Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
트리스(2,3-다이브로모프로필)인산염
트리스(2,3-다이브로모프로필)인산염 · 트리스(2,3-디브로모프로필)포스페이트 · 트리스-(2,3-다이브로모프로필)-포스페이트 · 트리스(2,3-다이브로모-1-프로필) 포스페이트 · TBPP · TDBPP · TDBP · 3pbr
식별자 및 물리적 특성
| CAS No. | 126-72-7 |
|---|---|
| 분자식 | C9H15Br6O4P |
| 평균 분자량 | 697.6 g/mol |
| 단동위원소 질량 | 691.58082 g/mol |
| SMILES | O=P(OCC(Br)CBr)(OCC(Br)CBr)OCC(Br)CBr |
| InChIKey | PQYJRMFWJJONBO-UHFFFAOYSA-N |
| PubChem CID | 31356 |
| ChEMBL | CHEMBL1904600 |
| ChEBI | CHEBI:82282 |
| EC No. | 204-799-9 |
| DTXSID | DTXSID5021413 |
| 현지명 | 트리스(2,3-다이브로모프로필)인산염 |
화학 및 물리적 성질
| XLogP | 4.3 |
|---|---|
| 극성 표면적 | 44.8 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 4 |
| 회전 가능 결합 수 | 12 |
| 무거운 원자 수 | 20 |
| 형식 전하 | 0 |
| 복잡도 | 255 |
| 물질 분류 | Other Classes -> Organophosphates, OtherCarcinogens |
| pH | High-purity & low-purity grades: acid number (mg KOH/g)= 0.05 maximum |
| LogP(분배 계수) | log Kow = 4.293.71 |
| 밀도 | 2.27 at 77 °F (NTP, 1992) - Denser than waterwill sink2.27 at 25 °CBulk density: 18.5 lb/galRelative density (water = 1): 2.272.27 g/cm3(Temp: 25 °C) |
| Flame Retardants | Flame Retardants -> Organophosphorus flame retardant (OP) |
| Viscosity | High purity grade: 3900-4200 centistokes at 25 °Clow purity grade: 1400-1700 centistokes at 25 °C |
| Color/Form | Viscous, pale yellow liquidDense, nearly colorless liquidCrystals |
| 용해도 | less than 1 mg/mL at 68 °F (NTP, 1992)In water, 8 mg/L at 24 °CMiscible with carbon tetrachloride, chloroform, and methylene chlorideSoluble in chloroformSolubility in water, g/100ml at 20 °C: 0.063에 용해됨클로로포름, 메탄올 (약간 용해됨) |
| 인화점 | greater than 234 °F (NTP, 1992)>112 °C>110 °C |
| Endocrine Disruptors | Potential endocrine disrupting compound |
| Decomposition | When heated to decomposition it emits very toxic fumes of /bromides/ and /phosphorus oxides/.200 °C. This produces toxic and corrosive fumes including hydrogen bromide and phosphorus oxides. Reacts with acids and bases. |
| 녹는점 | FP: 5.5 °C5.5°C |
| 끓는 점 | 544.2±50.0 °C(Predicted) |
| 저장 조건 | room temp |
| 용해도 | 8mg/L(24℃) |
| Merck | 13,9821 |
| 헨리 상수 | 3.8×10-1 mol/(m3Pa) at 25℃, HSDB (2015) |
| 안정성 | 수분에 민감한 |
| EPA | Tris(2,3-dibromopropyl) phosphate (126-72-7) |
화학적 성질
TDBP is a thick, clear to yellowish liquid. Odorless.
안전 및 규제
| GHS 분류 | DangerH302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]P203, P264, P270, P273, P280, P301+P317, P302+P352, P318, P321, P330, P332+P317, P362+P364, P391, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 42 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.H401: Toxic to aquatic life [Hazardous to the aquatic environment, acute hazard]P273, P391, and P501 (click each P-code to see the statement) |
|---|---|
| 규제 정보 | Chemical: 1-Propanol, 2,3-dibromo-, phosphate (3:1)Hazard Traits - CarcinogenicityRegulation (EC) No 178/2002 (amended)S - indicates a substance that is identified in a final Significant New Use Rule.Restricted substance: Tris (2,3 dibromopropyl) phosphateThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| 기타 안전 정보 | PEC / SN / Other assessments - Polybrominated flame retardants (PBFRs): Health and Environment |
| 운송 라벨(DOT) | Class 9 |
| 화재 위험 | This chemical is combustible. (NTP, 1992)Combustible under specific conditions. |
| 화재 가능성 | CombustibleMay be flammable when exposed to heat or flame. |
| 건강 유해성 | SYMPTOMS: Symptoms of exposure to this compound include gastrointestinal irritation, nausea, vomiting, headache, dizziness, central nervous system depression testicular atrophy, chronic lung disease, kidney damage and liver damage. It can cause eye irritation and severe skin irritation. It can also cause skin sensitization. |
| 유해성 요약 | Probably carcinogenic to humans[ICSC] Causes eye and severe skin irritationOral LD50 (rat) = 1010 mg/kgPercutaneous LD50 (rabbit) >8000 mg/kg[HSDB] An eye and strong skin irritantMay cause skin sensitizationMay cause liver and kidney injury |
용도
용도
Tris(2,3-dibromopropyl) Phosphate is a flame retardant that has previously shown to be a mutagen and carcinogen in experimental animals. Tris(2,3-dibromopropyl) Phosphate is widely used in pastics an d textiles.
일반 설명
Clear colorless to pale yellow viscous liquid.