Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Perfluoroisopropyl iodide
PERFLUOROISOPROPYL IODIDE · PERFLUORO-2-IODOPROPANE · IHFP · C3F7I · HeptafL · uoro-2-iodopropane · Heptafluoroiodopropane · 2-IODOPERFLUOROPROPANE
식별자 및 물리적 특성
| CAS No. | 677-69-0 |
|---|---|
| 분자식 | C3F7I |
| 평균 분자량 | 295.93 g/mol |
| 단동위원소 질량 | 295.89329554 g/mol |
| SMILES | FC(F)(F)C(F)(I)C(F)(F)F |
| InChIKey | BBZVTTKMXRPMHZ-UHFFFAOYSA-N |
| PubChem CID | 33978 |
| EC No. | 211-643-3 |
| DTXSID | DTXSID5060982 |
화학 및 물리적 성질
| XLogP | 3.4 |
|---|---|
| 극성 표면적 | 0 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 7 |
| 회전 가능 결합 수 | 0 |
| 무거운 원자 수 | 11 |
| 형식 전하 | 0 |
| 복잡도 | 129 |
| 물질 분류 | Other Classes -> Halogenated Aliphatics, Saturated |
| PFAS | PFAS -> Other/unspecifiedPFAS -> PFAS identified in REACH Regulation EC No. 1272/2008PFAS -> OECD Category |
| SpringerMaterials Properties | Schoenflies notation |
| 증기압 | 368.0 [mmHg]7.12 psi ( 20 °C) |
| Physical Description | Liquid[Sigma-Aldrich MSDS] |
| 녹는점 | -58 °C |
| 끓는 점 | 40 °C (lit.) |
| 밀도 | 2.08 g/mL at 25 °C (lit.) |
| 굴절률 | n20/D 1.329(lit.) |
| 인화점 | 38°C |
| 저장 조건 | 2-8°C |
| 물리적 상태 | 투명한 액체 |
| 색상 | Colorless to Light yellow to Light red |
| 비중 | 2.10 |
| 용해도 | 불용성 |
| BRN | 1841228 |
| InChI | 1S/C3F7I/c4-1(11,2(5,6)7)3(8,9)10 |
| InChIKey | BBZVTTKMXRPMHZ-UHFFFAOYSA-N |
| SMILES | FC(F)(F)C(F)(I)C(F)(F)F |
| LogP(분배 계수) | 3.94 |
| NIST | Propane, 1,1,1,2,3,3,3-heptafluoro-2-iodo-(677-69-0) |
| EPA | Propane, 1,1,1,2,3,3,3-heptafluoro-2-iodo- (677-69-0) |
화학적 성질
clear colorless to yellowish liquid
안전 및 규제
| GHS 분류 | This chemical does not meet GHS hazard criteria for 7.1% (6 of 85) of reports.DangerH315 (55.3%): Causes skin irritation [Warning Skin corrosion/irritation]P260, P261, P264, P264+P265, P270, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P316, P317, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 85 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| 규제 정보 | Status: Active Update: 17-02-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/23561 |
| 유해성 요약 | Causes changes in leukocyte count, changes in liver weight, and weight loss in repeated-dose inhalation studies of rats[RTECS] A skin and strong eye irritantHarmful by inhalation[Sigma-Aldrich MSDS] See Perfluoropropane. |
| Hazard Classes and Categories | Skin Irrit. 2 (55.3%) |
| 유해 작용 | Neurotoxin - Acute solvent syndrome |
| Toxicity Data | LC50 (rat) = 8,100 mg/m3/4hr |
| 수질 위해 등급(WGK) | 3 |
| TSCA 등재 상태 | TSCA listed |
| RTECS 번호 | TZ3925000 |
| 운송 번호(UN) | 2810 |
| 관세 코드 | 29037800 |
| 위험 문구(R) | 20-36/37/38 |
| 위험 표시 | Xn,Xi,T |
| 안전 문구(S) | 26-36-37/39 |
| 포장분류 | III |
| 위험 등급 | 6.1(b)Acute Tox. 4 InhalationEye Irrit. 2Skin Irrit. 2STOT SE 3 |
| F 고인화성물질 | 8 |
용도
용도
Heptafluoro-2-iodopropane may be used in the preparation of perfluoropropyl magnesium bromide and perfluoropropyl magnesium iodide. It may be used as chain-transfer agent in telomerization reactions of:1,1-difluoroethylene and tetrafluoroethyleneCF3I, C2F5I and n-C3F7I with 1,1-difluoroethylenen-C3F7I with tetrafluoroethylene
일반 설명
Heptafluoro-2-iodopropane is a secondary fluoro alkyl iodide. It can be prepared by addition of iodine monofluoride to hexafluoropropene.