(S)-(-)-2,2'-비스[디(3,5-자일릴)포스피노]-1,1'-비나프틸

(R)-(+)-2,2'-Bis(di(3,5-xylyl)phosphino)-1,1'-binaphthyl

HCID 4189905CAS 135139-00-3

부분 구조 검색 유사 구조 찾기

기본 정보

표준 SMILES: Cc1cc(C)cc(P(c2cc(C)cc(C)c2)c2ccc3ccccc3c2-c2c(P(c3cc(C)cc(C)c3)c3cc(C)cc(C)c3)ccc3ccccc23)c1
InChIKey: MXGXXBYVDMVJAO-UHFFFAOYSA-N
분자식: C52H48P2
평균 분자량: 734.9 g/mol
단동위원소 질량: 734.3231248

이름 및 식별자

우선 이름: (R)-(+)-2,2'-Bis(di(3,5-xylyl)phosphino)-1,1'-binaphthyl
IUPAC: [1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane
현지명: (S)-(-)-2,2'-비스[디(3,5-자일릴)포스피노]-1,1'-비나프틸
영어명: (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
분자식: C52H48P2
분자량: 734.89

이름 및 동의어

135139-00-3137219-86-4(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL(R)-(+)-2,2'-Bis(di(3,5-xylyl)phosphino)-1,1'-binaphthyl1,1'-Binaphthalene-2,2'-diylbis(bis(3,5-dimethylphenyl)phosphine)1,1'-Binaphthalene-2,2'-diylbis[bis(3,5-dimethylphenyl)phosphine]RefChem:406967681-146-8681-153-6(R)-DM-BINAP145416-77-9(S)-DM-BINAP

이름 더 보기

(S)-(-)-2,2'-비스[디(3,5-자일릴)포스피노]-1,1'-비나프틸XylbinapRAC-XYLYL-BINAP(S)-3,5-XYLYL-BINAP(S)-(-)-2,2'-bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl(S)-(-)-XyL98% (S)-XylBINAP(S)-(-)-XylBINAP(S)-3,5-Xyl-BINAPRAC-3,5-Xylyl-Binap

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl(R)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl2,2'-bis(di-3,5-xylylphosphino)-1,1'-binaphthylDM-BINAP[1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphaneMFCD01630821(R)-(+)-XYLBINAP(R)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene

데이터베이스 식별자

CAS: 135139-00-3、137219-86-4、145416-77-9
PubChem CID: 4189905
DTXSID: DTXSID301380044
EC Number: 681-146-8、681-153-6、682-114-6
Nikkaji: J1.535.409G、J2.376.180G、J986.374E

물성

구조 계산 물성

XLogP: 14.3
극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 7
무거운 원자 수: 54
형식 전하: 0
복잡도: 999

물리화학적 성질

녹는점: 203 · 203-206°C
끓는 점: 825.3 · 825.3±65.0 °C(Predicted)
저장 조건: Inert atmosphere,Room Temperature
수용성: 물에 불용성
물리적 상태: 수정 같은
색상: 흰색에서 연한 노란색
InChIKey: MXGXXBYVDMVJAO-UHFFFAOYSA-N
SMILES: C1(C2C=CC=CC=2C=CC=1P(C1=CC(=CC(C)=C1)C)C1=CC(=CC(C)=C1)C)C1C2C=CC=CC=2C=CC=1P(C1=CC(=CC(C)=C1)C)C1=CC(=CC(C)=C1)C

안전 및 규제

GHS 분류

GHS Classification · 6건

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 6 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

유해성 정보

Hazard Classes and Categories · 3건

Skin Irrit. 2 (100%)

안전 데이터

wgk: WGK 3
tsca: No
HS 번호: 2931.90.6000
risk_code: 36/37/38
safety_code: 26-37
스토리지 클래스: 11 - Combustible Solids

화학 및 산업

응용 분야 · 1건

용도Catalyst for:Asymmetric hydrogenation of benzophenoneRegio- and stereoselective preparation of axially chiral arylnaphthalene derivatives via rhodium-catalyzed [2+2+2] cycloaddition of diynes with naphthalenepropynoic acid derivatives in the presence of chiral biaryl bisphosphine ligandsRegiodivergent rhodium-catalyzed [(2+2)+2] carbocyclization of 1,6-enynes with Me propiolatesLigand controlled regioselective and stereoselective desymmetrizing rhodium-catalyzed allylic arylation of meso cyclopentene dicarbonates with arylboronic acids to form regioisomeric arylcyclopentenolsPlatinum(II) complex-catalyzed enantioselective aldol reaction with ketene silyl acetals in DMF at room temperatureStereoselective preparation of chiral N,O-biaryls via Rh-catalyzed [2+2+2] cycloaddition of conjugate ynamides with diynes