Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
나딕 메틸 무수물
나딕메틸무수물 · 나딕메틸무수물(NADICMETHYLANHYDRIDE) · MNA · NADIC METHYL ANHYDRIDE · METHYL NADIC ANHYDRIDE · NMA · XMNA · mea610

식별자 및 물리적 특성
| CAS No. | 25134-21-8 |
|---|---|
| 분자식 | C10H10O3 |
| 평균 분자량 | 178.18 g/mol |
| SMILES | CC12C=CC(C1)C1C(=O)OC(=O)C12 |
| InChIKey | LTVUCOSIZFEASK-MPXCPUAZSA-N |
| PubChem CID | 32802 |
| EC No. | 246-644-8 |
| 현지명 | 나딕 메틸 무수물 |
화학 및 물리적 성질
| XLogP | 1.2 |
|---|---|
| 극성 표면적 | 43.4 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 3 |
| 회전 가능 결합 수 | 0 |
| 무거운 원자 수 | 13 |
| 형식 전하 | 0 |
| 복잡도 | 344 |
| Polymers | Plastics & Rubber -> Acid Anhydrides, Cyclic |
| 밀도 | 1.200-1.250 @ 20 °C/20 °C1.232 @25 °C1.232 g/mL at 25 °C(lit.) |
| Viscosity | 175-225 CP @ 25 °C |
| Color/Form | COLORLESS TO LIGHT-YELLOW VISCOUS LIQ |
| 용해도 | MISCIBLE IN ALL PROPORTIONS WITH ACETONE, BENZENE, NAPHTHA, & XYLENE아세톤, 벤젠, 나프타, 자일렌과 혼합 가능. |
| 녹는점 | 18 °C |
| 증기압 | 0.1 [mmHg]5 mm Hg ( 120 °C) |
| Food Contact Substances | FCS -> FDA Cumulative Estimated Daily Intake (CEDI)FCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR |
| 굴절률 | INDEX OF REFRACTION: 1.500-1.506 @ 20 °C/Dn20/D 1.506(lit.) |
| Physical Description | LiquidColorless to light yellow liquid[HSDB] Colorless liquid[MSDSonline] |
| 끓는 점 | 140°C (10 mmHg) |
| 증기 밀도 | 6.1 (20 °C, vs air) |
| 인화점 | >230 °F |
| 저장 조건 | room temp |
| pKa(산도 계수) | 4.42[at 20 ℃] |
| 물리적 상태 | 기름진 액체 |
| 색상 | 맑은 연한 노란색 |
| 생물학적 소스 | synthetic |
| 용해도 | 물과 반응 |
| BRN | 162395 |
| 주요 응용 | 혈액학조직학 |
| InChI | 1S/C10H10O3/c1-10-6-3-2-5(4-6)7(10)8(11)13-9(10)12/h2-3,5-7H,4H2,1H3/t5-,6+,7+,10+/m0/s1 |
| InChIKey | LTVUCOSIZFEASK-MPXCPUAZSA-N |
| SMILES | [H][C@]12C3CC(C(C)=C3)[C@@]1([H])C(=O)OC2=O |
| LogP(분배 계수) | -4.01 at 20℃ |
| NIST | 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-(25134-21-8) |
| EPA | 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aR,4S,7R,7aS)-rel- (25134-21-8) |
화학적 성질
clear light yellow oily liquid
안전 및 규제
| GHS 분류 | DangerH302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]P233, P260, P261, P264, P264+P265, P270, P271, P272, P280, P284, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P319, P321, P330, P332+P317, P333+P317, P337+P317, P342+P316, P362+P364, P363, P403, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 295 reports by companies from 15 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.H302: Harmful if swallowed [Warning Acute toxicity, oral] |
|---|---|
| 규제 정보 | Chemical: 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3a.alpha.,4.alpha.,7.alpha.,7a.alpha.)-4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aR,4S,7R,7aS)-rel- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aR,4S,7R,7aS)-rel- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)REACH registered substance: 1,2,3,6-tetrahydromethyl-3,6-methanophthalic anhydride (EC: 246-644-8)Methylnorbornen-2,3-dicarboxylic anhydride: Does not have an individual approval but may be used under an appropriate group standard |
| 유해성 요약 | A skin and eye irritantMay cause respiratory sensitization[eChemPortal: ERMA] An irritantInhalation may cause respiratory sensitization[MSDSonline] See ACID ANHYDRIDES. |
| Hazard Classes and Categories | Acute Tox. 4 (100%)Acute toxicity (Oral) - Category 4 |
| Protective Action Criteria (PAC) | 0.49 [mg/m3]5.4 [mg/m3]32 [mg/m3] |
| 유해 작용 | Asthma - Reversible bronchoconstriction (narrowing of bronchioles) initiated by the inhalation of irritating or allergenic agents. |
| Toxicity Data | LCLo (rat) = 750 mg/m3/4h |
용도
용도
Methyl-5-norbornene-2,3-dicarboxylic anhydride is used as a curing agent in epoxy resins and in the preparation of vertically aligned and penetrated carbon nanotube/polymer film. It serves as an intermediate in polyesters, alkyd resins and plasticizers. It is also used in electrical laminating and filament-winding. Further, it is used in the preparation of methyl nadimides endcapped resins based on tris(3-aminophenyl)phosphine oxide. It is utilized in the flame retarding treatment.
일반 설명
additional information see 45359 Epoxy Embedding Medium kit