((트리메틸시릴)메틸)리튬

Lithium;methanidyl(trimethyl)silane

HCID 3482579CAS 1822-00-0
부분 구조 검색유사 구조 찾기

기본 정보

표준 SMILES
[CH2-][Si](C)(C)C.[Li+]
InChIKey
KVWLUDFGXDFFON-UHFFFAOYSA-N
분자식
C4H11LiSi
평균 분자량
94.2 g/mol
단동위원소 질량
94.07900643

개요

See also: Lithium, (trimethylsilyl)methyl- (annotation moved to).

이름 및 식별자

우선 이름
Lithium;methanidyl(trimethyl)silane
IUPAC
lithium methanidyl(trimethyl)silane
현지명
((트리메틸시릴)메틸)리튬
영어명
(Trimethylsilyl)methyllithium
분자식
C4H11LiSi
분자량
94.16

이름 및 동의어

lithium;methanidyl(trimethyl)silaneRefChem:799973629-440-7(Trimethylsilyl)methyllithium1822-00-0trimethylsilylmethyllithiumLiCH2SiMe3TMS-CH2LiTrimethylsilyllithium solution((trimethylsilyl)methyl)lithiumLithium (trimethylsilyl)methanideTrimethylsilylmethyllithium, 0.7M in hexane
이름 더 보기
((트리메틸시릴)메틸)리튬((트리메틸시릴)메틸)리튬(((TRIMETHYLSILYL)METHYL)LITHIUM)LithiomethyltrimethylsilaneRIMETHYLSILYL)METHYLLITHIUMmethanidyl(trimethyl)silaneTrimethyl(lithiomethyl)silaneLithio(trimethylsilyl)methaneTrimethylsiloxy-MethyllithiumLithium, (trimethylsilyl)methyl-(trimethylsilyl)methyllithiumsolution
(Trimethylsilylmethyl) lithiumlithium,methanidyl(trimethyl)silaneMFCD00010747trimethylsilylmethyl lithiumTrimethylsilyl methyllithium(trimethylsilylmethyl)lithiumSCHEMBL453842SCHEMBL7880155

데이터베이스 식별자

CAS
1822-00-0
PubChem CID
3482579
DTXSID
DTXSID90392901
EC Number
629-440-7
Nikkaji
J337.666D

물성

구조 계산 물성

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
1
회전 가능 결합 수
0
무거운 원자 수
6

실험 및 물리화학적 성질

Density0.65 @25 °C
Melting Point13.9 °C

물리화학적 성질

녹는점
112 · 112-117 °C (decomp)
끓는 점
35 · 35-36 °C
밀도
0.65 g/mL · 0.65 g/mL at 25 °C
인화점
57 °F · −57 °F
저장 조건
2 · 2-8°C
용해도
에테르 용매에 용해됨; 양성자성 용매와 반응한다.

화학적 성질

Clear light yellow liquid

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H225 (38.5%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 65 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory InformationREACH registered substance: lithium;methanidyl(trimethyl)silane (EC: 629-440-7)
Hazard Classes and CategoriesFlam. Liq. 2 (38.5%)

안전 및 보호

Protective Action Criteria (PAC) · 3건

1.2 [mg/m3]

13 [mg/m3]

79 [mg/m3]

안전 데이터

wgk
1
ridadr
UN 3399 4.3/PG 1
HS 번호
29319090
risk_code
11-14-34-51/53-65-66-67-12-2
hazard_code
F,C,N,F+
safety_code
16-26-33-36/37/39-43-45-61-62

화학 및 산업

응용 분야

용도Initiates polymerization and copolymerization of cyclosiloxanes.1 Alkylates metal complexes.2

제조 방법

Trimethylsilylmethyllithium is obtained by reaction of (chloromethyl)- trimethylsilane with lithium metal in an inert solvent. It is also available by displacement of a heteroatom group based on sulfur, silicon, or tin.

상·하류 제품 정보

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]

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