데이터를 보충하는 중입니다. 잠시 후 페이지를 새로 고치면 최신 내용을 볼 수 있습니다
기본 정보
- CAS
387362-69-8- 표준 SMILES
CN1CCCC1CN1CCCC1CO- InChIKey
VAUQXPBOGCJNHH-QWRGUYRKSA-N- 분자식
- C11H22N2O
- 평균 분자량
- 198.31 g/mol
이름 및 식별자
- 우선 이름
- (2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE
- 영어명
- (2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE
- 분자식
- C11H22N2O
- 분자량
- 198.31
이름 및 동의어
(2S,2''S)-(-)-2-HYDROXYMETHYL-1-[(1-METHY2-hydroxymethyl-(1-methylpyrrolidin-2ylmethyl)pyrrolidine(-)-2-HYDROXYMETHYL-(1-METHYLPYRROLIDIN- 2-YLME)PYRROLIDINE(1-((1-Methylpyrrolidin-2-yl)methyl)pyrrolidin-2-yl)methanol(2S,2S)-1-(1-Methyl-2-pyrrolidinylmethyl)pyrrolidine-2-methanol2-PyrrolidineMethanol,1-[[(2S)-1-Methyl-2-pyrrolidinyl]Methyl]-, (2S)-(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDINE-2-YL)-METHYL]-PYRROLIDINE
데이터베이스 식별자
- CAS
387362-69-8、66283-23-6- PubChem CID
- 4358320
물성
물리화학적 성질
- 끓는 점
- 275 · 275-277 °C
- 밀도
- 1.034 · 1.034±0.06 g/cm3(Temp: 25 °C; Press: 760 Torr)(predicted)
- 굴절률
- 20 · n20/D 1.494
- 용해도
- 2 O, · sol hexane, toluene, Me2O, Et2O, n-Pr2O, THF, dimethoxymethane.
- 산도 계수 (pKa)
- 14.773 · 14.773±0.10(predicted)
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
안전 데이터
- ridadr
- 1760
- risk_code
- 34
- hazard_code
- C
- safety_code
- 26-36/37/39-45
- 포장분류
- III
- 위험 등급
- 8
화학 및 산업
응용 분야
용도(2S,2′S)-2-Hydroxymethyl-1-[(1-methylpyrrolidin-2-yl)methyl]pyrrolidine is a chiral ligand for alkyllithium, dialkylmagnesium, alkynyllithium, and functionalized organolithiums in the enantioselective addition to aldehydes; accelerates the basicity of alkyllithiums; catalyzes the addition of dialkylzinc to aldehyde.
제조 방법
Preparative Method of (2S,2′S)-2-Hydroxymethyl-1-[(1-methylpyrrolidin-2-yl)methyl]pyrrolidine: reduction of N-[N(-benzyloxycarbonyl)prolyl]proline methyl ester with Lithium Aluminum Hydride affords the title reagent in 81% yield.
공급사1 곳
上海迪外化工科技有限公司021-61551100
관련 반응
0건
현재 필터 조건에 해당하는 반응 기록이 없습니다.
화합물 노트
불러오는 중…