Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
에토프로포스
에토프로포스 · 에토프로프 · O-에틸 S,S-디프로필디티오인산 · 티오인산 O-에틸 S,S-디프로필에스테르 · PROPHOS · ETHOPROP · MOCAP · Profos
식별자 및 물리적 특성
| CAS No. | 13194-48-4 |
|---|---|
| 분자식 | C8H19O2PS2 |
| 평균 분자량 | 242.3 g/mol |
| 단동위원소 질량 | 242.05640919 g/mol |
| SMILES | CCCSP(=O)(OCC)SCCC |
| InChIKey | VJYFKVYYMZPMAB-UHFFFAOYSA-N |
| PubChem CID | 3289 |
| ChEMBL | CHEMBL1894994 |
| ChEBI | CHEBI:38665 |
| EC No. | 236-152-1 |
| DTXSID | DTXSID4032611 |
| 현지명 | 에토프로포스 |
화학 및 물리적 성질
| XLogP | 3.6 |
|---|---|
| 극성 표면적 | 76.9 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 4 |
| 회전 가능 결합 수 | 8 |
| 무거운 원자 수 | 13 |
| 형식 전하 | 0 |
| 복잡도 | 152 |
| LogP(분배 계수) | log Kow = 3.59 @ 21 °C3.6 |
| 밀도 | 1.094 at 68 °F (EPA, 1998) - Denser than waterwill sink1.094 g/cu cm @ 20 °CRelative density (water = 1): 1.091.09 @ 20°Cd420 1.094 |
| Color/Form | Pale yellow liquidPale yellow oil |
| 용해도 | Readily sol in most organic solventsSOLUBLE IN KEROSENESolubility >300 g/kg @ 20 °C in acetone, ethanol, xylene, 1,2-dichloroethane, diethyl ether, ethyl acetate, petroleum spirit, cyclohexaneIn water, 750 mg/l @ 20-25 °CSolubility in water, g/100ml at 20 °C: 0.075DMF: 5mg/mLDMSO: 5mg/mLEthanol: 1.6mg/mL |
| Corrosivity | Non-corrosive to metals |
| 끓는 점 | 187 to 196 °F at 0.2 mmHg (EPA, 1998)86-91 °C @ 0.2 mm Hgat 0.03kPa: 86-91 °C86-91°C |
| Decomposition | When heated to decomposition it emits very toxic fumes of /phosphorus oxides and sulfur oxides/.room temperature. This produces flammable n-propylmercaptan (see ICSC 1492). Decomposes on heating. This produces toxic fumes including phosphorus oxides and sulfur oxides. |
| 녹는점 | -13 °C |
| 증기 밀도 | Relative vapor density (air = 1): 8.4 |
| 증기압 | 0.00035 mmHg at 78.8 °F (EPA, 1998)0.00035 [mmHg]3.8X10-4 mm Hg @ 20-25 °CVapor pressure, Pa at 20-25 °C: 0.050.00038 [mm Hg] @25 °C4.65 x 10-2 Pa (26 °C) |
| Physical Description | Ethorop is one of a family of organophosphorus pesticides. It is combustible though it may require some effort to ignite. It is very toxic by skin absorption and inhalation. It may or may not be water soluble.Pale yellow liquid[Merck Index] Colorless to yellow liquid with a strong odor of mercaptans[Reference #1]PALE YELLOW LIQUID WITH CHARACTERISTIC ODOUR. |
| Stability/Shelf Life | Very stable in neutral and weakly acidic media. Rapidly hydrolysed in alkaline media. Stable in water up to 100 °C at pH 7.... Thermally stable for 8 hr at 150 °C. |
| 인화점 | 100 °C |
| 저장 조건 | APPROX 4°C |
| 용해도 | 700mg l-1(20°C) |
| Merck | 13,3782 |
| BRN | 8139788 |
| 헨리 상수 | 6.1×101 mol/(m3Pa) at 25℃, HSDB (2015) |
| 안정성 | 흡습성 |
| 주요 응용 | 농업환경 |
| InChI | 1S/C8H19O2PS2/c1-4-7-12-11(9,10-6-3)13-8-5-2/h4-8H2,1-3H3 |
| InChIKey | VJYFKVYYMZPMAB-UHFFFAOYSA-N |
| SMILES | CCCSP(=O)(OCC)SCCC |
| NIST | Ethoprophos(13194-48-4) |
| EPA | Ethoprop (13194-48-4) |
화학적 성질
Ethoprophos is a pale yellow liquid.
안전 및 규제
| GHS 분류 | DangerH301: Toxic if swallowed [Danger Acute toxicity, oral]H310: Fatal in contact with skin [Danger Acute toxicity, dermal]H317: May cause an allergic skin reaction [Warning Sensitization, Skin]H330: Fatal if inhaled [Danger Acute toxicity, inhalation]H400: Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]H410: Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]P260, P261, P262, P264, P270, P271, P272, P273, P280, P284, P301+P316, P302+P352, P304+P340, P316, P320, P321, P330, P333+P317, P361+P364, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement) |
|---|---|
| 규제 정보 | Hazard Traits - CarcinogenicityEnvironmental toxAuthoritative List - CWA 303(d)Prop 65Report - regardless of intended function of ingredient in the productRegulation (EC) No 1107/2009 (amended)Ethoprop is listed in the dataset of EPA Human Health Benchmarks for Pesticides under the Safe Drinking Water Act (40 eCFR 141)07/52/EC, Reg. (EU) 2018/917, Reg. (EU) 2019/344, Reg. (EU) No 1178/2013, Reg. (EU) No 540/2011Status: Active Update: 30-05-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/33573The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| 기타 안전 정보 | IMAP assessments - Phosphorodithioic acid, O-ethyl S,S-dipropyl ester: Human health tier I assessmentIMAP assessments - Phosphorodithioic acid, O-ethyl S,S-dipropyl ester: Environment tier I assessment |
| 운송 라벨(DOT) | Poison |
| 화재 위험 | (Non-Specific -- Organophosphorus Pesticide, Liquid, n.o.s.) Container may explode in heat of fire. Fire and runoff from fire control water may produce irritating or poisonous gases. Stable in water. Hydrolyzed in alkali. (EPA, 1998)Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Heating will cause rise in pressure with risk of bursting. |
| 건강 유해성 |
용도
개요
Introduced in the 1960s, ethoprop is a nonsystemic insecticide/nematicide. The mobility of ethoprop in soil and its half-life are strongly dependent on soil organic matter (21). It is not known to be carcinogenic and is available as granules or emulsifiable concentrates.
용도
Ethoprophos is an organophosphate non-systemic nematicide and soil insecticide. Ethoprophos is an acetylcholinesterase (AChE) inhibitor.
일반 설명
Ethorop is one of a family of organophosphorus pesticides. Mocap is combustible though Mocap may require some effort to ignite. Mocap is very toxic by skin absorption and inhalation. Mocap may or may not be water soluble.