데이터를 보충하는 중입니다. 잠시 후 페이지를 새로 고치면 최신 내용을 볼 수 있습니다
기본 정보
- CAS
13965-03-2- 표준 SMILES
[Cl][Pd][Cl].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1- 분자식
- C36H30Cl2P2Pd
- 평균 분자량
- 701.9 g/mol
이름 및 식별자
- 우선 이름
- Bis(triphenylphosphine)palladium(II) chloride
- 영어명
- Bis(triphenylphosphine)palladium(II) chloride
- 분자식
- C36H30Cl2P2Pd
- 분자량
- 701.9
이름 및 동의어
Pd(PPh3)2Cl2PdCl2(PPh3)2Pd(PPh3)Cl2DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUMBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) DICHLORIDE(PPh3)2PdCl2DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II)BIS(TRIPHENYLPHOSPHINE)PALLADIUM CHLORIDEBis(triphenylphosphine)dichloropalladiumBis(triphenylphosphine)palladium(ll) chloride
데이터베이스 식별자
- CAS
13965-03-2- PubChem CID
- 420332
물성
물리화학적 성질
- 녹는점
- 260 °C · 260°C
- 증기압
- 0 Pa · 0Pa at 25℃
- 저장 조건
- 30 °C · Store below +30°C.
- 용해도
- 클로로포름(약간 용해됨), 디클로로메탄(약간 용해됨, 가열), 메탄올(약간 용해됨）
- 물리적 상태
- 가루
- 색상
- 노란색
- 수용성
- 물에 불용성. 벤젠, 톨루엔에 용해됩니다.
- BRN
- 4935975 · 4935975
- InChI
- InChI=1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
- InChIKey
- ILBDOZRDKNIJBS-UHFFFAOYSA-N
- SMILES
- P(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Pd](Cl)Cl
- LogP
- 5.69 at · 5.69 at 20℃
화학적 성질
Bis(triphenylphosphine)palladium chloride is a coordination compound of palladium containing two triphenylphosphine and two chloride ligands. This yellow solid is insoluble in water but can dissolve in some organic solvents, such as toluene and benzene, and is slightly soluble in acetone and chloroform. It is used for palladium-catalyzed coupling reactions, e.g. the Sonogashira–Hagihara reaction. The complex adopts a square planar geometry and numerous similar complexes are known, with different phosphine ligands.
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
안전 데이터
- wgk
- 3
- tsca
- No
- HS 번호
- 28439090
- risk_code
- 36/37/38-22-40-19
- hazard_code
- Xn
- safety_code
- 37/39-26-36/37
- F 고인화성물질
- 3-10-21
- Hazard Classifications
- Aquatic Chronic 4Skin Sens. 1A
- 스토리지 클래스
- 11 - Combustible Solids
화학 및 산업
응용 분야
용도Bis(triphenylphosphine)palladium(II) chloride is used primarily in organometallic catalytic reactions due to the palladium content of the compound. It is also involved in crystalized structures of me tallacyclic complexes which show antiinflammatory and antifungal properties.
일반 설명Bis(triphenylphosphine)palladium(II) dichloride is an organometallic complex. It is an efficient cross-coupling catalyst for C-C coupling reaction, such as Negishi coupling, Suzuki coupling, Sonogashira coupling and Heck coupling reaction. Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported. It is employed as catalyst for the Heck reaction medium.
상·하류 제품 정보
상류 원료
관련 반응
0건
현재 필터 조건에 해당하는 반응 기록이 없습니다.
화합물 노트
불러오는 중…