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헵타클로르

Heptachlor

HCID 3589
노트반응

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기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
76-44-8
표준 SMILES
ClC1=C(Cl)C2(Cl)C3C(Cl)C=CC3C1(Cl)C2(Cl)Cl
InChIKey
FRCCEHPWNOQAEU-UHFFFAOYSA-N
분자식
C10H5Cl7
평균 분자량
373.321 g/mol
단동위원소 질량
369.82109392

이름 및 식별자

우선 이름
Heptachlor
IUPAC
1,4,5,6,7,8,8-Heptachloro-3a,4,7,7a-tetrahydro-1H-4,7-methanoindene
현지명
헵타클로르
영어명
HEPTACHLOR
분자식
C10H5Cl7
분자량
373.32

이름 및 동의어

헵타헵타클로르3-클로로로데렌HeptaHeptachlor StandardE3314E3314(R)Heptachloor1,4,5,6,7,8,8-HEPTACHLORO-3A,4,7,7A-TETRAHYDRO-4,7-METHANOINDENEGPkhH-34H-60
이름 더 보기
Heptox

데이터베이스 식별자

CAS
76-44-8
PubChem CID
3589
DTXSID
DTXSID3020679
ChEMBL
CHEMBL194400
ChEBI
CHEBI:34785
EC Number
200-962-3
Nikkaji
J9.240A

물성

물리화학적 성질

녹는점
96 ℃ · 96℃
끓는 점
458.95 °C · 458.95°C (rough estimate)
밀도
1.6 g/cm3 · 1.6 g/cm3
증기압
2.33 · 2.33(x 10-4 mmHg) at 25 °C (subcooled liquid vapor pressure calculated from GC retention time data, Hinckleyet al., 1990)
굴절률
1.5407 · 1.5407 (estimate)
인화점
11 °C · 11 °C
저장 조건
4 °C · APPROX 4°C
수용성
0.056 mg · 0.056mg l-1(25-29°C)
Merck
13 · 13,4675
Henry's Law Constant
0.19 · 0.19(x 10-3 atmm3/mol) at 5 °C, 0.31 at 15 °C, 0.40 at 20 °C, 0.61 at 25 °C, 0.82 at 35 °C:in 3% NaCl solution: 0.52 at 5 °C, 0.82 at 15 °C, 1.33 at 25 °C, 2.09 at 35 °C (gas stripping-GC, Cetin et al., 2006)
안정성
안정적인. 불연성. 강알칼리, 산화제와 호환되지 않습니다. 많은 금속을 부식시킵니다.
EPA
Heptachlor (76-44-8)
화학적 성질 · 1건

Heptachlor is an organochlorine cyclodiene insecticide isolated from technical chlordane. It is available in the form of white crystals or a tan-colored waxy solid with a characteris- tic camphor-like or cedar-like odor. It is sparingly soluble or insoluble in water, but fairly soluble in acetone, benzene, ethanol, xylene, and other organic solvents. It is used for the control of termites, ants, and soil insects in cultivated and non-cultivated soils. Heptachlor epoxide is formed in nature when heptachlor is released into the environment and mixes with oxygen. Heptachlor epoxide remains in the soil for long periods of time. Heptachlor and heptachlor epoxide may also be present at numerous hazardous waste sites. Although the use of heptachlor is restricted, exposure to the general population does occur through the ingestion of contaminated food.

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

안전 데이터

OEB
C
OEL
TWA: 0.5 mg/m3 [skin]
wgk
3
IDLA
35 mg/m3
rtecs
PC0700000
ridadr
2761
독성
LD50 in male, female rats (mg/kg): 100, 162 orally (Gaines)
risk_code
24/25-33-40-50/53-39/23/24/25-23/24/25-11-67-65-38-51/53
hazard_code
T,N,F,Xn
safety_code
36/37-45-60-61-62-16-7
포장분류
II
위험 등급
6.1(a)
기존화학 물질
KE-05-0679
유해 물질 데이터
76-44-8(Hazardous Substances Data)
함량 및 규제정보
물질구분: 금지물질; 혼합물(제품)함량정보: 헵타클로르 및 이를 6% 이상 함유한 혼합물
유해화학물질 필터링
97-1-403;06-4-52

화학 및 산업

응용 분야 · 3건

개요Heptachlor is a soft, white to light tan, waxy, non-combustible, crystalline solid with a camphor-like odour. Heptachlor is a member of the cyclodiene group of chlorinated insecticides (aldrin, dieldrin, endrin, chlordane, heptachlor, and endosulfan) and has a long history following World War II. It was registered as a commercial pesticide in 1952 for foliar, soil, and structure applications and for malarial control programmes; after 1960, it was used primarily in soil applications against agricultural pests and to a lesser extent against termites. Heptachlor is available commercially as a dust, a dust concentrate, an emulsifiable concentrate, a wettable powder, or in oil solutions. It is corrosive to metals and reacts with iron and rust to form hydrogen chloride gas. Heptachlor is incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides but is stable under normal temperatures and pressures. It may burn, but does not ignite readily. Heptachlor at high heat and temperature produces highly toxic, corrosive fumes of hydrogen chlorine gas and toxic oxides of carbon. An important metabolite of heptachlor is heptachlor epoxide which is an oxidation product formed from heptachlor by many plant and animal species. Heptachlor is almost insoluble in water but soluble in ether, acetone, benzene, and many other organic solvents.

용도Heptachlor is used for the control of termites, ants, household insects and soil insects. It is also applied as a seed treatment, soil treatment or directly to foliage.

일반 설명HEPTACHLOR is a white to light tan waxy looking solid. Noncombustible. Insoluble in water. Can cause illness by inhalation, skin absorption and/or ingestion. The primary hazard is the threat posed to the environment. Immediate steps should be taken to limit its spread to the environment. Used as an insecticide.

제조 방법

Heptachlor may be synthesized by reacting chlordene with N-bromosuccinimide to give the intermediate 1-bromochlordene followed by chlorination with hydrogen chloride in nitromethane in the presence of aluminum trichloride.

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이 페이지에서기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
추가 설명 · 1건

정의ChEBI: A cyclodiene organochlorine insecticide that is 3a,4,7,7a-tetrahydro-1H-4,7-methanoindene substituted by chlorine atoms at positions 1, 4, 5, 6, 7, 8 and 8. Formerly used to kill termites, ants and other insects in agricultural and domes ic situations.