolein is then oxidized to acrylic acid. ... The acrylic acid is esterified with alcohol to the ... acrylic ester in a separate process. /Acrylic ester monomers/

Formulations/Preparations... Hydroquinone or monomethyl ether hydroquinone /is/ added to acrylic monomers to stabilize them ... . /Acrylic ester monomers/
General Manufacturing Information2-Propenoic acid, 2,2-dinitropropyl ester: INACTIVE

공급사1 곳

DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]

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화합물 노트

불러오는 중…

이 페이지에서기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
Personal Protective Equipment (PPE) · 2건

SUITABLE PROTECTIVE CLOTHING & SELF-CONTAINED RESP PROTECTIVE APPARATUS SHOULD BE AVAILABLE FOR USE OF THOSE WHO MAY HAVE TO RESCUE PERSONS OVERCOME BY FUMES. /ACRYLIC ACID & DERIVATIVES/

Protection required for safe handling of acrylic acid and esters commonly includes use of impervious gloves, shoe soles, and clothing; splash-proof goggles ... . /Acrylic acid & derivatives/

독성 정보

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Human Toxicity Excerpts · 1건

THE ACUTE TOXICITY OF THE ACRYLATES DECREASES WITH INCREASING MOLECULAR WEIGHT. ... HUMAN SIGNS & SYMPTOMS FOLLOWING INGESTION OF ACRYLIC MONOMERS INCL COLLAPSE, SEVERE RESPIRATORY DIFFICULTIES, & CNS STIMULATION. ACUTE INHALATION OF HIGHER CONCN MAY CAUSE MARKED IRRITATION, SALIVATION, CONJUNCTIVAL IRRITATION, & PRONOUNCED PULMONARY IRRITATION OR EDEMA. PROLONGED SKIN OR EYE CONTACT MAY RESULT IN SEVERE TISSUE DAMAGE. THE PATHOLOGY FROM SINGLE EXPOSURE IS NONSPECIFIC, CONTRARY TO REPEATED EXPOSURE EFFECTS, WHICH INCL PULMONARY CONGESTION OR HEMORRHAGE & CLOUDY SWELLING OF LIVER & KIDNEY. /ACRYLATES/

Non-Human Toxicity ExcerptsContact sensitivity was produced in guinea pigs with mono-, di-, and tri- acrylate compounds. /Mono-, di-, and tri- acrylate compounds/
Antidote and Emergency Treatment · 2건

Basic treatment: Establish a patent airway. Suction if necessary. Encourage patient to take deep breaths. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . /Irritating materials/

Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in respiratory arrest. Early intubation at the first sign of upper airway obstruction may be necessary. Positive-pressure ventilation techniques with a bag-valve mask device may be beneficial. Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start an IV with D5W TKO /SRP: "To keep open", minimal flow rate/. Use lactated Ringer's if signs of hypovolemia are present. Watch for signs of fluid overload. Consider drug therapy for pulmonary edema ... . Treat seizures with diazepam (Valium) ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Irritating materials/

안전 데이터

tsca
TSCA listed
유해 물질 데이터
17977-09-2(Hazardous Substances Data)