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7778-54-3Calcium hypochlorite, Ca(OCl)2.4H20, also known as calcium oxychloride, chlorinated lime, and bleach, is a deliquescent white powder used as a bleaching agent in the textile and pulp industries and as a disinfectant. It contains 60 to 65% available chlorine,
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개요Calcium hypochlorite, is an oxysalt; it is a crystalline solid and an oxidizer that decomposes at 212°F (100°C). Calcium hypochlorite is a dangerous fire risk in contact with organic materials. It is also a common swimming pool chlorinator and decomposes in contact with water, releasing chlorine into the water. If a container of calcium hypochlorite becomes wet in storage, the result can be an exothermic reaction. If combustible materials are present, a fire may occur. The chlorine in the compound will be released by contact with the water and will then accelerate the combustion process. The four-digit UN identification number for dry mixtures with not less than 39% available chlorine (8.8% oxygen) is 1748; hydrated with not less than 5.5% and not more than 10% water, the number is 2880; mixtures that are dry, with not less than 10% but not more than 39% available chlorine, are numbered as 2208. The NFPA 704 designation for calcium hypochlorite is health 3, flammability 0, and reactivity 1. The white section at the bottom of the diamond has the prefix “oxy,” indicating an oxidizer. The primary uses are as a bleaching agent, a swimming pool disinfectant, a fungicide, in potable-water purification, and as a deodorant.
용도Bleaching powder is actually a mixture of calcium hypochlorite (Ca(ClO)2) and the basic chloride CaCl2, H2O with some slaked lime, Ca(OH)2. The product is generally called “bleaching powder”. It consists of a mixture of calcium chloride (CaCl2), calcium hypochlorite (Ca(OCl)2), and calcium chloride hypochlorite (CaCl(OCl)). Ca(ClO)2 is used in industrial wastewater treatment, sanitation and cleaning, epidemic prevention and household sanitation facilities, as well as for disinfection and sterilization of swimming pools, drinking water, cleaning vegetables, and sanitizing fishponds. Calcium hypochlorite has been used for bleaching of cotton, hemp, fiber, pulp and starch, disinfection of surfaces, and as a sterilant for water treatment. It has also been proposed as a solid fire extinguisher.
일반 설명Calcium hypochlorite, hydrated is a white granular solid or tablets compressed from the granules having an odor of chlorine. Calcium hypochlorite is noncombustible, but Calcium hypochlorite will accelerate the burning of combustible materials. Calcium hypochlorite is decomposed by water with evolution of chlorine gas and heat. Prolonged exposure to fire or heat may result in the vigorous decomposition of the material and rupture of the container. Material containing less than 39% available chlorine may undergo reactions as described above though Calcium hypochlorite may take longer to initiate, and the resulting reactions may not be as vigorous. Calcium hypochlorite is used for water purification, disinfectant for swimming pools, for bleaching paper and textiles, and for many other uses.
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Calcium hypochlorite is manufactured by two main processes, the socalled “calcium process” and the “sodium process”. These are essentially the same as described for the Mg(ClO)2 salt method given above except that a sodium hypochlorite salt is used in one case and a calcium chloride salt in the other. The products are nearly the same. Calcium hypochlorite is manufactured by the calcium process: 2Ca(OH)2+2Cl2→Ca(ClO)2+CaCl2+2H2O In another method developed for the manufacture of Ca(ClO)2, chlorine gas is reacted with calcium hydroxide: Ca(OH)2+ 2Cl2→Ca(ClO)2+ 2HCl In this method, it is claimed that the excess HCl is neutralized by excess Ca(OH)2 to form CaCl2. The product is said to be more “neutral” chemically and more stable than that produced by other methods.
확인시험(1) 이 품목 0.5g에 물 5mL를 가하여 흔들어 섞고 이에 적색리트머스지를 담그면 리트머스지는 청색으로 변하고 다음에 퇴색한다. (2) 이 품목 0.1g에 초산(1→4) 2mL를 가하면 가스를 발생하면서 녹는다. 이에 물 5mL를 가하여 여과한 액은 확인시험법 중 칼슘염의 반응을 나타낸다.
정량법이 품목 약 0.7∼1.3g을 정밀히 달아 물 약 50mL을 가하여 잘 섞은 다음 500mL 메스플라스크에 넣고 물을 가하여 500mL로 한 다음 잘 흔들어 섞고 그 중 50mL에 요오드칼륨 2g 및 초산(1→2) 10mL을 가하고 바로 밀봉하여 암소에 15분간 방치한 후 유리된 요오드를 0.1N 치오황산나트륨용액으로 적정한다(지시약 : 전분시액). 종말점은 액의 청색이 사라질 때로 한다. 따로 같은 방법으로 공시험을 한다.
정의A white solid that can be regarded as a mixture of calcium chlorate(I) (calcium hypochlorite), calcium chloride, and calcium hydroxide. It is prepared on a large scale by passing a current of chlorine through a tilted cylinder down which is passed calcium hydroxide. Bleaching powder has been used for bleaching paper pulps and fabrics and for sterilizing water. Its bleaching power arises from the formation, in the presence of air containing carbon dioxide, of the oxidizing agent chloric(I) acid (hypochlorous acid, HClO): Ca(ClO)2.Ca(OH)2.CaCl2 + 2CO2 → 2CaCO3 + CaCl2 + 2HClO.