N-(메톡시메틸)-N-(트리메틸실릴메틸)벤질아민
Benzyl(methoxymethyl)((trimethylsilyl)methyl)amine
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기본 정보
- CAS
93102-05-7- 표준 SMILES
COCN(Cc1ccccc1)C[Si](C)(C)C- InChIKey
RPZAAFUKDPKTKP-UHFFFAOYSA-N- 분자식
- C13H23NOSi
- 평균 분자량
- 237.41 g/mol
- 단동위원소 질량
- 237.15489089
이름 및 식별자
- 우선 이름
- Benzyl(methoxymethyl)((trimethylsilyl)methyl)amine
- IUPAC
- N-(methoxymethyl)-1-phenyl-N-(trimethylsilylmethyl)methanamine
- 현지명
- N-(메톡시메틸)-N-(트리메틸실릴메틸)벤질아민
- 영어명
- N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
- 분자식
- C13H23NOSi
- 분자량
- 237.41
이름 및 동의어
benzyl(methoxymethyl)[(trimethylsilyl)methyl]amineBenzyl(methoxymethyl)((trimethylsilyl)methyl)amineRefChem:566907630-326-493102-05-7N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamineN-benzyl-1-methoxy-N-((trimethylsilyl)methyl)methanamineN-(methoxymethyl)-1-phenyl-N-(trimethylsilylmethyl)methanamineMFCD00674005N-Benzyl-N-(methoxymethyl)-N-trimethylsilylmethylaminen-methoxymethyl-n-(trimethylsilylmethyl)benzylamineC13H23NOSi
이름 더 보기
N-(메톡시메틸)-N-(트리메틸실릴메틸)벤질아민N-Benzyl-N-(methoxymethyl)trimethylsilylmethylamineN-benzyl(methoxy)-N-((trimethylsilyl)methyl)methanamine)-N-trimethyLcas:93102-05-7-N-(methoxymethyLN-(Methoxymethyl)-N-(trimethyl
N-(Methoxymethyl)-N-(trimethylsilylmethyl)-benzylamineN-Benzyl-1-methoxy-N-[(trimethylsilyl)methyl]methanamineS00978F0001-2246N-benzyl-N-methoxymethyl-N-(trimethylsilylmethyl)amineN-benzyl-1-methoxy-N-[(trimethylsilyl)methyl)methanamineN-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amineN-(Methoxymethyl)-N-[(trimethylsilyl)methyl]benzenemethanamine (>90%)
데이터베이스 식별자
- CAS
93102-05-7- PubChem CID
- 353442
- DTXSID
DTXSID30326563- EC Number
- 630-326-4
- Nikkaji
- J436.255A
물성
구조 계산 물성보충 중
- 극성 표면적
- 12.5 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 2
- 회전 가능 결합 수
- 6
- 무거운 원자 수
- 16
- 형식 전하
- 0
- 복잡도
- 185
물리화학적 성질
- 끓는 점
- 76 °C0.3 · 76 °C0.3 mm Hg(lit.)
- 밀도
- 0.928 g/mL · 0.928 g/mL at 25 °C(lit.)
- 굴절률
- 20 · n20/D 1.492(lit.)
- 인화점
- 151 °F · 151 °F
- 저장 조건
- Keep in dark place,Sealed in dry,Room Temperature
- 용해도
- 클로로포름, 에틸아세테이트에 용해됩니다.
- 물리적 상태
- 액체
- 산도 계수 (pKa)
- 7.29 · 7.29±0.50(Predicted)
- Specific Gravity
- 0.928 · 0.928
- 색상
- 무색투명~연황색
- BRN
- 4311216 · 4311216
- InChI
- 1S/C13H23NOSi/c1-15-11-14(12-16(2,3)4)10-13-8-6-5-7-9-13/h5-9H,10-12H2,1-4H3
- InChIKey
- RPZAAFUKDPKTKP-UHFFFAOYSA-N
- SMILES
- COCN(Cc1ccccc1)C[Si](C)(C)C
화학적 성질
N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine is clear colorless to light yellow liquid
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (98.1%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 52 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
유해성 정보
Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (98.1%)
안전 데이터
- wgk
- 3
- ridadr
- 1993
- HS 번호
- 29319090
- risk_code
- 36/37/38
- hazard_code
- Xi
- safety_code
- 26-37/39
- 포장분류
- Ⅲ
- 위험 등급
- 3
- Hazard Classifications
- Eye Irrit. 2Skin Irrit. 2STOT SE 3
- 스토리지 클래스
- 10 - Combustible liquids
화학 및 산업
응용 분야
용도N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine is useful reagent in synthesizing N-benzyl substituted pyrrolidines by [3+2] cycloaddition to α,ßunsaturated esters.
제조 방법
most conveniently prepared by treatment of benzylamine with chloromethyltrimethylsilane followed by formaldehyde and methanol.Access to higher ether homologs is achieved by replacing methanol with the appropriate alcohol. An alternate procedure involves alkylation of lithium N-benzyltrimethylsilymethylamide with methoxymethyl chloride.
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