tert-Butyldimethylsilyl glycidyl ether

HCID 3605359CAS 78906-15-7

기본 정보

표준 SMILES: CC(C)(C)[Si](C)(C)OCC1CO1
InChIKey: YANSSVVGZPNSKD-UHFFFAOYSA-N
분자식: C9H20O2Si
평균 분자량: 188.34 g/mol
단동위원소 질량: 188.12325641

이름 및 식별자

우선 이름: tert-Butyldimethylsilyl glycidyl ether
IUPAC: tert-butyl-dimethyl-(oxiran-2-ylmethoxy)silane
영어명: TERT-BUTYLDIMETHYLSILYL GLYCIDYL ETHER
분자식: C9H20O2Si
분자량: 188.34

이름 및 동의어

tert-Butyldimethylsilyl glycidyl ether78906-15-7DTXSID80394090RefChem:383918DTXCID40344950tert-butyl-dimethyl-(oxiran-2-ylmethoxy)silaneOxirane, 2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-tert-butyldimethyl(oxiran-2-ylmethoxy)silaneCTK5E6209SCHEMBL111369YANSSVVGZPNSKD-UHFFFAOYSA-NOxirane,2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-

이름 더 보기

tert-Butyldimethylsilyl glycidyl ether 98%ert-butyl-dimethyl-(oxiran-2-ylmethoxy)silane

AKOS025295761(S)-t-Butyldimethylsilyl Glycidyl EtherAS-91641DA-02761t-butyldimethyl(oxiran-2-ylmethoxy)silanetert-Butyldimethylsilyl glycidyl ether, 98%H57233(+/-)-(tert-butyldimethylsilyl) glycidyl ether

데이터베이스 식별자

CAS: 78906-15-7
PubChem CID: 3605359
DTXSID: DTXSID80394090
Nikkaji: J1.244.035I

물성

구조 계산 물성

극성 표면적: 21.8 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 2
회전 가능 결합 수: 4
무거운 원자 수: 12
형식 전하: 0
복잡도: 160

물리화학적 성질

끓는 점: 195 · 195-197 °C (lit.)
밀도: 0.901 g/mL · 0.901 g/mL at 25 °C (lit.)
굴절률: 20 · n20/D 1.531(lit.)
인화점: 70 °C · 70 °C
InChI: 1S/C9H20O2Si/c1-9(2,3)12(4,5)11-7-8-6-10-8/h8H,6-7H2,1-5H3
InChIKey: YANSSVVGZPNSKD-UHFFFAOYSA-N
SMILES: CC(C)(C)[Si](C)(C)OCC1CO1

안전 및 규제

안전 데이터

wgk: 3
스토리지 클래스: 10 - Combustible liquids

화학 및 산업

응용 분야

용도tert-Butyldimethylsilyl glycidyl ether may be used to synthesize (R/S)-1-benzylamino-3-(tert-butyldimethylsilyloxy)propan-2-ol and (2R/2S)-1-(tert-butyldimethylsilyloxy)-3-{[(4S)-2,2-dimethyl-1,3-dioxolan-4-ylmethyl]amino}propan-2-ol.

일반 설명tert-Butyldimethylsilyl glycidyl ether [tert-butyl-dimethyl-(oxiran-2-ylmethoxy)silane] can be synthesized from glycidol, via hydrolytic kinetic resolution (HKR) in the presence of R-(salen)Co complex and water.