기본 정보
- 표준 SMILES
[O]=[Mo]=[O]- InChIKey
QXYJCZRRLLQGCR-UHFFFAOYSA-N- 분자식
- MoO2
- 평균 분자량
- 127.95 g/mol
- 단동위원소 질량
- 129.89523744
이름 및 식별자
- 우선 이름
- Molybdenum dioxide
- IUPAC
- dioxomolybdenum
- 현지명
- 이산화 몰리브덴
- 영어명
- Molybdenum(IV) oxide
- 분자식
- MoO2
- 분자량
- 127.94
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
18868-43-4- PubChem CID
- 29320
- DTXSID
DTXSID10879986- EC Number
- 242-637-9
- Nikkaji
- J1.270.094F、J96.263E
물성
구조 계산 물성
- 극성 표면적
- 34.1 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 2
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 3
- 형식 전하
- 0
- 복잡도
- 18.3
실험 및 물리화학적 성질
Physical Description
CBI
Lead-gray solid; [Hawley] Red-brown odorless powder; Insoluble in water; [MSDSonline] Solid (dark blue crystals) that is a metallic conductor and weakly paramagnetic; [Ullmann]
물리화학적 성질
- 녹는점
- 85 · decomposes [JAN85]
- 밀도
- 6.47 g/mL · 6.47 g/mL at 25 °C (lit.)
- 저장 조건
- Store at room temperature, keep dry and cool
- 용해도
- 2 O, · insoluble in H2O, acid solutions, alkaline solutions
- 물리적 상태
- 가루
- 색상
- 적갈색
- Specific Gravity
- 6.47 · 6.47
- 수용성
- 2 SO4; · 약간 용해되는 H2SO4; 용해되지 않음 HCl, HF 및 알칼리 [HAW93]
- 비열
- 0.44 J/ · Cp(crystal): 0.44 J/(g·K), at 25℃
- 주요 응용
- 배터리 제조
- InChI
- 1S/Mo.2O
- InChIKey
- QXYJCZRRLLQGCR-UHFFFAOYSA-N
- SMILES
- O=[Mo]=O
- EPA
- Molybdenum oxide (MoO2) (18868-43-4)
화학적 성질
Lead-gray, nonvolatile powder. Dapproximately 6.4. Insoluble in hydrochloric acidand hydrogen fluoride and alkalies, sparingly solu-ble in sulfuric acid.
안전 및 규제
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 91.9% (57 of 62) of all reports.
Not Classified
Aggregated GHS information provided per 62 reports by companies from 4 notifications to the ECHA C&L Inventory.
유해성 정보
Regulatory Information
Chemical: Molybdenum oxide (MoO2)
Molybdenum oxide (MoO2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Molybdenum oxide (MoO2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 30-07-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/10167
안전 및 보호
Protective Action Criteria (PAC)
40 [mg/m3]
440 [mg/m3]
2600 [mg/m3]
안전 데이터
- wgk
- 1
- tsca
- TSCA listed
- rtecs
- QA4688000
- 독성
- mouse,LD50,subcutaneous,318mg/kg (318mg/kg),Zhurnal Vsesoyuznogo Khimicheskogo Obshchestva im. D.I. Mendeleeva. Journal of the D.I. Mendeleeva All-Union Chemical Society. Vol. 19, Pg. 186, 1974.
- HS 번호
- 28257000
- risk_code
- 20/21/22-36/37/38
- hazard_code
- Xn
- safety_code
- 26-36
- 기존화학 물질
- KE-25436
- 스토리지 클래스
- 11 - Combustible Solids
화학 및 산업
용도 및 제조
General Manufacturing Information
Primary Metal Manufacturing
Molybdenum oxide (MoO2): ACTIVE
응용 분야
용도Molybdenum(IV) oxide (MoO2) is a transition metal oxide with good electrical conductivity due to the presence of delocalized electrons in its valence band. It is traditionally prepared by reducing MoO3 in dry hydrogen in the temperature range of 450-550°C. MoO2 can be used in a variety of energy based applications such as an anode material in rechargeable lithium batteries and fuel flexible solid oxide fuel cells.It can also be used as a catalyst in hydrogen reforming processes.
일반 설명Molybdenum(IV) oxide (MoO2) is a transition metal oxide with good electrical conductivity due to the presence of delocalized electrons in its valence band. It is traditionally prepared by reducing MoO3 in dry hydrogen in the temperature range of 450-550°C.
제조 방법
Molybdenum(IV) oxide is obtained by passing steam over red hot molybdenum: Mo + 2H2O → MoO2 + 2H2 Alternatively, the oxide may be prepared by heating a molybdate salt, such as ammonium molybdate, with a reducing agent such as zinc. The dioxide also may be obtained along with other oxides of molybdenum when molybdenum metal is heated in air. A brown-black suspension of MoO2 in hydrate form may be obtained by reducing a solution of ammonium molybdate with hydrogen in the presence of colloidal palladium.
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